Results 91 to 100 of about 9,595 (203)

Selective photo labeling of tryptophan in N‐acetyl‐L‐tryptophan ethyl ester and peptide WWCNDGR with a diaryl nitrenium ion

open access: yesPhotochemistry and Photobiology, EarlyView.
Visible light photolysis of a N‐(N,N‐diarylaminopyridinium) salt allows for covalent modification of a peptide. Mass spectrometry demonstrates that this procedure selectively labels tryptophan residues. Laser flash photolysis experiments show that bond formation occurs via a diarylnitrenium ion intermediate.
Edward S. Chinn   +3 more
wiley   +1 more source

Poly(vinylbenzyl Pyridinium Salts) as Novel Sorbents for Hazardous Metals Ions Removal. [PDF]

open access: yesMolecules, 2022
Wieszczycka K   +4 more
europepmc   +1 more source

Structural and Spectroscopic Evidence of Hydrogen Bonded Anionic Wires in Protic Ionic Liquids

open access: yesChemPhysChem, Volume 27, Issue 19, 14 October 2026.
Anionic wires of deprotonated carboxylic acids challenge the general wisdom that like charges repel. The hydrogen bond motif observed in the X‐ray structure is even preserved in the liquid state of the material as shown by δ1H NMR spectroscopy. The experimental and theoretical findings provide deep insight into the nature of hydrogen bonding.
Maham Azhar   +5 more
wiley   +1 more source

Photosensitizing Au(I) Catalysis With Coumarins

open access: yesChemistry – A European Journal, Volume 32, Issue 38, 13 October 2026.
A Au(I) complex with a tethered coumarin fragment was synthesized and characterized by UV‐vis and emission spectroscopy. Its ability to facilitate photo‐driven cross‐coupling reactions through single‐electron and energy transfer events was evaluated. ABSTRACT Gold catalysis shows versatility in a wide range of challenging transformations, wherein light‐
Liliana Capulín Flores   +2 more
wiley   +1 more source

The Expanding Role of Diazirines in Synthetic Methodology

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 38, 13 October 2026.
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic   +3 more
wiley   +1 more source

Synthesis of 3-substituted pyridinium salts

open access: yesARKIVOC, 2000
Juliusz Pernak, Jaroslaw Rogoza
doaj   +1 more source

Donor-Acceptor Pyridinium Salts for Photo-Induced Electron-Transfer-Driven Modification of Tryptophan in Peptides, Proteins, and Proteomes Using Visible Light. [PDF]

open access: yesJ Am Chem Soc, 2022
Hoopes CR   +11 more
europepmc   +1 more source

Superlubricity and Corrosion Inhibition Properties of Solvate Ionic Liquids in Hybrid Carbon Fiber Reinforced Plastic–Steel Interfaces

open access: yesAdvanced Engineering Materials, Volume 28, Issue 19, 7 October 2026.
Solvate ionic liquids lubrication reduced the coefficient of friction by ∼60% compared to dry sliding, reaching steady‐state values as low as 0.04–0.05. Corrosion weight‐loss measurements in 1 M HCl further demonstrated significant inhibition behavior, with only 100 ppm of [Li(G3)][TFSI] (∼68.5 μL/L) reducing corrosion‐product weight loss by 63 ...
Sameh Dabees   +6 more
wiley   +1 more source

Supramolecular Polymerization and Morphological Transformation of Dynamic Helical Poly(Phenylacetylene)s via Chain‐End Host–Guest Interactions

open access: yesAngewandte Chemie, Volume 138, Issue 40, 28 September 2026.
A helical polymer whose chain ends are connected through pillar[5]arene‐based host–guest interactions translates molecular helicity into supramolecular morphology. Solvent‐triggered helicity inversion accompanied by changes in chain rigidity switches the supramolecular architecture between cyclic and rigid‐rod nanostructures.
Tatsuya Nishimura   +4 more
wiley   +2 more sources

Home - About - Disclaimer - Privacy