Results 71 to 80 of about 26,002 (260)

Steering Oxygen Activation Pathways via Redox Dual‐Defects in 2D Hydrated WO3 for High‐Yield Singlet Oxygen Evolution

Advanced Functional Materials, EarlyView.
Redox dual‐defects (Cs substitution and O vacancies) in 2D hydrated WO3 steer O2 activation toward selective singlet oxygen evolution. WO‐CO achieves 8.6–15.8 times higher 1O2 production than single‐defect or pristine catalysts, enabling efficient pollutant mineralization via a pathway‐selective photocatalytic mechanism.
Sheng‐Qi Guo, Mingqi Xiao, Fangyuan Zhang, Hui Li, Yuli Jia, Zhenfang Zhang, Liqun Ye, Bo Yang, Tianyi Ma   +8 more
wiley   +1 more source

Bandgap‐Engineered AlGaAs/GaAs Heterostructures for Wavelength‐Selective Dual‐Polarity Photoelectrochemistry

Advanced Functional Materials, EarlyView.
Bandgap‐engineered AlGaAs/GaAs heterostructures exhibit wavelength‐selective dual‐polarity photoelectrochemistry, switching from photocathodic to photoanodic response depending on excitation wavelength. The polarity transition is governed by band‐selective absorption, built‐in electric‐field‐driven carrier transport, and interfacial charge‐transfer ...
Yukai Mao, Lipin Chen, Jules Courtin, Siyu Lin, Gangri Cai, Yan Zhu, Yoan Léger, Nicolas Bertru, Jinshi Zhao, Charles Cornet   +9 more
wiley   +1 more source

Multilayer Casting Strategy for Enhanced Cation Contamination Resistance in Proton Exchange Membranes

Electron
The proton exchange membrane (PEM) is critical for the operation of proton exchange membrane fuel cells (PEMFCs). However, cationic impurities (e.g., Ca2+ and Mg2+) in water or the environment readily bind to the PEM's sulfonic acid groups (−SO3H ...
Haodong Xie, Yunfa Dong, Shijie Zhong, Yupei Han, Quan Li, Jiecai Han, Weidong He   +6 more
doaj   +1 more source

Novel composite Nafion membranes modified with copper phthalocyanine tetrasulfonic acid tetrasodium salt for fuel cell application

Journal of Materiomics, 2019
In this paper, Nafion membrane was firstly modified by copper phthalocyanine tetrasulfonic acid tetrasodium salt (CuTSPc) to prepare the Nafion/CuTSPc-x composite membranes.
Yanan Wei, Tianhua Qian, Jiawen Liu, Xaojing Guo, Qiaojuan Gong, Zhaorong Liu, Binglun Tian, Jinli Qiao   +7 more
doaj   +1 more source

Myrcene‐Based Tailored Co‐Polymers as Active Pharmaceutical Excipients: Bio‐Based Solutions for Mucoadhesive Excipients

Advanced Functional Materials, EarlyView.
Mucoadhesive amphiphilic block and statistical copolymers were synthesized via Reversible Addition–Fragmentation Chain Transfer polymerization from bio‐sourced myrcene and polyethylene glycol methacrylate. The resulting polymers exhibit narrow molar‐mass distributions, high regioselectivity, well‐defined microstructures, and tend to self‐assemble into ...
David Gintsburg, Selin Görkem Sari, Lana Molnar, Annabelle Knoll, Effrosyni‐Maria Kosti, Anna Seybold, Gozde Deveci, Nico Bruns, Andreas Bernkop‐Schnürch, Gergely Kali   +9 more
wiley   +1 more source

Engineering MnNiPx Cathode via Dual Role of Mn: Simultaneous Enhancement of Activity and Intermittent Operation Durability

Advanced Functional Materials, EarlyView.
Engineering MnNiPx cathodes through the dual role of Mn simultaneously improves hydrogen evolution reaction activity and intermittent‐operation durability. Mn preferentially oxidizes to protect Ni–P sites from irreversible oxidation, while metallic Mn incorporation enhances the HER kinetics of Ni–P active layer.
Ik‐Sun Kim, Jungwoo Choi, Sechan Lee, Jung Eun Park, Changsoo Lee, Jongsu Seo, Ji Hee Kwon, Gisu Doo, Hyeonjung Park, Dongju Lee, Won‐Chul Cho, Changhee Kim, Nosang Vincent Myung, Sang Soo Han, Byeong‐Seon An, MinJoong Kim, Hyun‐Seok Cho   +16 more
wiley   +1 more source

An effective strategy to enhance phosphoric acid retention and proton conductivity stability: Construction of proton transfer channels with starch rather than H3PO4

Polymer Testing
To enhance the phosphoric acid (PA) retention as well as maintain high proton conductivity of phosphoric acid doped proton exchange membranes at high temperature, we successfully design a series of phosphoric acid doped biobased composite membranes by ...
Xiuping Li, Jiyuan Zhang, Xiao Zhang, Xiudong Liu, Shuhua Chen, Yue Qiao, Qian Li, Cheng Liu   +7 more
doaj   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

Advanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler, Lucía Vizcaíno‐Anaya, Ahmad Tayyebi, José Manuel Vila‐Fungueiriño, María del Carmen Giménez‐López   +4 more
wiley   +1 more source

Pressure-induced amorphization of a dense coordination polymer and its impact on proton conductivity

APL Materials, 2014
The proton conductivity of a dense coordination polymer (CP) was investigated under high-pressure conditions. Impedance measurements under high pressures revealed that the proton conductivity of the CP decreased more than 1000-fold at pressures of 3–7 ...
Daiki Umeyama, Satoshi Horike, Cedric Tassel, Hiroshi Kageyama, Yuji Higo, Keisuke Hagi, Naoki Ogiwara, Susumu Kitagawa   +7 more
doaj   +1 more source

Nano‐Scale Characterization of Impurities Segregation in Solid Oxide Electrolysis Cells

Advanced Functional Materials, EarlyView.
Cathodic polarization induces impurity segregation in Ni, forming an amorphous Na─Al─Si─O amorphous phase at grain boundaries. Under ultralow oxygen partial pressure, multiple elements dissolve, migrate, and reoxidize within the metal. A patterned model system provides direct nanoscale evidence, clarifying the mechanism of polarization‐driven impurity ...
Zhongtao Ma, Qingjie Wang, Bowen Li, Vasileios Bilalis, Søren Bredmose Simonsen, Ming Chen   +5 more
wiley   +1 more source