Results 81 to 90 of about 60,238 (275)

Click‐Spaltung quartärer Anilinium‐Tetrazine ermöglicht Kaskadenaufbau multifunktioneller biomolekularer Gerüste

open access: yesAngewandte Chemie, EarlyView.
Die Click‐Chemie hat sich von dem Aufbau kovalenter Bindungen hin zum Spalten von Bindungen weiterentwickelt. Hier wird über einen Kaskaden‐Aufbau berichtet, der diese Verfahren kombiniert, um multifunktionale biomolekulare Gerüste in einer modularen Ein‐Topf‐Reaktion aufzubauen.
Markus Staudt   +9 more
wiley   +1 more source

2-Aminopyridinium 2,4-dinitrophenolate

open access: yesIUCrData, 2016
The asymmetric unit of the title organic salt, C5H7N2+·C6H3N2O5−, comprises two 2-aminopyridinium cations and two 2,4-dinitrophenolate anions. The cations are protonated at the pyridine N atoms, while the anions are deprotonated at hydroxyl O atoms.
S. Reena Devi   +4 more
doaj   +1 more source

Reactivity of Halo(pyridinium)carbenes

open access: yes, 2016
The reactivity of chloro- and fluoro(N-methyl-3-pyridinium)carbenes was examined by laser flash photolysis, where the halo(pyridinium)carbenes formed ylides with pyridine, acetonitrile, and acetone.
Reinaldo Moya-Barrios (2333677)   +2 more
core   +1 more source

Pyridinium dichlorophosphinomethylides

open access: yesHeteroatom Chemistry, 2001
AbstractSeven new pyridinium dichlorophosphinomethylides 2 have been obtained from dichlorophosphinylation of the pyridinium methylides generated in situ. 2 give 1,3‐bis(alkoxycarbonyl)‐2‐phosphaindolizines 4 through 1,5‐electrocyclization of the intermediate, bis(pyridinium ylidyl)phosphenium chloride 3 which is generated either from ...
Raj K. Bansal   +4 more
openaire   +1 more source

Ionic Hydrogenation of Pyridinium and Azetidinium Cations [PDF]

open access: yes, 2017
Research described herein seeks to study the reactivity of CpRu(P-P)H with pyridinium and azetidinium cations. For the former, we wish to determine if a previously established methodology for the regioselective reduction of a particular pyridinium ...
Yang, Zheren Jim
core   +1 more source

Facile access to pyridinium-based bent aromatic amphiphiles: nonionic surface modification of nanocarbons in water

open access: yesBeilstein Journal of Organic Chemistry
Efficient water-solubilization of nanocarbons is desirable for both their biological and material applications, but so far has mainly relied on covalent modifications or amphiphiles featuring ionic side-chains. Here, we report a facile 2–4-step synthesis
Lorenzo Catti   +2 more
doaj   +1 more source

A rare positively charged nicotinic acid disulfide: 2,2′-dithiodinicotinic acid hydrochloride monohydrate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2018
The title compound {systematic name: 3-carboxy-2-[2-(3-carboxypyridin-2-yl)disulfan-1-yl)]pyridin-1-ium chloride monohydrate}, C12H9N2O4S2+·Cl−·H2O, crystallizes in the triclinic space group P\overline{1}.
Alexander T. Chemey   +2 more
doaj   +1 more source

Crystal structure of pyridinium tetraisothiocyanatodipyridinechromium(III) pyridine monosolvate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
In the crystal structure of the title compound, (C5H6N)[Cr(NCS)4(C5H5N)2]·C5H5N, the CrIII ions are octahedrally coordinated by four N-bonding thiocyanate anions and two pyridine ligands into discrete negatively charged complexes, with the CrIII ion, as ...
Tristan Neumann   +2 more
doaj   +1 more source

Near Infrared Photoswitching by Direct Excitation—A Next Frontier

open access: yesAngewandte Chemie International Edition, EarlyView.
Molecular photoswitches finally enter the spectral realm of near‐infrared for their direct excitation. This minireview summarizes the current state‐of‐the‐art, the design principles for achieving such low‐energy light responsiveness, and the unique applications that are unlocked by it.
Diptiprava Sahoo   +2 more
wiley   +1 more source

Pyridinium chloride

open access: yes, 2017
Inelastic Neutron Scattering spectrum of Pyridinium chloride, C₅H₆ClN, measured on the TFXA ...
C. B. Jasciezek, U. of Sussex, UK
core   +1 more source

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