Results 31 to 40 of about 113 (96)
A redox‐active polyimide porous organic polymer, PI(MTA–PDA), operates as a lithium‐ion battery cathode through a three‐electron imide carbonyl redox process. Its carbonyl‐rich, π‐conjugated and microporous framework enables reversible capacities near 230 mAh g−1, about 95% capacity retention over 600 cycles, and good rate capability up to 4 C. Organic
Alem Gebrelibanos Hailu +3 more
wiley +1 more source
High Potential Isoindoline‐Based Nitroxides Posolytes for Aqueous Organic Redox Flow Batteries
A convenient metal‐catalyzed [2 + 2 + 2] cycloaddition enables the synthesis of isoindoline‐based nitroxides as new posolytes for aqueous organic redox flow batteries. The cationic PPO exhibits a 220 mV higher oxidation potential than 4‐TMA‐TEMPO, 3 M solubility in 1 M NaCl, and a cell voltage of 1.56 V.
Karim Boutamine +8 more
wiley +1 more source
Stabilized quasi-reversibility method for a class of nonlinear ill-posed problems
In this paper, we study a final value problem for the nonlinear parabolic equation $$displaylines{ u_t+Au =h(u(t),t),quad ...
Nguyen Huy Tuan, Dang Duc Trong
doaj
Asymmetrically substituted Jäger‐type ligands and their Fe(II) complexes show additive optical and redox trends. Ketone donors promote spin‐crossover while ester donors stabilize the high‐spin state, yet bulk materials display unexpected transitions governed by molecular symmetry and packing. A series of seven new asymmetrically substituted Jäger‐type (
Constantin Schreck +4 more
wiley +1 more source
Mind the Solid Side: Electrochemical Thermodynamics, Kinetics, and Hysteresis in Energy Materials
This mini‐review presents the electrochemical thermodynamics, kinetics, and hysteresis in solid‐to‐solid electrochemical phase transformation under three distinct categories of regular solutions, Fickian diffusion models, and spinodal decomposition. It highlights the role of electrochemical modeling combined with galvanostatic and cyclic voltammetry ...
Keyvan Malaie
wiley +1 more source
A novel vanadium–titanium redox flow battery is demonstrated using V5+/V4+ and Ti3+/Ti4+ electrolytes, delivering stable cycling (>150 cycles), high coulombic efficiency (>95%), and low‐cost operation. Ionic‐liquid‐based catholytes and SPEEK membranes further enhance sustainability while maintaining an appreciable electrochemical performance.
Kalyan Sundar Krishna Chivukula +1 more
wiley +1 more source
This review highlights the coordination chemistry of NHC bis‐phenolate ligands with metal centers, emphasizing structural features, redox and optical properties, and catalytic applications. Key roles in polymerization, nitrogen reduction catalysis, and small molecule activation are discussed, showcasing the versatility and potential of [OCO]M complexes
Johanna Frey +3 more
wiley +1 more source
The influence of the potential pulse height of square-wave voltammetry (SWV) (i.e., the SW amplitude) is studied for a variety of quasireversible electrode mechanisms, including a simple solution-phase electrode reaction at a planar or spherical electrode, a solution phase electrode reaction coupled with a reversible follow-up chemical reaction, and a ...
Mirceski, V +3 more
openaire +2 more sources
The modification of the glassy carbon electrode with carbon quantum dot‐titanium dioxide‐manganese dioxide (CQD‐TiO2–MnO2) and the immobilization of the aptamer have significantly enhanced the performance of the newly developed aptasensor. This improvement has led to better electrochemical performance, an increased electroactive surface area ...
Indiphile Nompetsheni +3 more
wiley +1 more source
A manganese oxide (MnO2) nanoparticle‐modified screen‐printed carbon electrode enables sensitive and simultaneous electrochemical detection of carbamazepine and sulfamethoxazole in wastewater, demonstrating improved oxidation signals and enhanced analytical performance for pharmaceutical monitoring. The extensive use of pharmaceutical compounds poses a
Pheladi Lizzy Mokaba +5 more
wiley +1 more source

