Results 81 to 90 of about 6,890,863 (253)

Template‐Encoded Assembly and Adaptive Function in Selenium‐Based Molybdenum Chalcoxide Rings

open access: yesAngewandte Chemie, EarlyView.
External templates write structural information into Se‐containing molybdenum rings, while selenium's softness confers adaptive host–guest behaviour and catalytic responsiveness, an integrated framework for programmable inorganic function. ABSTRACT Controlling both structure and function in inorganic self‐assembly remains a major challenge.
Giulia Pellegrino   +4 more
wiley   +2 more sources

An Autonomous Large Language Model‐Agent Framework for Transparent and Local Time Series Forecasting

open access: yesAdvanced Intelligent Discovery, EarlyView.
Architecture of the proposed large language model (LLM)‐based agent framework for autonomous time series forecasting in thermal power generation systems. The framework operates through a vertical pipeline initiated by natural language queries from users, which are processed by the LLM Agent Core powered by Llama.cpp and a ReAct loop with persistent ...
William Gouvêa Buratto   +5 more
wiley   +1 more source

Semiconducting Covalent Organic Frameworks Based on Spin‐Delocalized Trioxotriangulene Neutral Radicals

open access: yesAngewandte Chemie, EarlyView.
Imine‐linked 2D covalent organic frameworks incorporating delocalized trioxotriangulene (TOT) neutral radicals were synthesized through complementary routes. Direct incorporation of an amine‐functionalized TOT radical yields a highly crystalline, porous framework (TOT‐COF‐H) with intrinsic semiconducting behavior (σRT = 1.2 × 10−4 S cm−1) and a narrow ...
Paula Escamilla   +8 more
wiley   +2 more sources

Brasília convida Pessoa [PDF]

open access: yesPessoa Plural
Brasília and Fernando Pessoa share a fictional essence: the former as an invented city, the latter as a multifaceted, self-reflective poet. This special issue captures the unique encounter between Pessoa and Brazil’s capital, celebrated at the “II ...
Medeiros, Ana Clara de
doaj   +1 more source

Machine‐Learning‐Assisted Onset‐Time Determination in Transient Luminescence Thermometry

open access: yesAdvanced Intelligent Discovery, EarlyView.
Artificial neural networks enable autonomous extraction of onset times from transient heating curves in luminescence thermometry. Using Ln3+‐doped upconverting nanoparticles as luminescent thermometers, we combine experimental transients with physically motivated synthetic curves to enhance data diversity and improve generalization.
David J. Sousa   +3 more
wiley   +1 more source

Broad‐Spectrum, Cell Envelope‐Active Marinocyclin Antibiotics From a Coral‐Derived Bacterium Are Effective Against Colistin‐Resistant Bacteria

open access: yesAngewandte Chemie, EarlyView.
Marinocyclins, polycationic macrocyclic depsipeptides, were discovered by genome mining from the marine coral‐derived bacterium Aquimarina megaterium. The compounds have broad‐spectrum activity against gram‐positive and gram‐negative ESKAPE bacteria.
Clara Chepkirui   +9 more
wiley   +2 more sources

La presencia de lo extranjero en las novedades bibliográficas de La Ilustración Española y Americana (1869-1905)

open access: yesCahiers de Civilisation Espagnole Contemporaine, 2013
There is no doubt that La Ilustración Española y Americana (LIEA), magazine that includes approximately the last third of the 19th century and the first twenty years of the 20th century (1869-1921), had a relevant role from the point of view of the ...
Anna-Maria Corredor Plaja
doaj   +1 more source

Preferential trading in agriculture: New insights from a structural gravity analysis and machine learning

open access: yesAmerican Journal of Agricultural Economics, EarlyView.
Abstract Preferential trade agreements (PTAs) contain various non‐tariff provisions, yet identifying their trade effects remains challenging because these commitments are high‐dimensional and strongly correlated within agreements. We estimated a theory‐consistent structural gravity model with domestic flows for 26 agricultural subsectors over 1988–2017
Dongin Kim, Sandro Steinbach
wiley   +1 more source

Da construção identitária a uma trama de diferenças – Um olhar sobre as literaturas de língua portuguesa

open access: yesRevista Crítica de Ciências Sociais, 2005
Starting from an overview of Afro-Luso-Brazilian literary productions, this essay discusses the question of the Portuguese language, its expansion and the web of differences that it encompasses. In order to achieve this broader goal, the author addresses
Laura Cavalcante Padilha
doaj   +1 more source

Immigration detention centers as torturing environments: Ethical reckonings, radical refusals, and implications for a psychology of resistance

open access: yesAmerican Journal of Community Psychology, EarlyView.
Abstract This paper examines psychologists' ethical dilemmas in immigration detention centers. Using critical psychology, border, and detention scholarship, it highlights psychologists' historical complicity in state violence, from the U.S. Enhanced Interrogation Program to current border regimes.
Francesca Esposito   +6 more
wiley   +1 more source

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