Results 181 to 190 of about 131,276 (280)

The Role of Ion Size and π‐Interaction in Stabilizing Calix[4]arene Crown Ether Metal Complexes

open access: yesChemistry – A European Journal, Volume 31, Issue 40, July 17, 2025.
This work investigates MAXCalix's ability to coordinate alkali and alkaline earth metal ions, showing a preference for larger ions like Cs⁺. Structural analysis confirms that π‐interactions with benzene rings enhance stability, particularly for large cations that engage both rings.
Thomas Sittel   +5 more
wiley   +1 more source

Structural and Spectroscopic Trends in Alkali Tris(Acetato)Actinyl(VI) Complexes

open access: yesEuropean Journal of Inorganic Chemistry, Volume 28, Issue 19, July 12, 2025.
Alkali tris(acetato) actinyl(VI) complexes of different actinyls and identical alkali metals are mostly isostructural, showing a redshift in the symmetric actinyl stretch across the actinide series. With increasing alkali ionic radii, a progression to lower symmetry is observed that correlates with subtle changes in the electronic and vibrational ...
Julia Neumann   +2 more
wiley   +1 more source

Chiral Cobaltabis(dicarbollide) Catalysts Prepared Using a Silica Helical Nanoplatform for the Enantioselective Photooxidation of Aromatic Secondary Alcohols

open access: yesChemistry – A European Journal, Volume 31, Issue 37, July 2, 2025.
Chiral COSAN Nanocatalysts: Enantiopure silica COSAN‐Hybrid nanohelices have been prepared by electrostatic co‐assembly of achiral COSAN anions and silica hybrid nanohelices. Their optical activity was confirmed by CD and ROA measurements. These COSAN‐Hybrids are efficient and recoverable catalysts in the photooxidative kinetic resolution of aromatic ...
Hao Wang   +8 more
wiley   +1 more source

AAPM medical physics practice guideline 13.a: HDR brachytherapy, part B

open access: yesJournal of Applied Clinical Medical Physics, Volume 26, Issue 7, July 2025.
Abstract The goal of this report is to assist the clinical medical physicist in assuring that key quality standards and practice considerations are met to ensure safe, reliable, and reproducible high dose rate (HDR) brachytherapy (BT) treatment. This guideline has been developed to provide appropriate minimum standards for such services.
Susan L. Richardson   +8 more
wiley   +1 more source

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