Results 101 to 110 of about 358,569 (255)

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Total Syntheses of Agelamadin F and (±)‐Tauroacidin A, Enabled by NaClO2‐Mediated Coupling Reactions of Oroidin and Amines

Chemistry – A European Journal, EarlyView.
Total syntheses of agelamadin F and (±)‐tauroacidin A were achieved by sodium chlorite (NaClO2)‐mediated oxidative C─N coupling. Nine C15–N–amino acid‐substituted oroidin derivatives were successfully prepared to demonstrate the applicability and versatility of this oxidative coupling reaction.
Ryosuke Hirozumi, Yuta Kudo, Yuko Cho, Mari Yotsu‐Yamashita   +3 more
wiley   +1 more source

Synthesis of Pyridinium Moiety Containing Triazolyl Purines

Molbank
Pyridinium salts of 2-piperidinyl-6-triazolylpurine derivatives were obtained by the introduction of pyridinium moieties into the propane-1,3-diol fragment at the N(9) position of purine to enhance the solubility of 2-amino-6-triazolylpurine derivatives ...
Aleksejs Burcevs, Māris Turks, Irina Novosjolova   +2 more
doaj   +1 more source

Bioinspired Design and Synthesis of Polyphenolic Star‐Like and Hyperbranched Polyester Models

Chemistry – A European Journal, EarlyView.
Gallotannin‐inspired star‐like and hyperbranched aromatic polyesters were synthesized from D‐glucose and ABn‐type phenolic acid monomers, such as protocatechuic acid. This bioinspired approach afforded polyphenolic polymeric nanoparticles able to encapsulate hydrophobic dyes, opening new perspectives for biobased encapsulation and delivery systems ...
Guanfei Shen, Laurent Pouységu, Christophe Schatz, Etienne Grau, Stéphane Quideau   +4 more
wiley   +1 more source

Photosensitizing Au(I) Catalysis With Coumarins

Chemistry – A European Journal, EarlyView.
A Au(I) complex with a tethered coumarin fragment was synthesized and characterized by UV‐vis and emission spectroscopy. Its ability to facilitate photo‐driven cross‐coupling reactions through single‐electron and energy transfer events was evaluated. ABSTRACT Gold catalysis shows versatility in a wide range of challenging transformations, wherein light‐
Liliana Capulín Flores, Jacob J. van der Wal, Johannes E. M. N. Klein   +2 more
wiley   +1 more source

NUCLEOPHILIC SUBSTITUTION OF PYRIDINIUM SALTS BY MERCAPTANS.

, 1967
NUCLEOPHILIC SUBSTITUTION OF PYRIDINIUM SALTS BY ...
THOMAS EDWARD. DICKERHOFE (7959335)
core  

Alkylation of Pyridinium Acceptors via Thermal and Photoinduced Electron Transfer in Charge-Transfer Salts with Organoborates

, 2016
Colored salts of pyridinium tetraalkylborates [Py+,BR4-] are readily isolated by the metathesis of LiBMe4, LiBMePh3, or NaBPh4 with a series of pyridinium triflates in aqueous solution.
Dunming Zhu (1626343), Jay K. Kochi (2399332)   +1 more
core   +1 more source

Single‐Step Synthesis of Dithieno[3,2‐b:2′,3′‐e]Pyridines and Their Acid‐Dependent Optical and Photosensitising Properties

Chemistry – A European Journal, EarlyView.
The synthesis of dithieno[3,2‐b:2′,3′‐e]pyridines (DTPs) is herein reported, and their optical properties are studied both experimentally and computationally. Protonation or methylation of the nitrogen atom induced bathochromic shifts in their absorption and emission spectra.
Dominic Taylor, Matthew Wallace, Leonardo Amicosante, Gary S. Nichol, Scott J. Dalgarno, Filipe Vilela, Iain A. Wright, Neil B. McKeown   +7 more
wiley   +1 more source

Photocatalytic deaminative benzylation and alkylation of tetrahydroisoquinolines with N-alkylpyrydinium salts

Beilstein Journal of Organic Chemistry, 2020
A ruthenium-catalyzed photoredox coupling of substituted N-aryltetrahydroisoquinolines (THIQs) and different bench-stable pyridinium salts was successfully developed to give fast access to 1-benzyl-THIQs.
David Schönbauer, Carlo Sambiagio, Timothy Noël, Michael Schnürch   +3 more
doaj   +1 more source

The Synthesis of New Pyrylium and Pyridinium Salts.

, 2012
The synthesis, properties, and applications of symmetrical and unsymmetrical pyrylium and pyridinium salts is investigated. Our group has found particular interest in chiral pyrylium salts due to the fact that they are almost unknown in the literature ...
Korbitz, Holland.
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