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Protonation Equilibrium of 4-Substituted Benzohydroxamic Acids in Mineral Acids

The Journal of Organic Chemistry, 1999
The protonation equilibria of some 4-substituted benzohydroxamic acids 4-X(C(6)H(4)CONHOH) (X = H, OMe, Cl) have been investigated in aqueous sulfuric, perchloric, and hydrochloric acids at 25 degrees C UV spectrophotometrically. The Hammett acidity function method, the Bunnett-Olsen method, Cox-Yates excess acidity function method, and Marziano-Cimino-
Kallol K., Ghosh   +2 more
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Equilibrium ratios of protonated cations derived from N-alkylpiperidines and non-equilibrium ratios obtained by rapid ‘irreversible’ protonation with trifluoroacetic acid

J. Chem. Soc. B, 1969
Configurational equilibria for a range of N-alkylpiperidine hydrochlorides in deuterium oxide or deuteriochloroform have been examined by n.m.r. spectroscopy. Where comparison with equilibria in analogous cyclohexane systems is possible, higher proportions of the less stable configurations are observed in the hydrochloride solutions.
J. McKenna, J. M. McKenna
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Metal-proton equilibrium relations in a chelating iminodiacetic resin

Industrial & Engineering Chemistry Research, 1992
A model of equilibrium including the pH effect was proposed and tested with experimental data of the Na-H-metal systems onto chelating resins. The protonation constants were used to calculate the complexing capacity of the metals Cu, Ni, Co, and Zn in the iminodiacetic type resin.
Federico Mijangos, Mario Diaz
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Equilibrium structures, proton affinities, and ionization potentials of the fluoroacetones

Canadian Journal of Chemistry, 1985
Theoretical calculations on the fluoroacetones and their conjugate acids exhibit an inverse dependence of the proton affinity on the number of fluorine substituents. The good correlation between increasing proton affinity and decreasing ionization potential is attributed to the observation that the ionization of a nonbonding electron is essentially ...
Sai Cheng Choi, Russell J. Boyd
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Effect of the protonation equilibrium on the interaction of mixed micelles with their counterions

Colloid & Polymer Science, 1999
Ionic/nonionic mixed micelle formation of dodecyldimethylamine oxide (DDAO) was studied by measuring the activities of DDAO+ ions and Cl− ions using surfactant-selective electrodes and Ag/AgCl electrodes at three pH values in the absence of added salt.
H. Katsuura   +3 more
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Protonation Effects on the Equilibrium and Dynamical Properties of the Alanine Tetrapeptide

The Journal of Physical Chemistry B, 1997
The effect of terminal group charge on the structure and dynamics of the alanine tetrapeptide has been investigated using molecular dynamics simulations.
Herb D. Blatt   +2 more
openaire   +1 more source

Non-Equilibrium Proton Gradients for Photoenergy Conversion

ACS Applied Energy Materials
Biological systems use proton gradients to convert light into chemical potential with remarkable efficiency, offering a blueprint for synthetic approaches to light-to-ionic energy conversion. Inspired by this principle, light-responsive molecular switches have emerged as key building blocks for artificial systems that generate and sustain proton ...
Xinchen Dai   +7 more
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Electrochemical reactions with protonations at equilibrium

Journal of Electroanalytical Chemistry, 1992
R. Meunier-Prest, E. Laviron
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Equilibrium structure of equatorially mirroring radiation belt protons

Journal of Geophysical Research, 1977
The average quiet time structure of energetic radiation belt protons can be explained as an equilibrium balance among radial diffusive transport from a proton source located just within the first closed field lines, losses due to Coulomb collisions, and charge exchange with the ambient neutral hydrogen geocorona.
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Electrochemical reactions with protonations at equilibrium

Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1983
E. Laviron, L. Roullier
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