A ThDP-dependent enzymatic carboligation reaction involved in Neocarazostatin A tricyclic carbazole formation [PDF]
, 2016 Acknowledgements This work was supported by grants from the National Natural Science Foundation of China (31570033 to Y. Y.) and the Leverhulme Trust-Royal Society Africa Award (AA090088 to K. K and H. D.).
Deng, Hai +5 more
core +1 more source
Frontiers in Plant Science, 2016 The enhanced CO2 release of illuminated leaves transferred into darkness, termed light enhanced dark respiration (LEDR), is often associated with an increase in the carbon isotope ratio of the respired CO2 (δ13CLEDR). The latter has been hypothesized to
Marco M Lehmann +8 more
doaj +1 more source
Human 2-Oxoglutarate Dehydrogenase Complex E1 Component Forms a Thiamin-derived Radical by Aerobic Oxidation of the Enamine Intermediate. [PDF]
, 2014 Herein are reported unique properties of the human 2-oxoglutarate dehydrogenase multienzyme complex (OGDHc), a rate-limiting enzyme in the Krebs (citric acid) cycle.
Ambrus, Attila +5 more
core +4 more sources
Dichloroacetate, the Pyruvate Dehydrogenase Complex and the Modulation of mESC Pluripotency. [PDF]
PLoS ONE, 2015 The pyruvate dehydrogenase (PDH) complex is localized in the mitochondrial matrix catalyzing the irreversible decarboxylation of pyruvate to acetyl-CoA and NADH.
Ana Sofia Rodrigues +6 more
doaj +1 more source
Electron bifurcation mechanism and homoacetogenesis explain products yields in mixed culture anaerobic fermentations [PDF]
, 2017 Anaerobic fermentation of organic wastes using microbial mixed cultures is a promising avenue to treat residues and obtain added-value products. However, the process has some important limitations that prevented so far any industrial application.
González-Cabaleiro, R. +4 more
core +4 more sources
On-Surface Decarboxylation Coupling Facilitated by Lock-to-Unlock Variation of Molecules upon the Reaction [PDF]
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2021, 2021 On-surface synthesis (OSS) involving relatively high energy barriers remains challenging due to a typical dilemma: firm molecular anchor is required to prevent molecular desorption upon the reaction, whereas sufficient lateral mobility is crucial for subsequent coupling and assembly.
arxiv
Current Methods for Hyperpolarized [1-13C]pyruvate MRI Human Studies [PDF]
, 2023 MRI with hyperpolarized (HP) 13C agents, also known as HP 13C MRI, can measure processes such as localized metabolism that is altered in numerous cancers, liver, heart, kidney diseases, and more. It has been translated into human studies during the past 10 years, with recent rapid growth in studies largely based on increasing availability of ...
arxiv +1 more source
MicrobiologyOpen, 2021 The gut microbiome composition is influenced by many factors including environmental exposures. Here, we investigated the effect of thirdhand cigarette smoke (THS) and exposure age on gut microbiome diversity.
Li He +9 more
doaj +1 more source
Characteristics of C-4 photosynthesis in stems and petioles of C-3 flowering plants [PDF]
, 2002 Most plants are known as C-3 plants because the first product of photosynthetic CO2 fixation is a three-carbon compound. C-4 plants, which use an alternative pathway in which the first product is a four-carbon compound, have evolved independently many ...
A Ben Zioni +29 more
core +1 more source
Radical-induced Hetero-Nuclear Mixing and Low-field $^{13}$C Relaxation in Solid Pyruvic Acid [PDF]
, 2022 Radicals serve as source in dynamic nuclear polarization, but may also act as polarization sink. If the coupling between the electron spins and different nuclear reservoirs is stronger than any of the reservoirs' couplings to the lattice, radicals can mediate hetero-nuclear mixing.
arxiv +1 more source