Chemistry – A European Journal, EarlyView.A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang +4 more
wiley +1 more source
Apiol from Parsley Seeds as a Source for the Synthesis of Coenzyme Q<sub>0</sub> Propanoic Acid Conjugates with Amines Featuring Antioxidant Activity. [PDF]
ACS OmegaAdaeva OI +4 more
europepmc +1 more source
Cross‐Dehydrogenative Coupling Reactions With Redox‐Active Guanidine Reagents
Chemistry – A European Journal, EarlyView.ABSTRACT Cross‐dehydrogenative coupling (CDC) reactions are attractive and environmentally friendly ways to form new C‐C and other element‐element bonds. Here, we report the first CDC reactions triggered by a redox‐active guanidine reagent. N‐phenyltetrahydroisoquinoline and derivatives with electron‐donating and withdrawing substituents at the N ...
Petra Walter +2 more
wiley +1 more source
How Polyphenol Metabolites Spatiotemporally Reprogram Transcription Factors and Human Proteostasis: A Metabolite-Centric Framework. [PDF]
Curr Issues Mol BiolLastra JMP +4 more
europepmc +1 more source
Control of Gemcitabine Activity With Blue and Red Light
Chemistry – A European Journal, EarlyView.Treating cancer with chemotherapy is generally associated with many side effects, which can be addressed by selectively releasing the desired drugs with visible light. Sixteen new blue light‐activatable cytostatics were introduced, with the gemcitabine derivative exhibiting ideal properties.
Nils F. Kersten +6 more
wiley +1 more source
A Substrate-Dependent Redox Catalysis of Tellurenyl Species Involving Oxidation States +I, +II, and +IV. [PDF]
Inorg ChemHejda M +5 more
europepmc +1 more source
π‐Extended Salphen Scaffolds Enable CO2 Electroreduction and Singlet Oxygen Generation
Chemistry – A European Journal, EarlyView.New family of π‐extended salen ligands bearing phenylene bridge and tunable phenyl‐based substituents, and their corresponding boron difluoride complexes. Thanks to the extended π‐delocalization over the molecule, the ligands themselves show promising results in electrochemical CO2 reduction to CO, while the complexes act as efficient photosensitizers ...
Vincenzo Langellotti +10 more
wiley +1 more source
Redox State of Epigallocatechin Gallate Modulates Its Inhibition of Acrylamide Formation via the 3-Aminopropionamide Pathway. [PDF]
FoodsQi Y +5 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Reactions of 10‐mesityl‐1,8‐diphenylanthracene with DDQ/TfOH produced three products via sequential formation of a five‐ or seven‐membered ring. Unexpectedly, the triply cyclized product with a rubicene substructure was formed through cyclization involving 1,2‐methyl shift.
Tatsuhiro Sasaki +2 more
wiley +1 more source
Unique GNSS data from the Eastern Betic Tectonic Arc (Western Mediterranean), covering almost 28 years of campaign observations. [PDF]
Data BriefKhazaradze G +7 more
europepmc +1 more source