Results 111 to 120 of about 73,143 (258)

Regioselective Oxidation of 3-Substituted Pyridinium Salts

open access: yesMolecules, 2000
(1'R)-(+)-3-Hydroxymethyl-1-(1'-phenyl-ethyl)-pyridinium chloride (1), 1-benzyl-3-[1', 3']-dioxolan-2'-yl-pyridinium chloride (2) and (2'S, 4'S, 5'R)-(-)-1-benzyl-3-(3',4'-dimethyl-5'-phenyl-oxazolidin-2'-yl)-pyridinium bromide (3), were transformed by ...
W. F. Reynolds   +6 more
doaj   +1 more source

High Potential Isoindoline-Based Nitroxides Posolytes for Aqueous Organic Redox Flow Batteries. [PDF]

open access: yesChemSusChem
A convenient metal‐catalyzed [2 + 2 + 2] cycloaddition enables the synthesis of isoindoline‐based nitroxides as new posolytes for aqueous organic redox flow batteries. The cationic PPO exhibits a 220 mV higher oxidation potential than 4‐TMA‐TEMPO, 3 M solubility in 1 M NaCl, and a cell voltage of 1.56 V.
Boutamine K   +8 more
europepmc   +2 more sources

The nature of the silicaphilic fluorescence of PDMPO [PDF]

open access: yes, 2015
PDMPO (2-(4-pyridyl)-5-((4-(2-dimethylaminoethylaminocarbamoyl)methoxy)phenyl)oxazole), has unique silica specific fluorescence and is used in biology to understand biosilicification.
Amat   +44 more
core   +1 more source

3D Polymeric Nanonetworks: From Self‐Assembly to Advanced Fabrication

open access: yesMacromolecular Materials and Engineering, EarlyView.
This review provides the first systematic cross‐method comparison of fabrication techniques for 3D polymeric nanonetworks. It evaluates five key strategies—block copolymer self‐assembly, hyper‐crosslinking, template‐assisted methods, 3D printing, and nanolithography—across critical metrics including resolution, throughput, scalability, and material ...
Carlos G. Cobos   +2 more
wiley   +1 more source

Mitochondrially targeted ceramides preferentially promote autophagy, retard cell growth, and induce apoptosis

open access: yesJournal of Lipid Research, 2011
C6-pyridinium (d-erythro-2-N-[6′-(1′′-pyridinium)-hexanoyl]sphingosine bromide [LCL29]) is a cationic mitochondrion-targeting ceramide analog that promotes mitochondrial permeabilization and cancer cell death.
Qi Hou   +8 more
doaj   +1 more source

Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal-Organic Frameworks [PDF]

open access: yes, 2018
The isoreticular expansion and functionalization of charged-polarized porosity has been systematically explored by the rational design of 11 isostructural zwitterionic metal-organic frameworks (ZW-MOFs).
Aulakh, D   +8 more
core   +13 more sources

Catechol‐Containing Poly(2‐isopropyl‐2‐oxazoline): Synthesis and Thermoresponsive Behavior in Aqueous Salt Solutions

open access: yesMacromolecular Rapid Communications, EarlyView.
Polymers carrying catechol groups are interesting mussel‐inspired materials for wet adhesion applications or metal ion complexation for wastewater treatment. Here, catechol‐containing poly(2‐isopropyl‐2‐oxazoline)s were synthesized via microwave‐assisted cationic (co)polymerization and examined with regard to their thermoresponsive LCST behavior in ...
Niclas Madaj   +4 more
wiley   +1 more source

4-(Dimethylamino)pyridinium 4-toluenesulfonate

open access: yesActa Crystallographica Section E, 2008
In the title compound, C7H11N2+·C7H7O3S−, the cation is protonated at the N atom of the heterocyclic ring. The dimethylamino group lies close to the pyridinium ring plane with a dihedral angle between the pyridinium and the dimethylamine CNC ...
Jim Simpson, C. John McAdam
doaj   +1 more source

Characterisation and functionalisation of mechanically fractured graphene nanoribbons : a thesis presented in partial fulfilment of the requirements for the degree of Master of Science in Nanoscience at Massey University, Manawatū, New Zealand [PDF]

open access: yes, 2017
Graphene has been heralded as the supermaterial of the future, boasting incredibly high electron mobility, thermal conductivity, and physical strength – all contained within the world’s first true 2D material, only a single atom thick.
Brooke, Samuel James
core  

Microwave‐Assisted Organic Syntheses in Deep Eutectic Solvents: A Win‐Win Association for Sustainable Chemistry

open access: yesChemistryOpen, EarlyView.
In organic synthesis, deep eutectic solvents (DES) have demonstrated their ability to be used as reaction media for the development of reactions in line with green chemistry principles. This review presents an overview of microwave‐assisted organic synthesis in DES, highlighting the diversity of uses for these solvents, their role in mechanisms, the ...
Pierre‐Olivier Delaye   +2 more
wiley   +1 more source

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