Results 31 to 40 of about 151 (144)

Light‐Driven Out‐of‐Equilibrium Helicity Control in a Diarylethene–Helicene Photosystem

open access: yesAngewandte Chemie, EarlyView.
Distinct energy landscapes of different helicities in the open and closed states of a diarylethene–helicene photoswitch enable a light‐driven energy ratchet. Helix inversion occurs selectively in the closed form, and the resulting helicity is transferred and kinetically trapped upon ring opening, generating a persistent out‐of‐equilibrium chiral state ...
Eric Sidler   +3 more
wiley   +2 more sources

Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture

open access: yesAngewandte Chemie, EarlyView.
Force‐induced reversible on/off switching of circularly polarized luminescence is achieved with a rotaxane‐based supramolecular mechanophore. The mechanophore, featuring a chiral helicene luminophore, is incorporated as a first network cross‐linker into a double‐network organogel.
Keigo Nonaka   +10 more
wiley   +2 more sources

A Workflow to Accelerate Microstructure‐Sensitive Fatigue Life Predictions

open access: yesAdvanced Engineering Materials, EarlyView.
This study introduces a workflow to accelerate predictions of microstructure‐sensitive fatigue life. Results from frameworks with varying levels of simplification are benchmarked against published reference results. The analysis reveals a trade‐off between accuracy and model complexity, offering researchers a practical guide for selecting the optimal ...
Luca Loiodice   +2 more
wiley   +1 more source

Experimental Characterization and Constitutive Modeling of the Effect of Prior Inelastic Strain on the Viscoplastic Behavior of AD730 at 700 °C

open access: yesAdvanced Engineering Materials, EarlyView.
This study shows that superalloys used in aircraft engine disks become much more prone to deformation at high temperatures if they have been strained during manufacturing. This effect increases with the level of prior strain but eventually reaches a limit.
Fabio Machado Alves da Fonseca   +9 more
wiley   +1 more source

Special Section on Ratcheting [PDF]

open access: yesJournal of Pressure Vessel Technology, 2015
The design methods for pressure vessels and piping are based on the avoidance of potential modes of failure, such as collapse, excessive deformation, and cracking. Collapse and excessive deformation from a single load application are addressed by methods such as buckling analysis, primary stress analysis, and plastic limit analysis. For instance, limit
Reza, Adibi-Asl, Wolf, Reinhardt
openaire   +2 more sources

Progressive deformation behaviour of thin cylindrical shell under cyclic temperature variation using Combined Hardening Chaboche Model

open access: yesLatin American Journal of Solids and Structures
This study intends to evaluate thermal ratchetting deformation due to cyclic thermal loading along the axis of a smooth cylindrical shell. Two cases of progressive deformation behaviour are discussed for different loading methods.
Ashutosh Mishra   +2 more
doaj   +1 more source

Chemically Fueled Systems Chemistry Across Length Scales

open access: yesAdvanced Functional Materials, EarlyView.
Chemically fueled reaction cycles regulate processes through single and multiple catalytic sites on the molecular and assembly scale. This gives rise to unique kinetically controlled properties/functions like spatio‐temporal catalysis, oscillations, optical properties, and perform work.
Brigitte A. K. Kriebisch, Job Boekhoven
wiley   +1 more source

Implementing Demons and Ratchets [PDF]

open access: yesEntropy, 2017
Experimental results show that ratchets may be implemented in semiconductor and chemical systems, bypassing the second law and opening up huge gains in energy production. This paper summarizes or describes experiments and results on systems that effect demons and ratchets operating in chemical or electrical domains.
Orem, Peter, Orem, Frank
openaire   +2 more sources

Total fatigue life analysis of a nodular cast iron plate specimen with a center notch

open access: yesAdvances in Mechanical Engineering, 2017
The crack initiation and propagation phases of the fatigue life of a plate specimen with a center hole are analyzed. The local transient stress–strain relationship is investigated by means of finite element simulations with a nonlinear kinematic ...
Márton Gróza, Károly Váradi
doaj   +1 more source

Bioinspired Adaptive Surfaces for Intelligent Liquid Manipulation: Progressing From Passive and Active to Hybrid Strategies

open access: yesAdvanced Materials, EarlyView.
This review examines passive, active, and hybrid liquid manipulation strategies, highlighting hybrid approaches as an emerging route to reconcile energy efficiency with adaptive control. By actively reconstructing passive surfaces to store programmable interfacial energy, hybrid systems enable flexible yet low‐power liquid transport, with perspectives ...
Jiaqi Miao   +3 more
wiley   +1 more source

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