Results 51 to 60 of about 3,431 (233)

Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent

open access: yesE-Journal of Chemistry, 2011
Morpholinium fluorochromate(VI), MFC, is easily synthesized by reacting morpholine to an aqueous solution of CrO3 and HF. This reagent selectively oxidizes aryl alcohols to their corresponding aldehydes and ketones under mild conditions.
S. Zahra Sayyed-Alangi   +3 more
doaj   +1 more source

2-(2-(Dimethylamino)vinyl)-4H-pyran-4-ones as Novel and Convenient Building-Blocks for the Synthesis of Conjugated 4-Pyrone Derivatives

open access: yesMolecules, 2022
A straightforward approach for the construction of the new class of conjugated pyrans based on enamination of 2-methyl-4-pyrones with DMF-DMA was developed.
Dmitrii L. Obydennov   +8 more
doaj   +1 more source

Asymmetric Synthesis of Tertiary α‐Aryl Stereocentres in Tetrahydro‐4H‐pyran‐4‐ones Using Pd‐Catalyzed Decarboxylative Asymmetric Protonation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The Pd‐catalyzed decarboxylative asymmetric protonation (DAP) has been developed for sterically hindered tetrahydro‐4H‐pyran‐4‐one derived α‐aryl‐β‐keto esters. A substrate scope of nine examples of DAP showed that substrates containing a di‐ortho methoxy substitution pattern on the aryl ring gave rise to the highest enantioselectivities of up to 85 ...
Fionn McNeill   +5 more
wiley   +1 more source

[DMImd-DMP]: A highly efficient and reusable catalyst for the synthesis of 4H-benzo[b]pyran derivatives

open access: yesHeterocyclic Communications, 2019
A series of substituted 4H-pyrans derivatives were synthesized by a one-pot, multi-component reaction of aromatic aldehydes, malononitrile, and pyrazolone derivatives or active methylene carbonyl compounds such as dimedone, in the presence of 1,3 ...
Redouane Mohamed Abdenour   +3 more
doaj   +1 more source

Organic photonic synaptic transistors for bionic vision: From spectral engineering to flexible intelligent perception

open access: yesFlexMat, EarlyView.
Different wavelength photonic synapses are used for biomimetic visual applications. Abstract Bionic intelligent visual perception systems have significant application prospects in fields such as autonomous driving and robotics, medical imaging and auxiliary diagnosis, security and monitoring.
Longlong Jiang   +6 more
wiley   +1 more source

One Pot Synthesis of Spirocycles and Cyclopropa[b]pyrans by Alkenylation-Rearrangement of Cyclopropenes [PDF]

open access: yes, 2022
A one pot alkenylation followed by a stereoselective Alder-ene cycloisomerization of cyclopropenes give (aza)spiro[2.4]heptanes and spiro[2.5]octanes in high yields.
Eleonora Giona (13536112)   +3 more
core   +1 more source

Design and application of a novel natural deep eutectic solvent as a green solvent and catalyst for the efficient synthesis of tetrahydrobenzo[b]pyrans

open access: yesHeliyon
In this study, a novel natural deep eutectic solvent (NADES) composed of proline (HBA), choline chloride (HBA), glycerol (HBD) (1:1:6) was designed and utilized for the green synthesis of tetrahydrobenzo[b]pyrans.
Fatemeh Pirani, Hossein Eshghi
doaj   +1 more source

Impact of climate‐induced compositional shifts of ethanol and acidity on aroma release and perception in red wine: a case study on γ‐nonalactone and massoia lactone

open access: yesJournal of the Science of Food and Agriculture, EarlyView.
Abstract BACKGROUND Climate change‐driven warming is increasing wine ethanol, promoting an atypical convergence between pH and titratable acidity (TA), and favouring the accumulation of specific wine volatiles: γ‐nonalactone (γ‐C9) and massoia lactone (MLac).
Roberto Salvatore Di Fede   +3 more
wiley   +1 more source

Clean One-Pot Multicomponent Synthesis of Pyrans Using a Green and Magnetically Recyclable Heterogeneous Nanocatalyst

open access: yesSynOpen, 2021
Copper ferrite (CuFe2O4) magnetic nanoparticles (MNPs) were synthesized via thermal decomposition and applied as a reusable and green catalyst in the synthesis of functionalized 4H-pyran derivatives using malononitrile, an aromatic aldehyde, and a β ...
Mina Ghassemi, Ali Maleki
doaj   +1 more source

Gradient‐Structured Polymer Fiber Mats for Broadly Tunable Multicolor and White Lasing

open access: yesLaser &Photonics Reviews, EarlyView.
Hierarchically engineered electrospun fiber mats containing separated red, green, and blue dyes enable highly tunable multicolor and white random lasing. Spatially controlled dye distribution suppresses energy transfer, allowing precise color adjustment across wide color gamuts and accurate reproduction of daylight white standards.
Alina Szukalska   +6 more
wiley   +1 more source

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