Results 11 to 20 of about 113 (96)
Quasireversible cyclic voltammetry of a surface confined redox system: a mathematical treatment
By removing complications caused by transport, the surface confinement of substrate and product members of a redox pair simplifies the relationships governing transient electrode reactions, often permitting a mathematical solution even when the voltammetry is kinetically controlled.
Jan C Myland, Keith B Oldham
exaly +2 more sources
In this article, the inverse time problem is investigated. Regarding the ill-posed linear problem, utilize the quasi-reversibility method first. This problem has been regularized and after that provides an iterative regularizing strategy for noisy input ...
Rahimi Mostafa, Rostamy Davood
doaj +1 more source
The Quasi-Reversibility Regularization Method (Q-RRM) provides stable approximate solution of the Cauchy problem of the Helmholtz equation in the Hilbert space by providing either additional information in the Laplace-type operator in the Helmholtz ...
Benedict Barnes +3 more
doaj +1 more source
Lorenz Bifurcation: Instabilities in Quasireversible Systems
Summary: We describe the two generic instabilities which arise in quasireversible systems and show that their normal forms are the well-known real Lorenz equations and the Maxwell-Bloch equations. We present for the first time analytic predictions for the appearance of Lorenz chaos and we describe a simple mechanical system which experimentally ...
Clerc Gavilán, Marcel +2 more
openaire +1 more source
The Cauchy problem of the modified Helmholtz-type equation is severely ill-posed, i.e., the solution does not depend continuously on the given Cauchy data. Thus the regularization methods are required to recover the numerical stability. In this paper, we
Hong Yang, Yanqi Yang
doaj +1 more source
A theoretical analysis of reversible and quasireversible electrode reactions of a dissolved redox couple under conditions of the novel technique of differential square-wave voltammetry (DSWV) is presented. The technique is recently introduced as a hybrid form between differential pulse voltammetry (DPV) and square-wave voltammetry (SWV) as the two most
Dariusz Guziejewski +3 more
openaire +2 more sources
Boron‐Difluoride Curcuminoid Dendrimers as Organic Near‐Infrared Photothermal Materials
Dendritic boron‐difluoride curcuminoids are presented that show near‐infrared emission and high rates of nonradiative decay. Water‐dispersible nanoparticles containing these materials were prepared that show near‐infrared emission and photothermal properties, with photothermal conversion efficiencies of 58%–66%. Organic molecules with absorption in the
Angelica Sevilla‐Pym +4 more
wiley +1 more source
Metal Organic Framework‐Modified Carbon Fiber Microelectrodes for Enhanced Neurochemical Detection
In this work, we modified carbon fiber microelectrodes (CFMEs) with the iron‐based metal organic framework MIL‐88B(Fe) and examined their performance using fast scan cyclic voltammetry (FSCV). The modification enhanced the dopamine signal at low concentrations and enabled consistent nanomolar detection, while maintaining clear peak separation in ...
Teflah Alshammari +4 more
wiley +1 more source
A Sustainable and Low‐Cost Zn‐Lignosulfonate Redox Flow Battery
A cost‐effective Zn/lignosulfonate (NaLS) hybrid flow battery using 20 kDa NaLS delivers 3.52 Ah L−1 at 30 mM, with an average discharge voltage of 1.01 V, outperforming smaller NaLS. This sustainable design leverages industrial and bio‐based lignosulfonates, cheaper size exclusion membrane, and abundant Zn for ecofriendly, scalable energy storage ...
Athul Seshadri Ramanujam +3 more
wiley +1 more source
Redox‐Dependent Luminescence in a Pentavalent Uranyl Complex
Redox‐dependent luminescence in a molecular pentavalent uranyl complex supported by a pyridine dipyrrolide pincer ligand is presented. Electrochemical and chemical reduction of the uranyl(VI) species provides a stable uranyl(V) complex that emits blue light from a high‐energy excited state. The anti‐Kasha emission is credited to the presence of “nested”
Leyla R. Valerio +5 more
wiley +1 more source

