Results 171 to 180 of about 58,142 (306)

Developing a Suitable Anion Exchange Layer Structure for Pure–Water Fed Bipolar Membrane CO2 Electrolysis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A porous anion exchange layer (AEL) is implemented in a forward‐biased bipolar membrane CO2 electrolyzer to suppress carbonate crossover, support CO2 regeneration and maintain cathode alkalinity. Two fabrication strategies are compared—deposition on a silver gas diffusion electrode (GDE) or on the CEM—showing that a porous AEL‐coated GDE provides the ...
Henning Lorenz   +3 more
wiley   +1 more source

Expanded Scorpionate and Siderophore‐Inspired Ligands: From Foundational Designs to Modern Applications

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The concept of scorpionate ligands has evolved significantly since the introduction of tris(pyrazolyl)borate. By integrating a biological supramolecular ligand scaffold with the classic scorpionate architecture, researchers have made notable strides in mimicking the active sites of nitrogenase and advancing homogeneous catalysis.
Austin Winfield Medley   +1 more
wiley   +1 more source

Metal‐Free and Solvent‐Free CO2 Fixation Into Cyclic Carbonates Catalyzed by a Deferiprone‐Derived Bifunctional System

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A simple bifunctional organocatalyst derived from the FDA‐approved chelator deferiprone efficiently promotes CO2 fixation into cyclic carbonates. By combining epoxide activation and nucleophilic ring opening in a single scaffold, quantitative conversions are achieved under mild, metal‐free conditions. High activity, broad substrate scope, and excellent
Erika Saccullo   +6 more
wiley   +1 more source

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