Helical Dinaphthothiophenes Reveal the Limits of BN‐Based Optical Tuning
A BN‐7‐thia[5]helicene and an analogous CC‐7‐thia[5]helicene were prepared in two efficient synthetic routes. Their geometrical structures barely differ, which allows us to judge the influence of the BN substitution on the electronic properties. The formal substitution of carbon–carbon (CC) units by boron–nitrogen (BN) units is an established strategy ...
Yannik Appiarius +7 more
wiley +1 more source
Design and synthesis of hydrolyzable coumarin-naphthalimide dual probes for NIR fluorescence detection and selective photodynamic activity in cancer cells. [PDF]
Zúñiga-Salazar B +9 more
europepmc +1 more source
Click Bioconjugation of Aza‐BODIPY Fluorophores to LfcinB Peptides for Improved Biocompatibility
Click bioconjugation attaches NIR aza‐BODIPY fluorophores to LfcinB‐derived anticancer peptides via CuAAC and thiol‐maleimide chemistry. Conjugates exhibit improved predicted solubility while retaining strong NIR absorption (703–730 nm). Peptide‐aza‐BODIPY conjugates induce apoptotic morphology in HeLa cancer cells.
A. Verónica Rodríguez‐Mayor +6 more
wiley +1 more source
Crystal structure of 1-phenylsulfonyl-2-propanone, C9H10O3S
Zukerman-Schpector J. +3 more
doaj +1 more source
Efficient Solvent-Free Synthesis of Cyclic Carbonates via CO<sub>2</sub> Fixation Using Metal-Free Guanylated Cyclophosphazene Organocatalysts. [PDF]
Douglas-Gallardo OA +5 more
europepmc +1 more source
Bio-oleo Para Emprego Como Fonte De Insumos Para A Indústria Quimica E Métodos Para Sua Obtenção
BIO-ÓLEO PARA EMPREGO COMO FONTE INSUMOS PARA A INDÚSTRIA QUIMICA E MÉTODOS PARA SUA OBTENÇÃO, Sendo o Bio-óleo obtido por pirólise em atmosfera de hidrogênio.BR9804166 (B1); BR9804166 (A)C10B47/02C10G47/14C10B47/02C10G47/14BR19989804166C10B47/02C10G47 ...
Rocha Jose Dilcio, Luengo Carlos Alberto
core
An efficient gold‐catalyzed intramolecular cyclization of indole‐tethered alkynes using AgNTf2 as an additive has been developed, which provides bioactive exocyclic alkenyl tetrahydrocarbazoles with up to 85% yield. Control experiments and DFT studies indicate that the reaction proceeds via a 6‐exo‐dig cyclization pathway, with gold acetylide complexes
Haibo Mei +4 more
wiley +1 more source
Study of the Gas-Phase Pyrolysis of N-Aryl-3-Oxobutanamides and the 2-Aryl Hydrazone Derivatives: A Novel Computational Approach Including DFT with Multivariant Analysis. [PDF]
Ipanaque-Chávez R +4 more
europepmc +1 more source
Palladium(II)‐catalyzed intramolecular C─H alkenylation of cinnamides allows the atroposelective synthesis of axially chiral 4‐arylquinolones, with the chirality being installed by ring formation. DFT studies have shown that the reaction proceeds by prior activation of the alkene and the enantioselectivity is determined during the β‐hydride elimination
Brenda Fundora +8 more
wiley +1 more source
Torralba M. C. +4 more
doaj +1 more source

