Results 111 to 120 of about 276 (121)
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Quasireversible Maximum in Cathodic Stripping Square-Wave Voltammetry
Electroanalysis, 1999The apparent reversibility of a redox reaction, together with the position of the quasireversible maximum, depend on the single complex kinetic parameter K, which is defined through the standard rate constant, diffusion coefficient of the ligand and frequency of the SW signal.
Mirčeski, Valentin, Lovrić, Milivoj
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Performance Evaluation, 1998
Abstract This paper considers queueing networks comprised of quasireversible components linked by state-dependent routing. It is shown that the product form property is valid despite the state-dependent nature of the routing process. From this observation Norton's theorem for queueing networks is extended to include queueing networks with non-product
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Abstract This paper considers queueing networks comprised of quasireversible components linked by state-dependent routing. It is shown that the product form property is valid despite the state-dependent nature of the routing process. From this observation Norton's theorem for queueing networks is extended to include queueing networks with non-product
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Electrochimica Acta, 2013
Abstract Theory for the influence of uncompensated solution resistance on quasi-reversible charge transfer at an arbitrary rough electrode is developed. Detailed model analysis is performed for a finite fractal power spectrum; characterized with fractal dimension, lowest, highest cutoff-length scales of roughness and topothesy length (width) of the ...
Rama Kant +2 more
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Abstract Theory for the influence of uncompensated solution resistance on quasi-reversible charge transfer at an arbitrary rough electrode is developed. Detailed model analysis is performed for a finite fractal power spectrum; characterized with fractal dimension, lowest, highest cutoff-length scales of roughness and topothesy length (width) of the ...
Rama Kant +2 more
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Electroanalysis, 2009
AbstractAn experimental investigation of quasireversible maximum (QRM) of azobenzene on mercury electrode by two methods, i.e., traditional square‐wave voltammetry (SWV) and fast Fourier transformed square‐wave voltammetry (FT‐SWV), was presented, and the influence factors on QRM of FT‐SWV were discussed.
Lishi Wang +3 more
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AbstractAn experimental investigation of quasireversible maximum (QRM) of azobenzene on mercury electrode by two methods, i.e., traditional square‐wave voltammetry (SWV) and fast Fourier transformed square‐wave voltammetry (FT‐SWV), was presented, and the influence factors on QRM of FT‐SWV were discussed.
Lishi Wang +3 more
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Talanta, 1992
The reductive electrochemistry of methylocobalamin in nonaqueous solution is typical of many electrochemical mechanisms in that the initial electron transfer at the electrode is followed by a fast chemical reaction. The rate constant of the following chemical step, methyl radical cleavage, was measured by double potential step chronoamperometry to be ...
Q, Huang, D K, Gosser
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The reductive electrochemistry of methylocobalamin in nonaqueous solution is typical of many electrochemical mechanisms in that the initial electron transfer at the electrode is followed by a fast chemical reaction. The rate constant of the following chemical step, methyl radical cleavage, was measured by double potential step chronoamperometry to be ...
Q, Huang, D K, Gosser
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Electrochimica Acta, 1982
Abstract The method of orthogonal collocation is used to discretize the differential equations describing quasireversible electrode processes under conditions of potential scanning. The resulting set of ordinary differential equations is solved to give numerical simulations. The numerical values are compared to literature data.
Bernd Speiser +2 more
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Abstract The method of orthogonal collocation is used to discretize the differential equations describing quasireversible electrode processes under conditions of potential scanning. The resulting set of ordinary differential equations is solved to give numerical simulations. The numerical values are compared to literature data.
Bernd Speiser +2 more
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A probabilistic look at networks of quasi-reversible queues
IEEE Transactions on Information Theory, 1981It is known that quasi-reversible queueing systems [see \textit{F. P. Kelly}, Reversibility and stochastic networks (1979; Zbl 0422.60001)] exhibit ''mysterious'' and ''surprising'' properties whose proofs have little intuitive basis. The author introduces probabilistic arguments to explain the product form of the equilibrium line length probabilities,
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QUASIREVERSIBILITY OF QUEUING SYSTEMS WITH NONSTANDARD BATCH CUSTOMER MOTION
Problems of Physics, Mathematics and Technics, 2022openaire +1 more source
Theory for a homogeneous reaction following a quasireversible electrode reaction
The Journal of Physical Chemistry, 1972openaire +1 more source