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A Pseudo-Second Order Kinetic Equation for Sorption Processes

Russian Journal of Physical Chemistry A, 2020
The problem of substantiating a pseudo-second order equation in the kinetics of sorption processes is considered. A simple way is presented of transforming the Langmuir kinetic equation written for a process within a limited volume into a polynomial relation in the form of the sum of difference terms of first- and second-order kinetic equations.
exaly   +2 more sources

Adsorption kinetics at solid/aqueous solution interfaces: On the boundaries of the pseudo-second order rate equation

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020
Abstract The empirical pseudo-second order rate equation has become the equation of choice to account for adsorption kinetics at solid/aqueous solution interfaces. However, its validity boundaries still remain faint. Here, they are set on the basis of the predictions of the well-established Langmuir model, cast in terms of the relevant kinetic ...
Alberto E Regazzoni
exaly   +2 more sources

Modelling the solid–liquid adsorption processes using artificial neural networks trained by pseudo second order kinetics

Chemical Engineering Journal, 2009
Abstract A three-layer feed forward neural network was constructed and tested to analyze the second order kinetics of solid–liquid adsorption process. The pseudo second order kinetics of auramine O onto activated carbon was used to train the artificial neural network (ANN) to model the sorption system for various operating conditions.
Vasanth Kumar Kannuchamy
exaly   +2 more sources

Dynamic studies and pseudo-second order modeling of copper(II) biosorption onto pine cone powder

Desalination, 2010
Abstract The chemical interaction between biosorbent functional groups and metal ion species in solution can slightly be altered by chemical treatment of biosorbent surface. The biosorbent kinetics and mechanism for copper(II) biosorption onto pine cone powder and 0.15 mol dm − 3 NaOH treated pine cone powder were determined during batch kinetics ...
A.E. Ofomaja, E.B. Naidoo, S.J. Modise
exaly   +2 more sources

Pseudo-second order models for the adsorption of safranin onto activated carbon: Comparison of linear and non-linear regression methods

Journal of Hazardous Materials, 2007
Kinetic experiments were carried out for the sorption of safranin onto activated carbon particles. The kinetic data were fitted to pseudo-second order model of Ho, Sobkowsk and Czerwinski, Blanchard et al. and Ritchie by linear and non-linear regression methods.
exaly   +3 more sources

Second or pseudo-second-order model for adsorption kinetics?

Separation Science and Technology, 2021
Model of second-order (SO) adsorption kinetics from solutions was described and verified for the adsorption of phenol/lead (II) on samples of natural coal and activated carbon.
Boleslav Taraba, Petra Bulavová
openaire   +1 more source

Kinetic and Pseudo-Second-Order Modeling of Lead Biosorption onto Pine Cone Powder

Industrial & Engineering Chemistry Research, 2010
The sorption of lead(II) onto pine cone powder (PCP) and 0.15 mol/L NaOH treated pine cone powder (PCP 0.15), an abundant agricultural waste from the wood industry, was studied to evaluate the effect of NaOH treatment on the kinetics of lead(II) uptake by performing batch kinetic sorption experiments. Batch biosorption kinetics was performed by varying
A. E. Ofomaja   +2 more
openaire   +1 more source

Using of “pseudo-second-order model” in adsorption

Environmental Science and Pollution Research, 2013
A research paper's contribution exists not only in its originality and creativity but also in its continuity and development for research that follows. However, the author easily ignores it. Citation error and quotation error occurred very frequently in a scientific paper.
openaire   +2 more sources

Characteristics of pseudo-second-order kinetic model for liquid-phase adsorption: A mini-review

Chemical Engineering Journal, 2009
Abstract Since the introduction of pseudo-second-order (PSO) model for the description of adsorption kinetics in 1999, it has been widely applied in liquid-phase adsorption systems. An approaching equilibrium factor (Rw) was defined and deduced from the PSO model in this work.
Feng-Chin Wu   +3 more
openaire   +1 more source

Modeling pseudo-second-order kinetics of orange peel-paracetamol adsorption process using artificial neural network

Chemometrics and Intelligent Laboratory Systems, 2020
Abstract In this work, an artificial neural network (ANN) was developed to model the Pseudo- Second Order (PSO) kinetics of orange peel-paracetamol adsorption process. The orange peel used for the adsorption process was prepared, activated, and characterized using Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR ...
Inioluwa Christianah Afolabi   +2 more
openaire   +1 more source

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