Modeling Pyran Formation in the Molybdenum Cofactor: Protonation of Quinoxalyl–Dithiolene Promoting Pyran Cyclization [PDF]
Mononuclear Mo and W enzymes require a unique ligand known as molybdopterin (MPT). This ligand binds the metal through a dithiolene chelate, and the dithiolene bridges a reduced pyranopterin group. Pyran scission and formation have been proposed as a reaction of the MPT ligand that may occur within the enzymes to adjust reactivity at the Mo atom.
Douglas R. Gisewhite +4 more
openaire +2 more sources
Synthesis of Polyfunctionalized 4H‐Pyrans [PDF]
Amberlyst A21 catalyzed one‐pot three‐component coupling of aldehyde and malononitrile with active methylene compounds such as acetylacetone and ethyl acetoacetate for the synthesis of pharmaceutically important polyfunctionalized 4H‐pyrans has been reported. Simple experimental procedure, no chromatographic purification, no hazardous organic solvents,
Manisha Bihani +2 more
openaire +2 more sources
Graphene oxide supported ionic liquid/Fe complex: a robust and highly stable nanocatalyst. [PDF]
Taheri K +3 more
europepmc +1 more source
Magnetic resorcinol-formaldehyde supported Schiff-base/Cu as a robust and recoverable nanocatalyst for the synthesis of tetrahydrobenzo[<i>b</i>]pyrans. [PDF]
Bazmayon P, Elhamifar D, Kargar S.
europepmc +1 more source
Rh(III)-Catalyzed Regioselective [4 + 2] Annulation of 2-Benzyl-2H-indazole-6-carboxylic Acids with Ynamides to Access Indazole-Fused Pyrans. [PDF]
Hsieh HS +4 more
europepmc +1 more source
Solvent-free mechanochemical multicomponent preparation of 4H-pyrans catalyzed by Cu2(NH2-BDC)2(DABCO) metal-organic framework. [PDF]
Akhlaghi Z +4 more
europepmc +1 more source
Design and catalytic performance of a novel two-dimensional copper metal-organic framework for green synthesis of tetrahydrobenzo[b]pyrans. [PDF]
Bahaderani EJ +3 more
europepmc +1 more source
Copper immobilized MIL-125-NH<sub>2</sub> as an efficient nanocatalyst for click reaction and synthesis of benzo[b]pyrans. [PDF]
Sadati Z, Alinezhad H, Tajbakhsh M.
europepmc +1 more source
Zr-MOF-glutaraldehyde-Adn@Fe<sub>3</sub>O<sub>4</sub> nanocomposite: as a new adsorbent for removal of methylene blue and heterogeneous nanocatalyst for the synthesis of tetrahydrobenzo[b]pyran derivatives. [PDF]
Yazdiamiri F +3 more
europepmc +1 more source

