Results 141 to 150 of about 51,809 (295)

Mutual effect of thermochemical surface decomposition and viscous interaction during hypersonic flow past a sharp cone [PDF]

open access: yes
Numerical results on the hypersonic gas flow in viscous interaction regime past sharp circular cones with thermally destructible Teflon surface are presented. Characteristics of the mutual influence between the thermochemical decomposition of the surface
Limanskiy, A. V., Timoshenko, V. I.
core   +1 more source

Channel Microenvironment‐Controlled Pillared MOF as Efficient Triboelectric Nanogenerator Material for Self‐Powered Degradation of Organic Pollutants

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The pore microenvironment regulation of metal–organic framework (MOF) significantly enhanced the output performance of triboelectric nanogenerators (TENG) through SC‐SC transformation, which provides a new idea for the construction of self‐powered degradation systems for organic pollutants.
Long Li   +8 more
wiley   +1 more source

Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley   +1 more source

Emerging Trends in Organic Photoreactions Utilizing Disulfides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar   +3 more
wiley   +1 more source

Design and Synthesis of Lactose‐Derived Ligands and Their Application in Asymmetric Friedel–Crafts Alkylation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This work describes the synthesis of lactose‐ and glucose‐derived chiral ligands and their application in the catalytic enantioselective Friedel–Crafts alkylation of indole with a series of trans‐β‐nitrostyrenes. The optimal ligand was an acetate protected, lactose‐derived pyridyl imine and its zinc complex afforded ees up to 93% and yields up to 93 ...
Sandra Bulawa   +2 more
wiley   +1 more source

Hofmann Degradation of Asparagine and Glutamine as an Efficient Approach for the Synthesis of Derivatized Lysine Homologs

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A practical and scalable route to C1 and C2 lysine homologs has been developed using Hofmann degradation of N‐protected L‐asparagine and L‐glutamine as the key step. These short‐tether scaffolds enable efficient synthesis of diverse Fmoc‐protected noncanonical amino acids (ncAAs) bearing donor, acceptor, redox‐active, and fluorescent residues.
Adelaide R. Mashweu   +7 more
wiley   +1 more source

1,2‐Diazetidines − Structure, Synthesis, and Functionalization

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
wiley   +1 more source

New thallium(III) chloride complexes with pyridine carboxylic acids: from molecular compounds to supramolecular associations

open access: yesOpen Chemistry, 2003
Toma Monica   +7 more
doaj   +1 more source

Formal Diels-Alder reaction of saturated carboxylic acids via C-H activation. [PDF]

open access: yesNat Chem
He Q   +6 more
europepmc   +1 more source

Dicarboxylic acid anhydride condensation with compounds containing active methylene groups. 4: Some 4-nitrophthalic anhydride condensation reactions [PDF]

open access: yes
By 4-nitrophthalic anhydride condensation with acetoacetate in acetic anhydride and triethylamine solution with subsequent breakdown of the intermediate condensation product, 5-nitroindanedione-1,3 was obtained.
Oskaja, V., Rotberg, J.
core   +1 more source

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