Results 31 to 40 of about 79 (63)

Construction of the Bicyclic Carbon Framework of Euphosalicin. [PDF]

open access: yesJ Org Chem
Schachamayr D   +4 more
europepmc   +1 more source
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Allylation of aldehydes with potassium allyltrifluoroborate catalyzed by Amberlyst A-15

Tetrahedron, 2013
Abstract The use of the commercially available resin Amberlyst-15 as catalyst for allylation of aldehydes by potassium allyltrifluoroborate is described. The method features the use of a commercially available catalyst, aqueous media, and the products were obtained in high yields, short reaction times, at room temperature and no further purification.
Tulio R Couto   +2 more
exaly   +2 more sources

Mild Double Allylboration Reactions of Nitriles and Acid Anhydrides Using Potassium Allyltrifluoroborate

Journal of Organic Chemistry, 2013
The double allylboration of nitriles and acid anhydrides to form bis-allyl amines and esters, respectively, can be achieved through the use of potassium allyltrifluoroborate in the presence of boron trifluoride etherate at room temperature. The method described is relatively mild, exhibits chemoselectivity to other electrophiles present, avoids the use
Robert Batey, Timothy R Ramadhar
exaly   +3 more sources

Indium-Promoted Chemo- and Diastereoselective Allylation of α,β-Epoxy Ketones with Potassium Allyltrifluoroborate

Organic Letters, 2010
A practical method for the chemo- and diastereoselective allylation of α,β-epoxy ketones has been developed by using the convenient air and moisture stable reagent potassium allyltrifluoroborate. Indium metal was found to promote addition in stoichiometric or catalytic amounts, to afford α,β-epoxyhomoallylic tertiary alcohols in high yields and ...
Robert Batey, John Janetzko
exaly   +3 more sources

Synthesis of allyl sulfones from potassium allyltrifluoroborates

Tetrahedron Letters, 2017
Abstract Potassium allyltrifluoroborates underwent a bora-ene reaction with sulfur dioxide in the absence of Lewis acid catalysts to give sulfinyloxy-trifluoroborates, which subsequently undergo alkylation with electrophiles to produce sulfones in up to 91% yield.
Agnese Stikute   +2 more
openaire   +1 more source

ChemInform Abstract: Allylation of Aldehydes with Potassium Allyltrifluoroborate Catalyzed by Amberlyst A‐15.

ChemInform, 2013
AbstractThe title reaction is advantageous with respect to short reaction times, high yields, mild reaction conditions, and simple product isolation.
Tulio R. Couto   +4 more
openaire   +1 more source

ChemInform Abstract: Enantioselective Rhodium‐Catalyzed Allylation of Cyclic Imines with Potassium Allyltrifluoroborates.

ChemInform, 2014
AbstractThe asymmetric reaction of different types of cyclic imines with a range of allyltrifluoroborates is described using a rhodium complex catalyst having a chiral bicyclic diene as ligand.
Hamish B. Hepburn   +3 more
openaire   +1 more source

ChemInform Abstract: Allylation of Aldehydes with Potassium Allyltrifluoroborate Catalyzed by Lanthanide‐Based Metal‐Organic Framework.

ChemInform, 2013
AbstractThe reaction is advantageous with regards to short times, high yields, and reusability of the heterogeneous catalyst.
Juliano C. R. Freitas   +6 more
openaire   +1 more source

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