Results 21 to 30 of about 47,136 (264)

Catalytic Photochemical Enantioselective α-Alkylation with Pyridinium Salts

open access: yes, 2022
We have developed a chiral amine catalyzed enantioselective α-alkylation of aldehydes with amino acid derived pyridinium salts as alkylating reagents. The reaction proceeds in the presence of visible light (390 nm) and in the absence of a photocatalyst ...
Santhivardhana Reddy, Yetra   +2 more
core   +1 more source

Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
In the title hydrated salt, C13H10Cl2N3O+·Cl−·3H2O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the ...
J. Josephine Novina   +3 more
doaj   +1 more source

Crystal structure of bis[1-(naphthalen-1-ylmethyl)pyridinium] bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)

open access: yesActa Crystallographica Section E, 2014
A new ion-pair complex, (C16H14N)2[Ni(C4N2S2)2] or (1-NaMePy)2[Ni(imnt)2], where 1-NaMePy is 1-(4-naphthylmethylene)pyridinium and imnt is 2,2-dicyanoethene-1,1-dithiolate, was obtained by the direct reaction of NiCl2, K2imnt and (1-NaMePy)+Br− in H2O ...
Miao Zhang, Xu-Jie Xiong
doaj   +1 more source

Bright NIR-Emitting Styryl Pyridinium Dyes with Large Stokes’ Shift for Sensing Applications

open access: yesBiosensors, 2023
Two NIR-emitting donor-π-acceptor (D-π-A) type regioisomeric styryl pyridinium dyes (1a–1b) were synthesized and studied for their photophysical performance and environment sensitivity. The two regioisomers, 1a and 1b, exhibited interesting photophysical
Nirasha I. Wickramasinghe   +5 more
doaj   +1 more source

Crystal structure of 4-amino-1-(4-methylbenzyl)pyridinium bromide

open access: yesActa Crystallographica Section E, 2014
The title molecular salt, C13H15N2+·Br−, crystallized with two independent ion pairs (A and B) in the asymmetric unit. In the cations, the planes of the pyridine and benzene rings are inclined to one another by 79.32 (8) and 82.30 (10)° in ion pairs A ...
N. Sharmila   +4 more
doaj   +1 more source

(E)-2,6-Dibromo-4-{2-[1-(1H,1H,2H,2H-perfluorooctyl)pyridinium-4-yl]ethenyl}phenolate methanol disolvate, a fluoroponytailed solvatochromic dye

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2017
The title compound, C21H12Br2F13NO·2CH3OH, was obtained by condensation of 4-methyl-1-(1H,1H,2H,2H-perfluorooctyl)pyridinium iodide and 3,5-dibromo-4-hydroxybenzaldehyde, followed by deprotonation.
Lukas Fliri   +5 more
doaj   +1 more source

2-Amino-4-methoxy-6-methylpyrimidin-1-ium trifluoroacetate

open access: yesIUCrData, 2016
In the title molecular salt, C6H10N3O+·C2F3O2−, the pyrimidinium cation is essentially planar, with a maximum deviation of 0.042 (3) Å for all non-H atoms.
Muthaiah Jeevaraj   +5 more
doaj   +1 more source

Successive Crystallization of Organically Templated Uranyl Sulfates: Synthesis and Crystal Structures of [pyH](H3O)[(UO2)3(SO4)4(H2O)2], [pyH]2[(UO2)6(SO4)7(H2O)], and [pyH]2[(UO2)2(SO4)3]

open access: yesChemEngineering, 2021
Three new uranyl sulfates, [pyH](H3O)[(UO2)3(SO4)4(H2O)2] (1), [pyH]2[(UO2)6(SO4)7(H2O)] (2), and [pyH]2[(UO2)2(SO4)3] (3), were produced upon hydrothermal treatment and successive isothermal evaporation.
Evgeny V. Nazarchuk   +2 more
doaj   +1 more source

Pyridinium based amphiphilic hydrogelators as potential antibacterial agents

open access: yesBeilstein Journal of Organic Chemistry, 2010
The numerous applications of hydrogelators have led to rapid expansion of this field. In the present work we report the facile synthesis of amphiphilic hydrogelators having a quaternary pyridinium unit coupled to a hydrophobic long alkyl chain through an
Sayanti Brahmachari   +3 more
doaj   +1 more source

Recent Progress in Heterocycle Synthesis: Cyclization Reaction with Pyridinium and Quinolinium 1,4-Zwitterions

open access: yesMolecules, 2023
Heteroarene 1, n-zwitterions are powerful and versatile building blocks in the construction of heterocycles and have received increasing attention in recent years.
Zhen-Hua Wang   +5 more
doaj   +1 more source

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