Results 131 to 140 of about 60,238 (275)

Selective N‐Functionalization of Pyrazoles

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek   +2 more
wiley   +1 more source

Investigating the chemistry of pyridinium ylides [PDF]

open access: yes
This thesis describes investigation into catalytic formation of pyridinium ylides from diazo compounds and their subsequent reactivity. In particular, cycloaddition reactions with electrophilic alkenes are performed to generate tetrahydroindolizines that
Abdullah, Rasha Azzam
core   +2 more sources

Spatially Resolved Metabolomics of Optimal Cutting Temperature (OCT) Compound‐Embedded Tumors

open access: yesInternational Journal of Cancer, EarlyView.
ABSTRACT Mass spectrometry imaging (MSI) is emerging as a powerful tool for uncovering the distribution of metabolites in the tumor microenvironment and studying tumor metabolism in vivo. To date, MSI of biobanked tissues contextualized by patient data has been limited to peptides, proteins, and glycans—with few examples for metabolites.
Joseph Monaghan   +6 more
wiley   +1 more source

Pyridinium p-DSSC Dyes

open access: yes, 2019
Data to accompany Pyridinium p-DSSC Dyes: An Old Acceptor Learns New Tricks DYPI_2018_2284_R1 .
F Black (7835606), J Mallows (8422365)
core   +1 more source

Ionic liquids: structure–toxicity relationships, predictive toxicology, and sustainable design

open access: yesJournal of Chemical Technology &Biotechnology, EarlyView.
Abstract Ionic liquids (ILs) have often been described as green alternatives to conventional solvents because of their negligible vapor pressure and highly tunable properties. However, low volatility does not necessarily translate into environmental safety, as their biological and ecological effects are strongly influenced by molecular structure.
Letícia Zanchet   +5 more
wiley   +1 more source

Pyridinium ylids in synthesis. III. Synthesis of indolizines

open access: yes, 1967
Treatment of pyridinium, quinolinium, and isoquinolinium ylids with acetylenes yields indolizine derivatives. Pyridinium phenacylid with iodine in dimethylacetamide gives 1,2,3-tribenzoylindolizine.
CA Henrick, E Ritchie, WC Taylor
core   +1 more source

Gold(I)‐Catalyzed Annulation of Pyridines Containing Alkyne: Synthesis of N‐Alkenyl Pyridonyl Azides via Rearrangement

open access: yesJournal of Heterocyclic Chemistry, EarlyView.
One‐pot gold(I)‐catalysts synthesis was developed in order to prepare N‐alkenyl 2‐pyridonyl azides. This method provides a series of N‐alkenyl 2‐pyridonyl azides in moderate to excellent yields (up to 94%). ABSTRACT A novel strategy, involving the preparation of gold‐catalyzed cyclization salts and the rearrangement of these salts in the presence of ...
Ali Osman Karatavuk
wiley   +1 more source

Analysis of Carbohydrates and Glycoconjugates by Matrix‐Assisted Laser Desorption/Ionization Mass Spectrometry: An Update for 2023–2024

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT The use of MALDI mass spectrometry for the analysis of carbohydrates and glycoconjugates is a well‐established technique and this comprehensive review is the twelfth update of the original article published in 1999 and brings coverage of the literature to the end of 2024.
David J. Harvey
wiley   +1 more source

Cross‐Scale Engineering of Single‐Atom Catalysts from Local Planar Coordination to Spatial Architectures

open access: yesSmall, EarlyView.
This Review presents a cross‐scale framework for single‐atom catalysts, spanning in‐plane and out‐of‐plane coordination; primary coordination, secondary‐sphere interactions, through‐space microenvironments and support interfaces; individual sites and macroscopic architectures; and static design and directed dynamic reconstruction.
Dazhi Yao   +4 more
wiley   +1 more source

Synthesis, characterisation and magnetic behaviour of ionic metalloporphyrins: metal-tetrakis(N-octyl-4-pyridinium)-porphyrins with tetrabromoferrate(III) anions [PDF]

open access: yes, 2013
A series of magnetic, ionic-substituted tetrapyridyl metalloporphyrins, [tetrakis(N-octyl-4-pyridinium)-metal-porphyrin][tetrabromoferrate(III)] 4 (metal=iron, cobalt, manganese, copper or zinc), have been synthesised.
Zhou, Qing   +9 more
core  

Home - About - Disclaimer - Privacy