Results 131 to 140 of about 182,803 (252)

Orchestrating Anion–π+ Interactions to Accelerate Metal‐Free Room‐Temperature Phosphorescence

Angewandte Chemie, EarlyView.
Tuning anion–π+ interactions in pyridinium iodide contact ion pairs enables ultrafast metal‐free room‐temperature phosphorescence (540–605 nm) with radiative rates up to 5.2×105 s−1. Strong iodide→π+ charge‐transfer coupling, enhanced spin–orbit interactions, and dynamic ion‐pair organization accelerate intersystem crossing and emission, establishing ...
Eetu Hakkarainen, Corentin Montagne, Hao‐Cheng Lin, Chen‐Yu Lin, Khai‐Nghi Truong, Po‐Yu Chen, Anton Nechaev, Fabien B. L. Cougnon, Igor O. Koshevoy, Toni Eskelinen, Hao‐Wu Lin, Pi‐Tai Chou, Andrey Belyaev   +12 more
wiley   +2 more sources

Highly Stabilized Ni‐Rich Cathodes Enabled by Artificially Reversing Naturally‐Formed Interface

Advanced Energy Materials, Volume 15, Issue 11, March 18, 2025.
The application of Ni‐rich cathode materials is obstructed by interfacial and structural instability. This work proposes a facile and cost‐effective Al‐based vapor‐phase surface reaction strategy on Ni‐rich cathode to maintain its structural integrity from near‐surface to bulk.
Jinjin Ma, Yipeng Sun, Duojie Wu, Changhong Wang, Ruizhi Yu, Hui Duan, Matthew Zheng, Ruying Li, M. Danny Gu, Yang Zhao, Jigang Zhou, Xueliang Sun   +11 more
wiley   +1 more source

In Vitro Selection of Functional Neoproteins Containing Highly Fluorinated Cores

Angewandte Chemie, EarlyView.
The generation of neoproteins—functional proteins containing unnatural amino acids—is a key goal in synthetic biology. We develop a platform to discover neoproteins with specified bioactivity from trillion‐member sequence libraries, using genetic code reprogramming, in vitro selection and microwave peptide synthesis.
Adam Beattie, Alexander Vinogradov, Chikako Okada, Toru Sengoku, Takayuki Katoh, Hiroaki Suga   +5 more
wiley   +2 more sources

Free Charge Generation in Organic Photoconversion Devices–the Impact of Electrostatic Potentials

Advanced Energy Materials, EarlyView.
Free charge generation in organic photovoltaic and photodetector devices typically requires an external driving force to separate bound excitons formed upon photoexcitation. This review details how electrostatic potentials, arising from molecular charge distributions in organic semiconductors, can impact interfacial energetic landscapes and promote ...
Emily J. Yang, Song Yi Park, Vick Y. Qiu, Ji‐Seon Kim   +3 more
wiley   +1 more source

Direct Observation of Radical‐Mediated Oxide‐to‐Alloy Transformation in Solution Under Pulsed Laser Irradiation

Angewandte Chemie, EarlyView.
Time‐resolved in situ x‐ray absorption spectroscopy and DFTB‐based molecular dynamics simulations identify direct hydrogen atom transfer from ethanol to lattice oxygen as the elementary step of laser‐driven reduction in NiCo2O4. While this transfer is facile, the subsequent release of lattice oxygen is entropy‐driven and becomes accessible only at ...
Woo Hyeok Kim, Sieon Jung, Ahreum Min, Raja Arumugam Senthil, Juhyeon Park, Wonil Seo, Seung Yeon Choi, Junu Bae, Cheolhee Yang, In‐hui Hwang, Joonghan Kim, Tae Wu Kim, Myong Yong Choi   +12 more
wiley   +2 more sources

Descriptor‐Guided Computational Screening of Non‐Fullerene Acceptor Cores for Organic Solar Cells

Advanced Energy Materials, EarlyView.
We screen over 4000 non‐fullerene acceptors using their ionization energy, electron affinity, quadrupole, and dipole moments to select the top‐ten candidates for a given donor polymer. The workflow recovers known high‐performance motifs and reveals how molecular components influence material properties.
Kun‐Han Lin, J. Terence Blaskovits, Wenlan Liu, Shu‐Yi Hu, Kuei‐Jhong Lin, Sandeep Sharma, Julien Gorenflot, Martin Heeney, Frédéric Laquai, Denis Andrienko   +9 more
wiley   +1 more source

Rational Design of a Synthetic Galliphore for the Diagnostic Nuclear Imaging and Treatment of Bacterial Infections

Angewandte Chemie, EarlyView.
KO‐NH2 is a synthetic metallophore that preferentially binds Ga3+ over Fe3+ and is recognized by bacterial transporters. Photocrosslinking identifies CirA and Fiu as key uptake proteins in E. coli. KO‐NH2 enables targeted imaging and treatment of E. coli soft tissue infections.
Phuong Nguyen Tran, Axia Marlin, Edith K. Amason, Marie Huynh, Hannah Carlisle, Eszter Boros   +5 more
wiley   +2 more sources

Efficient Pulsed Quadrupole

, 2016
In order to raise the focusing gradient in case of bunched beam lines, a pulsed quadrupole was designed. The transfer channels between synchrotrons as well as the final focusing for the target line are possible applications.
Petzenhauser, I., Blell, U., Spiller, P., Tenholt, C.   +3 more
core  

Interplay between the quadrupole-quadrupole and spin-orbit interactions in nuclei

, 2020
The interplay between the quadrupole-quadrupole and spin-orbit interactions in nuclei is analyzed in an SU͑3͒ basis. Results for two ds-shell nuclei 20 Ne and 22 Ne and one f p-shell nucleus 44 Ti are considered for realistic values of the ...
J P Draayer, P O Hess, J G Hirsch, C Vargas   +3 more
core  

Mechanistic Origin of Capacity Limitation in Sidorenkite‐Type Na3‐xFe(PO4)(CO3) Carbonophosphate Cathodes for Na‐Ion Batteries

Advanced Energy Materials, EarlyView.
The potential–capacity profile reveals a one‐electron limitation in sidorenkite Na3−xFe(PO4)(CO3). Structural analysis shows that Fe4+ formation induces lattice strain and suppresses electronic conductivity, blocking further Na extraction. These findings establish key design rules: preserve crystallinity, avoid Jahn–Teller–active d4 configurations, and
Samuel Franz Gatti, Simon Krarup Steensen, Łukasz Kondracki, Haolan Fang, Moulay Sougrati, Ivano E. Castelli, Andrea Testino, Sigita Trabesinger   +7 more
wiley   +1 more source