Results 201 to 210 of about 25,460 (262)

The MadQCI Cloud Scenario: Quantum as a Service. [PDF]

open access: yesEntropy (Basel)
Buruaga JS   +6 more
europepmc   +1 more source

Delayed Halide‐Rich Molecular Passivation of CsPbCl3 Perovskite Nanocrystals Enables Bright Violet Light‐Emitting Diodes

open access: yesAngewandte Chemie, EarlyView.
POCl3 enables delayed dual passivation in CsPbCl3 nanocrystals by slowly releasing Cl‐containing and phosphonic species that heal halide vacancies and Pb‐related defects over time. This self‐healing boosts PLQY by >40‐fold, preserves efficient violet emission for over 2 months in air, and yields a record 409 cd m−2 luminance for CsPbCl3 violet LEDs ...
Nadesh Fiuza‐Maneiro   +14 more
wiley   +2 more sources

Radical‐Based On‐Surface Transformation of Nonplanar Aromatics Into Nonbenzenoid Nanographenes

open access: yesAngewandte Chemie, EarlyView.
Formation of radicals in nonplanar hydrocarbons through thermally induced dehydrogenation leads to molecular transformation via intramolecular radical‐based cyclization and dimerization, leading to formation of nonbenzenoid nanographenes. ABSTRACT On‐surface synthesis has emerged as a powerful tool for atomically precise C─C bond formation, enabling ...
Daniel Rothhardt   +8 more
wiley   +2 more sources

Steric Hindrance and Secondary Interactions Govern Reconfiguration Between Two Complex CuI Coordination Cages

open access: yesAngewandte Chemie, EarlyView.
Fine‐tuning steric and C─H···π contacts directs assembly of two CuI cages. An identical naphthylene‐based subcomponent forms a [CuI12L6]12+ pseudo‐hexagonal prism stabilized by 29–32 C─H···π contacts and 12 arene stacking pairs with 6‐methyl‐2‐formylpyridine, whereas the 3‐methyl analog imparts steric clashes, yielding a [CuI8L4]8+ open prism ...
Houyang Xu   +3 more
wiley   +2 more sources

Strategies Toward Accessing Enantioenriched (Hetero)Benzo‐Fused 5‐ and 6‐ Membered Rings via Intermolecular Carbometalation

open access: yesAngewandte Chemie, EarlyView.
The use of transition‐metal catalysts and design of chiral ligands have allowed chemists to access highly functionalized benzofused 5‐ and 6‐ membered rings in high yield and enantioselectivity. A common strategy used relies on an intermolecular carbometalation across alkynes and olefins, usually followed by a subsequent intramolecular carbometalation.
Clara Jans   +3 more
wiley   +2 more sources

Self‐Limiting Polymerization‐Induced Crystallization‐Driven Self‐Assembly (SL‐PI‐CDSA) Enables Templated Synthesis of Chiral Plasmonic, Hybrid 2D Hexagonal Assemblies

open access: yesAngewandte Chemie, EarlyView.
This work details the rapid generation (t ≤ 5 min) of size‐tunable, ultralow dispersity (Ð ≤ 1.01) 2D hexagonal nanosheets by self‐limiting polymerization‐induced crystallization‐driven self‐assembly (SL‐PI‐CDSA) of modular and templating poly(aryl isocyanide) block copolymers, with functions that permit post‐polymerization modifications. Specifically,
Randall A. Scanga   +13 more
wiley   +2 more sources

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