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Adsorption kinetics models in clay systems. The critical analysis of pseudo-second order mechanism
Applied Clay Science, 2020Abstract The research topics involving adsorption kinetics of chemical substances on clays and related materials include hundreds of papers over the last decades. In many of them, it is concluded that the adsorption is governed by the so-called pseudo-second order (PSO) mechanism.
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Inorganica Chimica Acta, 1997
Abstract Pseudo second-order Jahn-Teller distortions are proposed to explain why the equatorial hydride ligands in a series of cyclopentadienyl metal polyhydrides (Cp ∗ ReH 6 , Cp ∗ OsH 5 , Cp ∗ IrH 4 ) bend away from the Cp ring at such large angles. Restricted Hartree-Fuck (RHF) geometry optimizations on models of these complexes where the Cp* ring
Craig A. Bayse, Michael B. Hall
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Abstract Pseudo second-order Jahn-Teller distortions are proposed to explain why the equatorial hydride ligands in a series of cyclopentadienyl metal polyhydrides (Cp ∗ ReH 6 , Cp ∗ OsH 5 , Cp ∗ IrH 4 ) bend away from the Cp ring at such large angles. Restricted Hartree-Fuck (RHF) geometry optimizations on models of these complexes where the Cp* ring
Craig A. Bayse, Michael B. Hall
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Industrial & Engineering Chemistry Research, 2018
In this research note, we revisit the pseudo-second-order model for adsorption kinetics, its assumptions, and its application to simulated, random, and published data.
Ye Xiao, Jalel Azaiez, Josephine M. Hill
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In this research note, we revisit the pseudo-second-order model for adsorption kinetics, its assumptions, and its application to simulated, random, and published data.
Ye Xiao, Jalel Azaiez, Josephine M. Hill
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Pseudo-Isotherms Using a Second Order Kinetic Expression Constant [PDF]
Adsorption, 2004 . The kinetics of four sorption systems, Cu/tree fern, Pb/tree fern, AB9/activated clay and BR18/activated clay have been studied based on the assumption of a pseudo-second order rate law. Pseudo-isotherms using the pseudo-second order kinetic expression
Yuh-Shan Ho, Ho Yuh-Shan
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Chemometrics and Intelligent Laboratory Systems, 2020
Abstract In this work, an artificial neural network (ANN) was developed to model the Pseudo- Second Order (PSO) kinetics of orange peel-paracetamol adsorption process. The orange peel used for the adsorption process was prepared, activated, and characterized using Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR ...
Inioluwa Christianah Afolabi +2 more
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Abstract In this work, an artificial neural network (ANN) was developed to model the Pseudo- Second Order (PSO) kinetics of orange peel-paracetamol adsorption process. The orange peel used for the adsorption process was prepared, activated, and characterized using Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR ...
Inioluwa Christianah Afolabi +2 more
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2008 2nd International Conference on Bioinformatics and Biomedical Engineering, 2008
A comparison was made of the linear least-squares method and a nonlinear least-square method of the Langmuir isotherm and pseudo second order kinetic model for the biosorption of methylene blue onto rice husk. The parameters obtained from the linear method and the nonlinear method were different. The error analysis was performed.
Runping Han +6 more
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A comparison was made of the linear least-squares method and a nonlinear least-square method of the Langmuir isotherm and pseudo second order kinetic model for the biosorption of methylene blue onto rice husk. The parameters obtained from the linear method and the nonlinear method were different. The error analysis was performed.
Runping Han +6 more
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World Journal of Microbiology and Biotechnology, 2009
The removal of hexavalent chromium from aqueous solution was studied in batch experiments using dead biomass of three different species of marine Aspergillus after alkali treatment. All the cultures exhibited potential to remove Cr(VI), out of which, Aspergillus niger was found to be the most promising one.
Yasmin Khambhaty +3 more
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The removal of hexavalent chromium from aqueous solution was studied in batch experiments using dead biomass of three different species of marine Aspergillus after alkali treatment. All the cultures exhibited potential to remove Cr(VI), out of which, Aspergillus niger was found to be the most promising one.
Yasmin Khambhaty +3 more
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Sorption kinetics: Obtaining a pseudo-second order rate equation based on a mass balance approach
Journal of Environmental Chemical Engineering, 2014Abstract Various formulations of pseudo second-order rate equations have been widely used in elucidating the rate constants of a wide variety of sorption systems. In this paper, it is shown that a new formulation can be obtained by making use of the mass balance equation of a single stage batch-type system.
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Chemical Engineering Journal, 2009
Abstract A three-layer feed forward neural network was constructed and tested to analyze the second order kinetics of solid–liquid adsorption process. The pseudo second order kinetics of auramine O onto activated carbon was used to train the artificial neural network (ANN) to model the sorption system for various operating conditions.
K. Vasanth Kumar, K. Porkodi
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Abstract A three-layer feed forward neural network was constructed and tested to analyze the second order kinetics of solid–liquid adsorption process. The pseudo second order kinetics of auramine O onto activated carbon was used to train the artificial neural network (ANN) to model the sorption system for various operating conditions.
K. Vasanth Kumar, K. Porkodi
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