Results 141 to 150 of about 105,049 (336)

Dual‐Function Cosubstrates Enable Threonine Dehydrogenase‐Driven Chemoenzymatic Pyrrole Synthesis

open access: yesAngewandte Chemie International Edition, EarlyView.
Classical Knorr chemistry meets contemporary biocatalysis. Threonine dehydrogenase generates aminoacetone from l‐threonine, which is directly intercepted in a chemoenzymatic Knorr pyrrole synthesis. A dual‐function β‐dicarbonyl substrate serves as both pyrrole precursor and hydride acceptor for integrated NAD+ recycling, affording substituted pyrroles ...
Valentina Jurkaš   +8 more
wiley   +1 more source

Über Azofarbstoffe substituierter Pyrrole

open access: yes, 1911
ÜBER AZOFARBSTOFFE SUBSTITUIERTER PYRROLE Details: Zeitschrift für physiologische Chemie: 1.1877-20.1895 Hoppe-Seyler's Zeitschrift für physiologische Chemie: 21.1895- 112.1921 (-) Hoppe-Seyler's Zeitschrift für Physiologische Chemie (76) (a0002)
Fischer, Hans E. Bartholomäus
core  

Tunable electrochemical synthesis of pyrrole-based adsorbents

open access: yes, 2019
Pyrrole-based adsorbents were developed electrochemically using systems: (i) pyrrole-potassium bromide, (ii) pyrrole-KBr-an anionic surfactant sodium dodecyl sulfate, and (iii) pyrrole-KBr-NaDS-Prussian blue.
Avinash Kumar Pandey (8193285)   +1 more
core   +1 more source

Strain-Based Design, Direct Macrocyclization, and Metal Complexation of Thiazole-Containing Calix[3]pyrrole Analogues [PDF]

open access: yes
Coordination chemistry of ring-contracted porphyrins, such as subporphyrin and calix[3]pyrrole, has been largely unexplored due to the synthetic difficulty of their free-base analogues.
Kotaro, Shibata   +6 more
core   +2 more sources

Cyclo[4]pyrrole with α–β direct linkages

open access: yes
A cyclo[4]pyrrole bearing pyrrole C(α)–C(β) direct linkages, a contracted porphyrin analogue with no meso-carbon bridge, was synthesized from an oligoketone-related precursor.
Senboku, Hisanori   +8 more
core   +2 more sources

Pyrrole Compounds as Food Mutagens

open access: yes, 1987
The mutagenicity of some pyrrole compounds were studied. Pyrrole compounds tested showed the mutagenicity on bacterial tester strains. Pyrrole and N-methylpyrrole had positive mutagenic activity on the ret-assay with Bacillus subtilis strains H 17 (Ret+)
大村, 浩久   +6 more
core  

Biocatalysts for Peptide Geranylation With Linear and Cyclic Prenyl Groups

open access: yesAngewandte Chemie International Edition, EarlyView.
A combination of genome mining, synthetic biology, and biocatalytic assays revealed enzymes that install linear and cyclized prenyl moieties on ribosomally or chemically synthesized peptides. The promiscuity of both enzymes, while being specific for modification of C‐terminal tryptophans, enables enzymatic access to peptide terpenoid hybrids.
Sarolt Magyari   +10 more
wiley   +1 more source

Accelerating green heterocyclic synthesis: Convergence of AI, automation, and sustainable chemistry

open access: yesBulletin of the Korean Chemical Society, EarlyView.
Green heterocyclic synthesis and data‐driven tools such as AI, high‐throughput experimentation, continuous flow, and self‐driving laboratories have developed largely in parallel. This review connects them and asks how green metrics such as E‐factor and PMI might serve as explicit optimization targets rather than post‐hoc measures, toward sustainable ...
Noor Aisyah Ahmad Shah   +8 more
wiley   +1 more source

A nanoplatform that induces dual‐amino acid deprivation to reverse tumor immunosuppression and enhance metabolic immunotherapy

open access: yesBMEMat, EarlyView.
ZIF‐8‐based nanoparticles co‐delivering CB‐839 (glutaminase inhibitor) and 1‐MT (IDO1 inhibitor), dual‐targeting glutamine/tryptophan metabolism to induce immunogenic cell death, activate STING, block kynurenine production, reverse immunosuppression, and enhance cancer immunotherapy to suppress primary/distant tumors.
Wenli Ning   +10 more
wiley   +1 more source

Porous Carbon Materials for Carbon Dioxide Capture

open access: yesCarbon Energy, EarlyView.
This work aims to address the current status and challenges associated with the regulation of pore structures, as well as the influence of pore structures on CO2 capture. Systematic quantitative analysis of structure–property relationships, combined with machine learning approaches, can effectively evaluate the contributions of structural ...
Zhifu Liu   +6 more
wiley   +1 more source

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