Results 101 to 110 of about 61,221 (238)

4-(4-Nitrobenzyl)pyridinium 5-nitrosalicylate [PDF]

, 2010
In the title salt, C12H11N2O2+·C7H4NO5−, the cations and anions interact through asymmetric cyclic pyridinium–carboxylate N—H...O,O′ hydrogen-bonding associations [graph set R12(4)], giving discrete ...
Urs D. Wermuth, Smith, Graham, Wermuth, Urs D., Graham Smith   +3 more
core   +2 more sources

Mitochondrially targeted ceramides preferentially promote autophagy, retard cell growth, and induce apoptosis

Journal of Lipid Research, 2011
C6-pyridinium (d-erythro-2-N-[6′-(1′′-pyridinium)-hexanoyl]sphingosine bromide [LCL29]) is a cationic mitochondrion-targeting ceramide analog that promotes mitochondrial permeabilization and cancer cell death.
Qi Hou, Junfei Jin, Hui Zhou, Sergei A. Novgorodov, Alicja Bielawska, Zdzislaw M. Szulc, Yusuf A. Hannun, Lina M. Obeid, Yi-Te Hsu   +8 more
doaj   +1 more source

FLP Mediated Conversion of Difluorobenzylalkynes to Fluoroallenyl Oniums via an SN1’ Pathway

Chemistry – A European Journal, EarlyView.
Frustrated Lewis pair (FLP) selective C‒F activation of difluorobenzylalkynes allows the formation of fluoroallenic oniums via an SN1’ substitution pathway. The fluoroallenic onium salts are synthetic precursors that allow subsequent functionalization at allenic and onium positions.
Max Coles, Tianhong Wang, Rubi McLennan, Long Kit Kwan, Bivas Mondal, Chakyu Richard Chan, Rowan D. Young   +6 more
wiley   +1 more source

4-(Dimethylamino)pyridinium 4-toluenesulfonate

Acta Crystallographica Section E, 2008
In the title compound, C7H11N2+·C7H7O3S−, the cation is protonated at the N atom of the heterocyclic ring. The dimethylamino group lies close to the pyridinium ring plane with a dihedral angle between the pyridinium and the dimethylamine CNC ...
Jim Simpson, C. John McAdam
doaj   +1 more source

Expanding the Scope of Indium in Frustrated Lewis Pair Chemistry

Chemistry – A European Journal, EarlyView.
All good things come in threes: The pyridine‐“protected” FLP tBu2InCH2PtBu2·Py shows three different kinds of reactivity: Besides “typical” FLP activity, it prefers formation of the “soft” isomers for substrates with multiple sites for FLP attack, but reacts with SO2 as a “masked” In/C FLP by insertion into the In─C bond.
Daniel N. Heuer, Jan‐Hendrik Lamm, Beate Neumann, Andreas Mix, Yury V. Vishnevskiy, Norbert W. Mitzel   +5 more
wiley   +1 more source

4-(3-Ethoxy-4-hydroxystyryl)-1-methylpyridinium tosylate monohydrate

Acta Crystallographica Section E, 2009
In the title compound, C16H18NO2+·C7H7O3S−·H2O, the dihedral angle between the pyridyl and benzene rings of the pyridinium cation is 0.2 (1)°. The benzene ring of the tosylate anion makes a dihedral angle of 4.8 (2)°
S. Murugavel, A. SubbiahPandi, C. Srikanth, S. Kalainathan   +3 more
doaj   +1 more source

From Charge‐Transfer Adducts to (Tri)Halide‐Templated Supramolecular Cages: Covalent vs Ionic Products in the Reactions of Pyridin‐4‐ylthio‐Substituted Tetrathiafulvalene With Dihalogens and Interhalogens

Chemistry – A European Journal, EarlyView.
The reactions between tetra(pyridin‐4‐ylthio)tetrathiafulvalene and Br2/I2/ICl/IBr led to a variety of products, including a rare example of neutral 1:4 CT adduct and ionic products showing supramolecular cage motifs at (tri)halide templates. The nature of the reaction products was elucidated based on XRD analysis, Raman spectroscopy and QTAIM, NCI ...
Anna Caria, Stéphane A. Baudron, M. Carla Aragoni, Vito Lippolis, Anna Pintus, Enrico Podda, Massimiliano Arca   +6 more
wiley   +1 more source

Asymmetric reduction of aromatic ketones in pyridinium-based ionic liquids

, 2006
The asymmetric reduction of aromatic ketones has been studied in pyridinium-based room temperature ionic liquids, namely, 1-ethyl-pyridinium tetrafluoroborate, [EtPy]+[BF4]- and 1-ethyl-pyridinium trifluoroacetate, [EtPy]+[CF3COO]-.
Xiao, Ying, Malhotra, Sanjay V.
core   +1 more source

NUCLEOPHILIC SUBSTITUTION OF PYRIDINIUM SALTS BY MERCAPTANS.

, 1967
NUCLEOPHILIC SUBSTITUTION OF PYRIDINIUM SALTS BY ...
THOMAS EDWARD. DICKERHOFE (7959335)
core   +3 more sources

Pyridinium Cations Act as Charge Reservoirs in Expanded Halide Perovskite Analogs at High Pressure. [PDF]

Angew Chem Int Ed Engl
Redox‐innocent pyridinium derivatives can act as charge reservoirs in expanded tin‐iodide perovskite analogs. Material compression reduces the energy gap between the pyridinium π* acceptor orbital and the valence‐band maximum, facilitating electron transfer from the framework to the molecules and thereby significantly increasing electronic conductivity
Deschene CR, Ke F, Fykouras K, Su AC, Lin Y, Leppert L, Karunadasa HI, Matheu R.   +7 more
europepmc   +3 more sources