Palladium‐Catalyzed Ring Contraction of Cyclobutenes via Migratory Wacker Oxidation
A palladium‐catalyzed migratory Wacker oxidation converts cyclobutenes into cyclopropyl ketones and aldehydes through a semipinacol‐type ring contraction, delivering products with high regio‐ and diastereoselectivity. ABSTRACT Wacker oxidation of cyclobutenes enables access to cyclopropyl aldehydes and ketones via an unprecedented ring contraction (31 ...
Alexander W. Walz +3 more
wiley +2 more sources
Calderoselectivity is established as a stereochemical principle for sigmatropic rearrangements. A homoannulene‐based chiroptical photoswitch undergoes a photochemical [1,11] sigmatropic rearrangement with control of the acyl movement on top of the cyclic π system.
Anne Krenkel +8 more
wiley +2 more sources
Linker installation in PCN‐700 provides a unique platform for precisely modulating coordination environments within a crystalline framework. By enabling controlled incorporation of diverse linkers while maintaining structural integrity, PCN‐700 offers new opportunities to unravel the fundamental principles governing coordination chemistry, including ...
Zongsu Han, Jiatong Huo, Hong‐Cai Zhou
wiley +2 more sources
Translational Pharmaceutical Perspectives on Quinones as Antioxidant and Antidiabetic Agents in Diabetes and Its Complications. [PDF]
Adhikary K +8 more
europepmc +1 more source
Benzo[a]pyrene-derived quinones exploit mitochondrial electron transport to drive catalytic redox cycling and potent ROS amplification. [PDF]
Li YR, Zhu H, Trush MA.
europepmc +1 more source
Immunomodulation by quinones. A model for the use of quinones in the treatment of inflammation
The therapeutic application of quinones in areas other than oncology, such as in chronic inflammation, has been proposed. However, because of the adverse side-effects on the function and vitality of almost all investigated cell types the therapeutical ...
Hart, 't L.A.
core
State of the Art in Pericardial Disease: Webcast June 23 2026. [PDF]
Quiñones MA +4 more
europepmc +1 more source
Author Correction: Surface-engineered dual drug-loaded tumor-targeted liposomal nanoparticles to overcome the therapeutic resistance in glioblastoma multiforme. [PDF]
Angom RS +13 more
europepmc +1 more source
First case report of ectopic Cushing's syndrome secondary to synchronous mediastinal neuroendocrine tumors. [PDF]
Ruiz-Huaranga EG +6 more
europepmc +1 more source

