Results 91 to 100 of about 8,250 (257)

Synthesis of a π‐Extended Phenazine Diimide Derivative and Characterization of Its Closed‐Shell Reduced States

open access: yesChemistry – A European Journal, EarlyView.
In this work, the synthesis and characterization of novel π‐extended phenazine diimides is reported. The derivatives undergo differential reduction to a dihydrophenazine or Meisenheimer form depending on the reaction conditions employed. The outcome of this work highlights the paramount importance of structural design in determining the nature of the ...
Francesco Rigodanza   +7 more
wiley   +1 more source

Enantioselectivity in Transition Metal Catalyzed Propargylic Substitution Reactions: A Theoretical Perspective

open access: yesChemistry – A European Journal, EarlyView.
Recent theoretical efforts to elucidate the origin of enantioselectivity in transition metal‐catalyzed propargylic substitution reactions are highlighted in this review. ABSTRACT In recent years, asymmetric catalytic propargylic substitution reactions have undergone remarkable development, enabling the construction of chiral carbon centers adjacent to ...
Ken Sakata, Yoshiaki Nishibayashi
wiley   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Xylose Acetals ‐ a New Class of Sustainable Solvents and Their Application in Enzymatic Polycondensation

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Novel organic solvents with an unmodified carbohydrate core were synthesised both from D‐xylose and directly from biomass and were successfully used as reaction media for lipase biocatalysts to synthesise aliphatic and aromatic polyesters. Abstract The use of organic solvents in academic research and industry applications is facing increasing ...
Anastasia O. Komarova   +8 more
wiley   +1 more source

Brønsted acidity of H-adatoms at protic solvent-transition metal interfaces and its kinetic consequences in electrophilic addition reactions

open access: green, 2021
Junnan Shangguan   +6 more
openalex   +2 more sources

Efficient Conductivity Enhancement of Flexible Polyaniline Films Induced by Ultrafast Photoexcitation

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work uses ultrafast photoexcitation to enhance doped polyaniline films' conductivity and transistor transconductance. Polyaniline (PANI) exhibits remarkable electrical conductivity and mechanical flexibility, rendering it widely applicable in flexible electronic devices.
Jiawei Li   +10 more
wiley   +1 more source

Structural Design of MOF‐Based and MOF‐Derived Composites for Oxygen Evolution Electrocatalysis: Materials Innovation for Energy and Environmental Sustainability

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review provides an overview of recent developments in metal organic framework (MOF)‐based and MOF‐derived composites for efficient oxygen evolution reaction. This review also emphasizes the structural design of electrocatalyst, active site optimization, and emerging prospects of their use in practical electrolyzer systems.
Bhagyashri B. Kamble   +7 more
wiley   +1 more source

SOLVATOCHROMISM OF ASYMMETRICAL SUBSTITUTED 3,7-DIAMINOPHENOTHIAZINIUM DYE

open access: yesStudia Universitatis Babes-Bolyai Chemia, 2015
A convenient procedure for the synthesis of 3-diethylamino-7-phenylaminophenothiazin-5-ium iodide was developed and the solvatochromism of this blue dye was examined by means of UV-Vis spectroscopy.
Camelia CIOBOTARIU   +2 more
doaj  

Organic–Inorganic Composite Nanofibers Based on YSZ Nanofibers Anchored PANI/SnS2 Heterojunction for Flexible Room Temperature NO2 Sensor

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel organic–inorganic YSZ@PANI/SnS2 composite nanofiber film was prepared via an in‐situ construction strategy of a PANI interfacial layer. The biomimetic "branch‐leaf" structure effectively disperses and releases stress and energy, while accelerating gas diffusion/transport and providing abundant active sites.
Han Zhang   +7 more
wiley   +1 more source

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