Results 101 to 110 of about 9,595 (203)
Chemical glycosylation facilitates the scalable synthesis of structurally well-defined carbohydrates for functional studies and therapeutic development, with progress being driven by donors and strategies.
Xiaoting Qin +9 more
doaj +1 more source
Memristors based on trimethylsulfonium (phenanthroline)tetraiodobismuthate have been utilised as a nonlinear node in a delayed feedback reservoir. This system allowed an efficient classification of acoustic signals, namely differentiation of vocalisation of the brushtail possum (Trichosurus vulpecula).
Ewelina Cechosz +4 more
wiley +1 more source
Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie +11 more
wiley +2 more sources
Catalytic enantioselective synthesis of 1,4-dihydropyridines via the addition of C(1)-ammonium enolates to pyridinium salts. [PDF]
McLaughlin C +4 more
europepmc +1 more source
Sulfur‐Bridged Cationic and Neutral [6]Helicenes: Chiral Trityls With Property and Stability Twists
Replacing oxygen or nitrogen bridges with sulfur reshapes cationic [6]helicenes and simultaneously tunes their reactivity, photophysics, and configurational dynamics. Sulfur bridging increases helical curvature and electrophilicity, narrows electronic gaps to promote redshifted absorption and emission with larger Stokes shifts, yet unexpectedly lowers ...
Aurélien Chignac +5 more
wiley +1 more source
Quinolin‐4‐ones were converted to chloroquinolinium salts, allowing formation of axially chiral aminoquinolinium salts via an enantioretentive SNAr reaction with a variety of amine nucleophiles. The salts have a high rotational barrier, with a racemization half‐life of ∼1000s of years.
Darren Holmes +5 more
wiley +1 more source
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley +1 more source
An efficient and sustainable method for the synthesis of biologically relevant isoxazoles is developed using modified montmorillonite‐K10 (MMT) nanoclay as a heterogeneous catalyst. The catalyst exhibited good stability and reusability over five cycles, with minimal loss of activity (95%–88%). ABSTRACT Guided by green chemistry principles, an efficient
Anushka Servesh +3 more
wiley +1 more source
Divergent reactivity of sulfinates with pyridinium salts based on one- versus two-electron pathways. [PDF]
Kim M, You E, Park S, Hong S.
europepmc +1 more source
Covalent organic frameworks provide a structurally programmable platform for solid‐state lithium batteries. This review outlines a design framework linking structural descriptors to ion‐transport metrics. It examines mechanisms of confinement, channel architecture, and hybrid designs, addressing the reasons for the occasional failure of high intrinsic ...
Rajesh Dhanushkotti +7 more
wiley +1 more source

