Results 11 to 20 of about 26,347 (256)

A study of the behaviour of some substituted 1,2,4-triazoline-3-thiones in different media [PDF]

open access: yesJournal of the Serbian Chemical Society, 2000
The acid-base behaviour of 4-phenyl-5-(4-R-benzyl)-1,2,4-triazoline-3-thione (1(R = OH); 2(R = OC2H5)) was studied in aqueous sulfuric acid and sodium hydroxide solutions.
Arman-Zubić Lučijana   +2 more
doaj   +3 more sources

Proton number fluctuations in partial chemical equilibrium [PDF]

open access: yesPhysical Review C, 2021
We calculate volume-independent ratios of cumulants of the net-proton number distribution up to sixth order in a fireball that cools down after the chemical freeze-out. A hadron resonance gas model is used together with the assumption of partial chemical equilibrium, which fixes the number of observed stable hadrons after the chemical freeze-out. It is
Boris Tomášik   +2 more
openaire   +2 more sources

Protonation of apolar species: From Cl2H+ to (E)-NCCHCHCNH+ through computational investigations

open access: yesFrontiers in Astronomy and Space Sciences, 2023
Radioastronomy is a powerful tool for the discovery of molecules in space but it requires molecular species to be polar. The observation of apolar species can be however enabled by protonation, which occurs from reaction with the abundant H3+ ion ...
Silvia Alessandrini   +3 more
doaj   +1 more source

Acid–base equilibria of the Zn(II) and Fe(III) complexes with condensation products of 2-acetylpyridine and the dihydrazide of oxalic and malonic acid [PDF]

open access: yesJournal of the Serbian Chemical Society, 2009
Acid–base equilibria of Zn(II) and Fe(III) complexes with N',N'2-bis[(1E)-1-(2-pyridyl)ethylidene]ethanedihydrazide (ligand L1) and N',N'2-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide (ligand L2), i.e., [Fe(L1)Cl2(H2O)], [Fe(L2)Cl(H2O)]2+, [Zn(L1)(
DUŠAN SLADIĆ   +6 more
doaj   +3 more sources

Kelvin–Helmholtz Instability at Proton Scales with an Exact Kinetic Equilibrium [PDF]

open access: yesThe Astrophysical Journal, 2020
Abstract The Kelvin–Helmholtz instability (KHI) is a ubiquitous physical process in ordinary fluids and plasmas, frequently observed also in space environments. In this paper, kinetic effects at proton scales in the nonlinear and turbulent stage of the KHI have been studied in magnetized collisionless plasmas by means of hybrid Vlasov ...
A. Settino   +5 more
openaire   +4 more sources

On the mechanism of chloroquine resistance in Plasmodium falciparum. [PDF]

open access: yesPLoS ONE, 2010
Resistance to chloroquine of malaria strains is known to be associated with a parasite protein named PfCRT, the mutated form of which is able to reduce chloroquine accumulation in the digestive vacuole of the pathogen.
Mauro Chinappi   +3 more
doaj   +1 more source

Protonation Equilibria of Biologically Active Ligands in Mixed Aqueous Organic Solvents

open access: yesBioinorganic Chemistry and Applications, 2014
The review is mainly concerned with the protonation equilibria of biologically active ligands like amino acids, peptides, DNA constituents, and amino acid esters in nonaqueous media.
Ahmed A. El-Sherif   +3 more
doaj   +1 more source

Potentiometric Studies on the Protonation Constants and Protonation Energies of Some Diamines in Methanol + Water Mixtures

open access: yesE-Journal of Chemistry, 2007
The protonation constants of diamines such as ethylenediamine, 1,2-diaminopropane, 1,3-diaminopropane, o-phenylenediamine, m-phenylene-diamine, p-phenylenediamine were determined on the basis of Bjerrum and Calvin method in methanol-water mixtures.
Sangita Sharma   +4 more
doaj   +1 more source

Molecular Synchronization Enhances Molecular Interactions: An Explanatory Note of Pressure Effects

open access: yesCrystals, 2018
In this study, we investigated a unique aspect of the supramolecular polymerization of tetrakis (4-sulfonatophenyl) porphyrin (TPPS), a self-assembling porphyrin, under non-equilibrium conditions by subtracting the effects of back-pressure on its ...
Munenori Numata, Chisako Kanzaki
doaj   +1 more source

Tautomeric equilibrium, proton affinity and mass spectrometry fragmentation of flexible hydrogen-bonded precursors and rigid $$\hbox {N}\longrightarrow \hbox {BF}_2$$ N ⟶ BF 2 fluorescent dyes

open access: yesScientific Reports, 2021
The stability of two groups of conformationally locked molecules, similar in topology, but differing only by the type of the bridge rigidifying their structure, is studied.
Małgorzata A. Kaczorowska   +2 more
doaj   +1 more source

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