Results 151 to 160 of about 16,770 (249)

Cage‐Type Porous Organic Salts as Ship‐in‐a‐Bottle Nanoreactors for Light‐Transparent and Reusable Molecular Photocatalysts

open access: yesAngewandte Chemie, EarlyView.
Light‐transparent, cage‐type porous organic salts (POSs) function as nanoreactors that heterogenize molecularly defined photocatalysts through size exclusion. Photocatalysts are encapsulated intact during crystallization, providing confined yet accessible reaction fields under visible light without catalyst modification.
Kazuki Shiga   +5 more
wiley   +2 more sources

Single‐Atom Iron‐Catalyzed Oxidative Esterification: From Methylarenes to the Upcycling of Polystyrene and Lignin‐Derived Feedstocks

open access: yesAngewandte Chemie, EarlyView.
Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma   +8 more
wiley   +2 more sources

Quantitative Photo‐Reforming of Biomass to CO Spurred by In Situ Protonation of Carbon Dioxide Radical Anions

open access: yesAngewandte Chemie, EarlyView.
A “two‐in‐one” photoreduction strategy enabled by electron‐rich yolk Cd species both remote from and adjacent to sulfur vacancies is delivered to be ultraselective for the reduction of O2 and •CO2− in situ formed on the shell Bi2S3 composition (hole) by water oxidation and oxidative C–C cleavage of various biomass organic acids, furnishing CO with > 99%
Tengyu Liu   +5 more
wiley   +2 more sources

Gold(III) Semiquinone Complexes: Synthesis, Structure, and Application in Photocatalysis

open access: yesAngewandte Chemie, EarlyView.
Au(III) catecholate complexes engage into electron donor acceptor (EDA) interactions with aryldiazonium salts, enabling single‐electron transfer under green light irradiation. Ligand‐centered one‐electron oxidation to stable semi‐quinone complexes provides a new platform for standalone Au(III) photoredox catalysis, as substantiated by the C–H arylation
Miguel A. Gonzálvez   +8 more
wiley   +2 more sources

Joe Quinones - HSI Speaker

open access: yes
John Quinones' presentation for the HSI Speaker SeriesAngelo State ...
Quiñones, John
core  

Effect of quinones to flk cells.

open access: yes, 2009
Many of recently used chemotherapeutic agents have a quinoidal structure. It is supposed that the main mechanism of antitumour aziridinyl substituted benzoquinones is their two-electron reduction to alkylating products.
Dirginčiutė, Vaidilutė,
core  

Recent Trends in Heterocyclic Quinones

open access: yes, 2012
Hetrocyclic quinones are plant secondary metabolites that have found numerous applications. Resulting from exhaustive studies of the past decades, their biological activity in relation to a variety of diseases was reported and countless attempts for ...
Erdelyi, Mate,, Endale, Milkyas,
core  

The Synthesis and Reactivity of Vitamin E Quinones

open access: yes, 2017
Vitamin E has been the subject of numerous studies over the last nine decades since its discovery. Still, the biological activity of vitamin E is not completely understood.
Krueger, Nicholas W.
core  

Photocatalytic Solar Hydrogen Peroxide Production on Donor+Acceptor Linear Polymer Semiconductor Powders Reconfigurable by H‐Bonding and π‐Stacking Interactions

open access: yesAngewandte Chemie International Edition, EarlyView.
A linear polymer, poly(2,3‐dihydroxynaphthalene), when insolubilized, leads to self‐assembly into a hydroquinone–quinone donor+acceptor semiconducting architecture through H‐bonding and π‐stacking interactions. The polymer behaves as a heterogeneous photocatalyst in water for H2O2 production via water oxidation and O2 reduction under visible light.
Koki Yoshida   +4 more
wiley   +1 more source

Toward Chromoselective Transformations in Biological Systems: Perspectives and Challenges

open access: yesAngewandte Chemie International Edition, EarlyView.
Controlling biological systems with small‐molecule chromophores has evolved into a powerful strategy and is applied from chemical biology to medicine. However, the complexity of in vivo systems cannot be matched by a single wavelength of light. Developing methods to combine and individually control multiple chromophores is crucial.
Nadja A. Simeth
wiley   +1 more source

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