Results 41 to 50 of about 1,560 (187)

Beyond d‐Band Catalysis: A Critical Review and Descriptor Framework for Rare‐Earth Engineering in Lithium–Sulfur Batteries

open access: yesAdvanced Science, EarlyView.
Rare‐earth catalysts regulate lithium–sulfur battery chemistry through f‐orbital–mediated interactions, enabling simultaneous polysulfide adsorption and catalytic conversion on conductive carbon hosts. This synergistic control suppresses the shuttle effect, accelerates redox kinetics, and guides stable Li2S nucleation, providing a mechanistic framework
Fan Wang   +5 more
wiley   +1 more source

Frustrated Heisenberg antiferromagnet on the pyrochlore lattice [PDF]

open access: yesPhysical Review B, 2001
We investigate quantum phase transitions for the $s=1/2$ antiferromagnetic Heisenberg model on a pyrochlore lattice. By means of a series expansion starting from isolated tetrahedra, the ground-state phase diagram is determined. When the ratio of the two competing exchange couplings is varied, the first-order (second-order) quantum phase transition ...
Akihisa Koga, Kawakami, N
openaire   +2 more sources

On the age of pyrochlore carbonatites from the Ilmeno-Vishnevogorsky Alkaline Complex, the Southern Urals (insights from Rb-Sr and Sm-Nd isotopic data)

open access: yesЛитосфера, 2020
Research subject. In this research, we carried out Sm-Nd- и Rb-Sr-dating of pyrochlore carbonatite from the Vishnevogorsky niobium deposit, Ilmeno-Vishnevogorsky Alkaline Complex, Southern Urals.
I. L. Nedosekova   +5 more
doaj   +1 more source

Low‐Field Giant Dielectric Tunability by Polaron‐Mediated Interfacial Polarization in Pulsed‐Laser‐Deposited‐Nanocrystalline/Amorphous Composite BaTiO3 Thin Films

open access: yesAdvanced Electronic Materials, EarlyView.
Comparison of tunability efficiency between vacuum‐deposited PLD‐BTO films grown at Td = 550°C in the present study and representative previous reports. ABSTRACT Electrically tunable dielectric thin films are essential components for next‐generation low‐voltage electronic devices.
Shinya Kondo   +7 more
wiley   +1 more source

Pyrochlore-Supergroup Minerals Nomenclature: An Update [PDF]

open access: yesFrontiers in Chemistry, 2021
The general formula of the pyrochlore-supergroup minerals is A2B2X6Y. The mineral names are composed of two prefixes and one root name (identical to the name of the group). The first prefix refers to the dominant anion (or cation or H2O or vacancy) of the dominant valence at the Y-site.
openaire   +3 more sources

Fe,Mg-Codoped Bismuth Tantalate Pyrochlores: Crystal Structure, Thermal Stability, Optical and Electrical Properties, XPS, NEXAFS, ESR, and 57Fe Mössbauer Spectroscopy Study

open access: yesInorganics, 2022
The effect of Fe and Mg-codoping on the crystal structure, optical and dielectric properties of bismuth tantalate-based pyrochlores has been studied. Samples of Bi2MgxFe1−xTa2O9.5−Δ (x ≤ 0.7) are characterized by a porous dendrite-like microstructure. Fe,
N. A. Zhuk   +10 more
doaj   +1 more source

Complex Iridium Oxides Converge In Structure And Reactivity During Acidic Oxygen Evolution Electrocatalysis

open access: yesAdvanced Energy Materials, EarlyView.
Ir‐based double perovskites restructure during acidic oxygen evolution electrocatalysis through dissolution of non‐Ir cations and convergence toward IrOx active‐site motifs with similar structure and intrinsic activity across compositions. The identity of the dissolving cations controls dissolution and surface reconstruction kinetics, clarifying how ...
Harrison H. Lippie   +5 more
wiley   +1 more source

Strain engineered pyrochlore at high pressure [PDF]

open access: yesScientific Reports, 2017
AbstractStrain engineering is a promising method for next-generation materials processing techniques. Here, we use mechanical milling and annealing followed by compression in diamond anvil cell to tailor the intrinsic and extrinsic strain in pyrochlore, Dy2Ti2O7 and Dy2Zr2O7.
Dylan R. Rittman   +6 more
openaire   +3 more sources

Topological thermal Hall effect of magnetic monopoles in the pyrochlore U(1) spin liquid

open access: yesPhysical Review Research, 2020
“Magnetic monopole” is an exotic quantum excitation in three-dimensional U(1) spin liquid, and its emergence is purely of quantum origin and has no classical analog.
Xiao-Tian Zhang   +3 more
doaj   +1 more source

High Entropy–Driven Performance Enhancement in Perovskite Oxides for Energy Conversion and Storage Systems

open access: yesCarbon Energy, EarlyView.
High‐entropy perovskite oxides enable tunable structures and properties through multi‐cation disorder and entropy stabilization. This review summarizes advances in synthesis, structural and defect engineering, and their applications in OER/ORR, CO2RR, and electrochemical energy storage, highlighting in situ characterization and modeling that clarify ...
Obeylaw Moyo   +8 more
wiley   +1 more source

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