Results 231 to 240 of about 202,127,633 (309)

Bridging Chemical Literature and Molecular Graphs: LLM‐Augmented Enantioselectivity Prediction for Iridium‐Catalyzed Asymmetric C–H Borylation

open access: yesAdvanced Science, EarlyView.
A machine‐learning framework for asymmetric C–H borylation bridges multi‐entity 3D molecular graphs and chemical literature. Atom‐resolved mechanistic annotations extracted by large language models augment three‐component graph encoding of catalyst, substrate, and product. The model predicts enantioselectivity with high accuracy on unseen scaffolds and
Zhe Wang   +4 more
wiley   +1 more source

Soil fertility controls on tropical forest productivity and mortality: synthesis and roadmap. [PDF]

open access: yesNew Phytol
Wong MY   +26 more
europepmc   +1 more source

Cellular Mechanisms Enabling Mitochondria Transfer and Transplantation

open access: yesAdvanced Science, EarlyView.
Mitochondrial transfer and transplantation (mitoTT) is examined as a multistep process governed by distinct transfer routes and post‐transfer checkpoints. Mechanisms controlling mitochondrial uptake, network integration, cristae remodeling, mtDNA maintenance, immune sensing, and quality control are highlighted, revealing key biological and ...
F. Seyma Gokdemir   +3 more
wiley   +1 more source

Molecular Electrocatalysis Coupled With a Palladium Membrane Reactor Affords Selective Nitrogen Reduction

open access: yesAdvanced Science, EarlyView.
A palladium membrane reactor delivers active hydrogen to homogeneous nickel terpyridine catalysts, which then selectively hydrogenate dinitrogen to ammonia. ABSTRACT Ammonia production is a cornerstone of modern industry and society, yet the conventional Haber–Bosch process accounts for nearly 2% of the global CO2 emissions. A promising and potentially
Morgan McKee   +11 more
wiley   +1 more source

Coordination‐Asymmetry‐Regulated Reconstruction of Electron‐Rich Cu Sites for pH‐Dependent Nitrate‐to‐Ammonia Electrocatalysis

open access: yesAdvanced Science, EarlyView.
Distinct initial Cu coordination environments drive different pH‐dependent structural evolution pathways, resulting in divergent nitrate reduction activity and behavior. ABSTRACT Electrocatalytic nitrate reduction reaction (e‐NO3RR) offers a promising route to valorize nitrate‐contaminated wastewater while enabling sustainable ammonia production ...
Shih‐Ching Huang   +11 more
wiley   +1 more source

Elevated CO<sub>2</sub> reinforces PT11-dependent symbiotic phosphate uptake to reprogram root nutrient acquisition in rice. [PDF]

open access: yesProc Natl Acad Sci U S A
Chiu CH   +7 more
europepmc   +1 more source

Electron‐Rich Nickel Enabled by Charge Transfer in Multimetal Nanostructures for Efficient Ammonia‐to‐Hydrogen Conversion

open access: yesAdvanced Science, EarlyView.
A charge‐transfer‐engineered Ni catalyst derived from an atomically mixed layered precursor enables efficient ammonia‐to‐hydrogen conversion. Cr‐to‐Ni electron transfer creates electron‐rich Ni active sites that favor NH3 adsorption, modify the dehydrogenation energetics, and weaken N2 binding to facilitate product desorption. This electronically tuned
Donghyeok Kim   +9 more
wiley   +1 more source

Planta Centennial editorial. [PDF]

open access: yesPlanta
Bartels D, Cheng MHK, de Folter S.
europepmc   +1 more source

Sustainable Hydrogel‐Forming Microneedle‐Reservoir Patches for Transdermal Delivery of Hydrophilic Macromolecules: Biopolymers, Green Manufacturing and Translation

open access: yesAdvanced Science, EarlyView.
Hydrogel‐forming microneedle (HFMN)‐reservoir patches provide a modular route for controlled transdermal delivery of hydrophilic biomacromolecules. The platform integrates skin‐barrier penetration, sustainable biopolymers, scalable green manufacturing, hydration‐driven transport, model‐cargo validation, and translational quality requirements.
Siddharth Mohanty   +4 more
wiley   +1 more source

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