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Magnetic frustration in lead pyrochlores [PDF]
The rich phase diagrams of magnetically frustrated pyrochlores have maintained a high level of interest over the past 20 years. To experimentally explore these phase diagrams requires a means of tuning the relevant interactions. One approach to achieve this is chemical pressure, that is, varying the size of the non-magnetic cation. Here, we report on a
Hallas, A. M. +6 more
openaire +2 more sources
The second phase transition in the pyrochlore oxide Cd2Re2O7 [PDF]
Evidence for another phase transition at 120 K in the metallic pyrochlore oxide Cd2Re2O7, following the structural transition at 200 K and followed by the superconducting transition at 1.0 K, is given through resistivity, magnetoresistance, specific heat,
Hanawa M. +4 more
core +1 more source
Phase formation on the surface of lead ferroniobate depending on the conditions of mechanochemical synthesis and sintering [PDF]
The perovskite structure is formed at lower temperatures with an increase in the time of preliminary activation. It is demonstrated that thermal treatment of mechanically activated for 25 minutes mixture composed of niobium oxide, lithium ...
Gusev Aleksey Alekseevich +3 more
doaj +1 more source
Structural evolution in functional materials is a physicochemical phenomenon, which is important from a fundamental study point of view and for its applications in magnetism, catalysis, and nuclear waste immobilization.
Madhab Pokhrel +5 more
doaj +1 more source
Universal geometric frustration in pyrochlores [PDF]
AbstractMaterials with the pyrochlore/fluorite structure have diverse technological applications, from magnetism to nuclear waste disposal. Here we report the observation of structural instability present in the pyrochlores A2Zr2O6Oʹ (A = Pr, La) and Yb2Ti2O6Oʹ, that exists despite ideal stoichiometry, ideal cation-ordering, the absence of lone pair ...
Trump, BA +13 more
openaire +4 more sources
XPS and NEXAFS Studies of Zn-Doped Bismuth Iron Tantalate Pyrochlore
The effect of Zn-doping on the phase composition and optical properties of the Bi2ZnxFe1-xTa2O9.5-Δ (x = 0.3, 0.5, 0.7) was studied. XRD data showed that the samples crystallize in the structural type of pyrochlore (sp. gr.Fd-3m). For all the samples, an
Sergey V. Nekipelov +7 more
doaj +1 more source
A Novel Pyrochlore Ruthenate: Ca2Ru2O7 [PDF]
Single crystals of a novel ruthenate, Ca2Ru2O7, were obtained. An X-ray diffraction study on a single crystal revealed that this material crystallizes in a pyrochlore structure with a lattice parameter, a = 10.197 Angstroms.
Aléonard R. +33 more
core +1 more source
Frustrated Quantum Rare-Earth Pyrochlores [PDF]
In this review, we provide an introduction to the physics of a series of frustrated quantum rare-earth pyrochlores. We first give a background on the microscopic single- and two-ion physics of these materials, discussing the origins and properties of their exchange interactions and their minimal low-energy effective models before outlining what is ...
Rau, J., Gingras, M.
openaire +3 more sources
Pressure-induced order–disorder transition in Gd1.5Ce0.5Ti2O7 pyrochlore [PDF]
An experimental study on ordered pyrochlore structured Gd1.5Ce0.5Ti2O7 (Fd3¯m) was carried out up to 45 GPa by synchrotron radiation X-ray diffraction and Raman spectroscopy.
Jingjing Niu +3 more
doaj +1 more source
The XPS study of the structure of uranium-containing ceramics [PDF]
The samples of the (Ca0.5GdU0.5)Zr2O7 and (Ca0.5GdU0.5)(ZrTi)O7 ceramics with the fluorite and pyrochlore structures used as matrixes for the long-lived high-level radioactive waste disposal were studied with the X-ray photoelectron spectroscopy ...
Teterin Anton Yu. +7 more
doaj +1 more source

