Results 41 to 50 of about 3,742 (239)

Hydrochloric acid immobilized on nano‐titanium dioxide: a novel and efficient nanocatalyst for the synthesis of tetrahydrobenzo[b]pyrans [PDF]

open access: yesشیمی کاربردی روز, 2017
Hydrochloric acid was immobilized onto the surface of amine functionalized nano‐titania. For this purpose, 2,4‐toluene diisocyanate (TDI) as a bi‐functional covalent linker was grafted onto a nano‐titania and next, the unreacted isocyanate groups were ...
Taiebeh Shamsi   +2 more
doaj   +1 more source

Dynamic Fluorescence Modulation via Light‐Driven Competitive Protonation

open access: yesAdvanced Optical Materials, EarlyView.
A two‐component molecular system demonstrates reversible, light‐driven fluorescence write–erase cycling and thermal imaging. Illumination of a merocyanine photoacid transfers a proton to a highly efficient fluorescent pyridinium dye, switching its emission color; thermal relaxation reverses the process in the dark.
Serena X. Liu   +10 more
wiley   +1 more source

Ionic liquid–driven pyran synthesis: Pathways and perspectives

open access: yesJournal of Ionic Liquids
Pyrans and their fused derivatives are privileged oxygen heterocycles with broad biological activity and industrial relevance, yet their sustainable synthesis remains a continuing challenge.
Pravas Maity, Amrit Krishna Mitra
doaj   +1 more source

Magnetic silica/graphene oxide nanocomposite supported ionic liquid–manganese complex as a powerful catalyst for the synthesis of tetrahydrobenzopyrans

open access: yesScientific Reports, 2023
A novel magnetic silica/graphene oxide nanocomposite supported ionic liquid/manganese complex (Fe3O4@SiO2-NH2/GO/IL-Mn) is prepared, characterized and its catalytic application is investigated.
Farkhondeh Dadvar, Dawood Elhamifar
doaj   +1 more source

Synthesis of New 2-Substituted 4-(2-Furyl)-4H-pyrans

open access: yes, 1994
Substituted 2-amino-3-cyano-4H-pyrans represent important precursors in syntheses of condensed heterocycles containing a 4H-pyran nucleus. In the context of studies of reactivity of 2-amino-5-acetyl-4-(5-X-2-furyl)-3-cyano-6-methyl-4H-pyrans we were ...
Dušan Ilavský   +3 more
core   +1 more source

Purely Equatorial Lasing in Spherical Liquid Crystal Polymer Microlasers with Bipolar Refractive Index Profile

open access: yesAdvanced Optical Materials, EarlyView.
Spherical liquid crystal polymer microlasers with a bipolar configuration confine lasing to a single equatorial plane, allowing precise control over where the laser emission is generated. The anisotropic refractive index profile additionally lifts the energy degeneracy of azimuthal whispering gallery modes, which causes a characteristic splitting into ...
David Ripp   +5 more
wiley   +1 more source

Mitochondria‐Targeted Multimodal Nanotherapeutics Suppress Oxidized mtDNA‐Driven Inflammation at the Source

open access: yesAdvanced Science, EarlyView.
Ox‐mtDNA fragments escaping from mitochondria drive robust inflammatory responses. A targeted nanoplatform simultaneously inhibits mitochondrial FEN1‐mediated mtDNA cleavage and scavenges ROS, preventing the generation of immunogenic Ox‐mtDNA fragments. The released SeNPs further promote autophagic clearance of cytosolic mtDNA. Consequently, cGAS‐STING,
Wen‐Ling Li   +7 more
wiley   +1 more source

Molecular Atlas of Key Food Odorants Reveals Mixture‐Level Organization and Enables Generative Aroma Design

open access: yesAdvanced Science, EarlyView.
KFO‐Atlas reveals how real‐world aromas are organized as structured mixtures rather than individual molecules. Building on these principles, KFO‐Gen, a generative AI framework, designs perceptually valid aroma formulations and reconstructs meat‐like aromas exclusively from plant‐derived odorants, providing a foundation for mixture‐level studies and AI ...
Jingzhi Zhang   +5 more
wiley   +1 more source

Design and application of a novel natural deep eutectic solvent as a green solvent and catalyst for the efficient synthesis of tetrahydrobenzo[b]pyrans

open access: yesHeliyon
In this study, a novel natural deep eutectic solvent (NADES) composed of proline (HBA), choline chloride (HBA), glycerol (HBD) (1:1:6) was designed and utilized for the green synthesis of tetrahydrobenzo[b]pyrans.
Fatemeh Pirani, Hossein Eshghi
doaj   +1 more source

2-(2-(Dimethylamino)vinyl)-4H-pyran-4-ones as Novel and Convenient Building-Blocks for the Synthesis of Conjugated 4-Pyrone Derivatives

open access: yesMolecules, 2022
A straightforward approach for the construction of the new class of conjugated pyrans based on enamination of 2-methyl-4-pyrones with DMF-DMA was developed.
Dmitrii L. Obydennov   +8 more
doaj   +1 more source

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