Results 101 to 110 of about 408,195 (330)

Persistent Mono‐Oxo Bonding with Protactinium(V) Revealed in Highly Acidic Chloride Solutions

open access: yesAngewandte Chemie, EarlyView.
Protactinium(V) defies expectations. Its elusive mono‐oxo bond was revealed through a combination of extended X‐ray absorption fine structure (EXAFS) and X‐ray absorption near‐edge structure (XANES) analyses, as well as quantum chemical calculations. This bond persists even in 12 M HCl.
Melody Maloubier   +9 more
wiley   +2 more sources

Label‐Free and Immobilization‐Free Protein‐Binding Assays by Ultraviolet Transient Absorption Microscopy

open access: yesAdvanced Science, EarlyView.
A femtosecond UV pump–probe microscope resolves binding‐induced changes in protein excited‐state dynamics and converts these intrinsic contrasts into an equilibrium affinity readout. By probing tryptophan responses directly in solution, the approach enables quantitative determination of dissociation constants without labeling or immobilization ...
Jianghao Shen   +5 more
wiley   +1 more source

Stable BF2 Boracycles as Versatile Reagents for Selective Ortho C–H Functionalization

open access: yesAngewandte Chemie, EarlyView.
We report a robust, metal‐free and scalable synthesis of stable BF2 boracycles via directed ortho CH borylation, delivering isolable, shelf‐stable reagents without chromatographic purification. These BF2 boracycles exhibit unique and tunable reactivity, enabling highly selective ipso‐functionalization across a broad range of transformations.
Ganesh H. Shinde   +11 more
wiley   +2 more sources

Graph‐Theory Approach to Element Miscibility and Alloy Design

open access: yesAdvanced Science, EarlyView.
Graph and network theory enables pathway toward complex multiscale interactions between different elements for alloy design or interface engineering. Utilizing element's inherent properties and preferential interactivity, favorable mixed material formation, solubility and miscibility can be predicted.
Andrew Martin   +6 more
wiley   +1 more source

Engineered CAR‐NKT Extracellular Vesicles Suppress Tumor Progression and Enhance Antitumor Immunity

open access: yesAdvanced Science, EarlyView.
TM4SF1‐nanobody engineered CAR‐natural killer T–derived extracellular vesicles (CARTM4SF1‐EVs) provide a cell‐free alternative to CAR‐NKT therapy, achieving potent, targeted antitumor activity with reduced toxicity. CARTM4SF1‐EVs induce immunogenic cell death, remodel the tumor microenvironment, and enhance CD8⁺ T‐cell antitumor immunity.
Xiaopei Hao   +14 more
wiley   +1 more source

Growth Responses of Holcus lanatus L. (Velvet Grass) in Soils Contaminated with Cesium or Strontium

open access: yesSoil Systems
Radiocesium (r-Cs) and radiostrontium (r-Sr) released from nuclear accidents (e.g., Chornobyl, Fukushima) and routine operations (reactors, reprocessing) pose environmental and health concerns.
Bayezid M. Khan   +3 more
doaj   +1 more source

Measurements of radiocesium in animals, plants and fungi in Svalbard after the Fukushima Daiichi nuclear power plant disaster

open access: yesHeliyon, 2019
An earthquake struck the eastern part of Japan on March 11, 2011. The Fukushima Daiichi nuclear power plant was severely damaged by the earthquake and subsequent tsunami, leading to the emission of large amounts of radioactive pollutants, including 134Cs
Yoshihiro Mezaki   +8 more
doaj   +1 more source

Radioactive Decay

open access: yes, 2022
Radioactive decay of unstable atomic nuclei leads to liberation of nuclear binding energy in the forms of gamma-ray photons and secondary particles (electrons, positrons); their energy then energises surrounding matter. Unstable nuclei are formed in nuclear reactions, which can occur either in hot and dense extremes of stellar interiors or explosions ...
openaire   +3 more sources

Effect of thiols on beta 2-adrenoceptors in human mononuclear leucocytes [PDF]

open access: yes, 1988
The effect of the disulfide reducing agent dithiothreitol (DTT) and other thiols on binding of the beta-adrenoceptor antagonist (-)-125iodocyanopindolol (125ICYP) to human mononuclear leucocytes (MNL) was investigated.
Anhäupl, T.   +3 more
core  

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