Results 31 to 40 of about 79 (63)
Development of a Double Allylboration Reagent Targeting 1,5-syn-(E)-Diols: Application to the Synthesis of the C(23)-C(40) Fragment of Tetrafibricin. [PDF]
Nuhant P +4 more
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Construction of the Bicyclic Carbon Framework of Euphosalicin. [PDF]
Schachamayr D +4 more
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Allylation of aldehydes with potassium allyltrifluoroborate catalyzed by Amberlyst A-15
Tetrahedron, 2013Abstract The use of the commercially available resin Amberlyst-15 as catalyst for allylation of aldehydes by potassium allyltrifluoroborate is described. The method features the use of a commercially available catalyst, aqueous media, and the products were obtained in high yields, short reaction times, at room temperature and no further purification.
Tulio R Couto +2 more
exaly +2 more sources
Journal of Organic Chemistry, 2013
The double allylboration of nitriles and acid anhydrides to form bis-allyl amines and esters, respectively, can be achieved through the use of potassium allyltrifluoroborate in the presence of boron trifluoride etherate at room temperature. The method described is relatively mild, exhibits chemoselectivity to other electrophiles present, avoids the use
Robert Batey, Timothy R Ramadhar
exaly +3 more sources
The double allylboration of nitriles and acid anhydrides to form bis-allyl amines and esters, respectively, can be achieved through the use of potassium allyltrifluoroborate in the presence of boron trifluoride etherate at room temperature. The method described is relatively mild, exhibits chemoselectivity to other electrophiles present, avoids the use
Robert Batey, Timothy R Ramadhar
exaly +3 more sources
Organic Letters, 2010
A practical method for the chemo- and diastereoselective allylation of α,β-epoxy ketones has been developed by using the convenient air and moisture stable reagent potassium allyltrifluoroborate. Indium metal was found to promote addition in stoichiometric or catalytic amounts, to afford α,β-epoxyhomoallylic tertiary alcohols in high yields and ...
Robert Batey, John Janetzko
exaly +3 more sources
A practical method for the chemo- and diastereoselective allylation of α,β-epoxy ketones has been developed by using the convenient air and moisture stable reagent potassium allyltrifluoroborate. Indium metal was found to promote addition in stoichiometric or catalytic amounts, to afford α,β-epoxyhomoallylic tertiary alcohols in high yields and ...
Robert Batey, John Janetzko
exaly +3 more sources
Synthesis of allyl sulfones from potassium allyltrifluoroborates
Tetrahedron Letters, 2017Abstract Potassium allyltrifluoroborates underwent a bora-ene reaction with sulfur dioxide in the absence of Lewis acid catalysts to give sulfinyloxy-trifluoroborates, which subsequently undergo alkylation with electrophiles to produce sulfones in up to 91% yield.
Agnese Stikute +2 more
openaire +1 more source
ChemInform, 2013
AbstractThe title reaction is advantageous with respect to short reaction times, high yields, mild reaction conditions, and simple product isolation.
Tulio R. Couto +4 more
openaire +1 more source
AbstractThe title reaction is advantageous with respect to short reaction times, high yields, mild reaction conditions, and simple product isolation.
Tulio R. Couto +4 more
openaire +1 more source
ChemInform, 2014
AbstractThe asymmetric reaction of different types of cyclic imines with a range of allyltrifluoroborates is described using a rhodium complex catalyst having a chiral bicyclic diene as ligand.
Hamish B. Hepburn +3 more
openaire +1 more source
AbstractThe asymmetric reaction of different types of cyclic imines with a range of allyltrifluoroborates is described using a rhodium complex catalyst having a chiral bicyclic diene as ligand.
Hamish B. Hepburn +3 more
openaire +1 more source
ChemInform, 2013
AbstractThe reaction is advantageous with regards to short times, high yields, and reusability of the heterogeneous catalyst.
Juliano C. R. Freitas +6 more
openaire +1 more source
AbstractThe reaction is advantageous with regards to short times, high yields, and reusability of the heterogeneous catalyst.
Juliano C. R. Freitas +6 more
openaire +1 more source

