Results 31 to 40 of about 112,578 (285)

Synthesis, Characterization and Protonation Behavior of Quinoxaline-Fused Porphycenes

open access: yesMolecules, 2017
9,10-Quinoxaline-fused porphycenes 1a-H2 and 1b-H2 were synthesized by intramolecular McMurry coupling. As a result of the annulation of the quinoxaline moiety on the porphycene skeleton, 1a-H2 and 1b-H2 display absorption and fluorescence in the near ...
Daiki Kuzuhara   +5 more
doaj   +1 more source

A gated strategy stabilizes room‐temperature phosphorescence

open access: yesAggregate, 2023
Room‐temperature phosphorescence (RTP) of purely organic materials is easily quenched with unexpected purposes because the excited triplet state is extremely susceptible to external stimuli.
Kaizhi Gu   +7 more
doaj   +1 more source

Protonation-Induced Sign Inversion of the Cotton Effects of Pyridinophanes. A Combined Experimental and Theoretical Study

open access: yes, 2017
The circular dichroisms (CDs) of planar chiral [2.2]- and [3.3]-pyridinophanes were investigated experimentally and theoretically. Strong multisignate Cotton effects, typical for cyclophane derivatives, were observed.
Akinori Shimizu (281584)   +2 more
core   +1 more source

Direct observation of the potential dependent protonation of 4-(Dimethylamino)pyridine on gold electrodes [PDF]

open access: yes, 2023
The pyridine derivative, 4-(dimethylamino)pyridine (DMAP), is important in a surprisingly wide variety of applications spanning chemical, biological and technological domains.
Richard Kramer, Campen   +2 more
core   +2 more sources

Role of Thr82 for the unique photochemistry of TAT rhodopsin

open access: yesBiophysics and Physicobiology, 2021
Marine bacterial TAT rhodopsin possesses the pKa of the retinal Schiff base, the chromophore, at neutral pH, and photoexcitation of the visible protonated state forms the isomerized 13-cis state, but reverts to the original state within 10–5 sec.
Teppei Sugimoto   +2 more
doaj   +1 more source

Protonation-Induced Charge Transfer and Polaron Formation in Organic Semiconductors Doped by Lewis Acids [PDF]

open access: yes, 2022
Lewis acid doping of organic semiconductors (OSCs) opens up new ways of p-type doping and has recently become of significant interest. As for the mechanistic understanding, it was recently proposed that upon protonation of the OSC backbone, electron ...
Fabian, Bauch   +2 more
core   +1 more source

Proton-proton Bremsstrahlung

open access: yesNuclear Physics B, 1967
Abstract We calculate proton-proton Bremsstrahlung cross sections using the Tabakin separable potentials to generate off-shell nucleon-nucleon t-matrix elements in low partial waves and off-shell one-pion-exchange amplitudes for the higher partial waves.
W.A. Pearce, W.A. Gale, I.M. Duck
openaire   +2 more sources

Potentiometric Studies on the Protonation Constants and Protonation Energies of Some Diamines in Methanol + Water Mixtures

open access: yesE-Journal of Chemistry, 2007
The protonation constants of diamines such as ethylenediamine, 1,2-diaminopropane, 1,3-diaminopropane, o-phenylenediamine, m-phenylene-diamine, p-phenylenediamine were determined on the basis of Bjerrum and Calvin method in methanol-water mixtures.
Sangita Sharma   +4 more
doaj   +1 more source

Social Functioning Within the First Years After Pediatric Brain Tumor Diagnosis and the Relationship With Family Psychosocial Risk

open access: yesPediatric Blood &Cancer, EarlyView.
ABSTRACT Background Survivors of pediatric brain tumors (PBTs) can experience long‐term social difficulties, impacting quality of life. Beyond medical and environmental factors, family psychosocial risk may play a role in social outcomes by shaping the caregiving environment and may provide intervention options.
Renske H. Houben   +4 more
wiley   +1 more source

Chemotherapy for Spinal Cord Intramedullary Pediatric Low‐Grade Glioma—A Systematic Literature Review

open access: yesPediatric Blood &Cancer, EarlyView.
ABSTRACT Pediatric intramedullary low‐grade gliomas (PIMLGGs) are rare neoplasms that present unique clinical and management challenges. Although surgery remains the primary tool for tissue diagnosis and decompression, complete gross‐total resection is frequently unfeasible due to the infiltrative nature of these lesions.
Olga M. Sergeenko   +5 more
wiley   +1 more source

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