Results 171 to 180 of about 18,873 (207)
Modular and Stereoselective Synthesis of Cyclobutane β‐Amino Alcohols
Late‐stage functionalization and photoisomerization of 1,2‐azaborine leads to a general strategy for the synthesis of diversely substituted cyclobutane β‐amino alcohols. The relative stereochemistry of the resulting products is unambiguously defined by the stereospecific and stereoselective nature of the photoisomerization‐hydrogenation‐oxidation ...
Xinyu Yang +3 more
wiley +2 more sources
Cobalt-Catalyzed Enantioselective Intermolecular C-H Carboamination with Racemic Allenes. [PDF]
Verdhi LK, Cramer N.
europepmc +1 more source
An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri +5 more
wiley +2 more sources
The Mechanism of Visible‐Light Photochemical Rearrangements of Conjugated Amide Enolates
Visible light irradiation of extended enolates of N‐benzylamides leads to homolytic C─N Bond cleavage, generating a biradical. Computational and mechanistic studies suggest rapid radical recombination within a solvent cage to give either ring‐expanded or rearranged products. ABSTRACT Deprotonation of conjugated amides forms colored solutions of lithium
James Mortimer +3 more
wiley +1 more source
Regio-, Stereo-, and Enantioselective C(sp<sup>3</sup>)─H Monofluoroalkenylation via Photo-HAT/Nickel Dual Catalysis. [PDF]
Chen Y +6 more
europepmc +1 more source
A simple, modular, and unified strategy for the synthesis of reverse‐prenylated hexahydropyrrolo indole alkaloids has been developed. An unusual retrosynthetic disconnection allows for the late introduction of a side chain, which distinguishes many members of this class of natural products.
Daniel Schmelzer +2 more
wiley +1 more source
A vector dataset of the high-speed road network in Poland integrated with commissioning year information (1936-2023). [PDF]
Krasnodębska K +3 more
europepmc +1 more source
Phosphonium Ions as Activating Groups for the Selective Alkylation of Pyridines and Polyazines. [PDF]
Brunner DA +4 more
europepmc +1 more source
Computed tomography in the vivo anatomy of rabbit kidneys (<i>Oryctolagus cuniculus</i>). [PDF]
Dineva A +9 more
europepmc +1 more source

