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Recent Advances in Radical C–H Activation/Radical Cross-Coupling

Chemical Reviews, 2017
Research and industrial interest in radical C-H activation/radical cross-coupling chemistry has continuously grown over the past few decades. These reactions offer fascinating and unconventional approaches toward connecting molecular fragments with high ...
Hong Yi, Guoting Zhang, Huamin Wang
exaly   +2 more sources

Catalysis of Radical Reactions: A Radical Chemistry Perspective

Angewandte Chemie - International Edition, 2016
The area of catalysis of radical reactions has recently flourished. Various reaction conditions have been discovered and explained in terms of catalytic cycles. These cycles rarely stand alone as unique paths from substrates to products.
Armido Studer, Dennis P Curran
exaly   +2 more sources

A radical approach to radicals

Acta Crystallographica Section D Structural Biology, 2022
Nitroxide radicals are characterized by a long-lived spin-unpaired electronic ground state and are strongly sensitive to their chemical surroundings. Combined with electron paramagnetic resonance spectroscopy, these electronic features have led to the widespread application of nitroxide derivatives as spin labels for use in studying protein structure ...
Youjia Liu   +2 more
openaire   +2 more sources

Unveiling the Origins of Selective Oxidation in Single-Atom Catalysis via Co-N4-C Intensified Radical and Nonradical Pathways.

Environmental Science and Technology, 2022
Single-atom catalysts (SACs)-based peroxymonosulfate (PMS) systems are highly selective to the type of organic pollutants while the mechanisms remain ambiguous.
Mengxue Yang   +8 more
semanticscholar   +1 more source

Phosphorus radicals and radical ions

Dalton Transactions, 2022
This review presents the so far isolated and structurally characterized phosphorus-centered radicals and radical ions. Their reactivity, structure, and bonding are described.
Bindusagar Das   +2 more
openaire   +2 more sources

Commentary: When is a Radical not a Radical?

Free Radical Research, 1996
It is not commonly realised that symmetrical Fe(III) complexes are expected to have EPR spectra dominated by a symmetrical narrow line close to the free-spin g-value. The aim of this note is to stress that such features can be mistakenly identified as the spectra for stable organic radicals.
Declan P. Naughton, Martyn C. R. Symons
openaire   +3 more sources

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