To fully leverage the power of the ruthenium‐catalyzed trans‐hydrosilylation of propargyl alcohols, it was necessary to develop a practical and robust method for the activation of those products that carry the silyl group distal to the hydroxy substituent.
Paul Haf‐Moths +2 more
wiley +2 more sources
Selective N‐Functionalization of Pyrazoles
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek +2 more
wiley +1 more source
Regioselective and Stereodivergent C-H Functionalization of Internal Alkenes. [PDF]
Ryutov EA +5 more
europepmc +1 more source
Regiospecific, Diastereo- and Enantioselective Allylboration with Methylenecyclobutylboranes: Experimental and Computational Study. [PDF]
Mikhaylov OA +5 more
europepmc +1 more source
Konstruktion hochselektiver Bindungstaschen in UiO‐Typ‐MOFs mittels verbrückter Linker
Großer Gestaltungsspielraum: Es wird eine generelle Strategie für die präzise ortsspezifische Modifikation von UiO‐Typ‐MOFs mit funktionellen Gruppen vorgestellt. Durch den Einsatz von vorverbrückten oder pre‐connected Linkern werden gezielt taschenartige Poren für die molekulare Erkennung erzeugt, deren hohe Affinität gegenüber aliphatischen ...
Tobias Hennig +7 more
wiley +1 more source
Dual-Hybrid Treatment Approach for Peri-Implant Hard and Soft Tissue Stability. [PDF]
Gallucci GO +5 more
europepmc +1 more source
Catalytic Asymmetric Dearomative Cyclizations of Indolyldimethanols via Umpolung Strategy. [PDF]
Wu P +5 more
europepmc +1 more source
Formation of Highly Selective Binding Pockets in UiO‐Type MOFs From Bridged Linkers
Much room for design: We present a generalizable strategy for precisely modifying UiO‐type Metal‐organic frameworks with functional groups in a site‐specific manner. Through the use of pre‐connected linkers, pocket‐like pores for molecular recognition are generated.
Tobias Hennig +7 more
wiley +1 more source
Visible-light-mediated stereoselective construction of oxa-spiro bicyclohexanes via strain-release [2π + 2σ] cycloaddition. [PDF]
Singh S, Kim C, Lee D, Kim D, Hong S.
europepmc +1 more source
Biobased Cyclic Enoate Monomers: Enabling Intrinsically Crystalline, Chemically Recyclable, Ultratough Polymers. [PDF]
Wang Y +7 more
europepmc +1 more source

