Concerted Proton and Electron Transfer in Heterogeneous Electrocatalytic CO2 Reduction
Concerted proton‐electron transfer (CPET) enables CO2‐to‐CO conversion with significantly reduced energy cost compared to cation‐stabilized pathways. Under controlled mass transport of proton donors, CPET dominates at modest potentials. At higher overpotentials, a cation‐stabilized pathway is found to dominate.
Seonmyeong Noh +3 more
wiley +1 more source
Ore Genesis of the Jiawula Pb-Zn-Ag Deposit, Inner Mongolia: Constraints from C-H-O Isotopes, In Situ S Isotopes, Fluid Inclusions, and LA-ICP-MS Analysis of Chalcopyrite. [PDF]
Li H, Mi W, Zuo Y, Xu J, Ren Z.
europepmc +1 more source
Re-Os isotope constraints on the ages of diamonds from Mwadui, Tanzania
openaire +2 more sources
A Homogeneously Catalyzed Paired Electrolytic Cell for Hydrogen Peroxide Production
Cu(tmpa) and Sn‐TMPyP are compatible and efficient catalysts for 2e−‐ORR and 2e−‐WOR, respectively, which have been employed to assemble an efficient paired electrochemical cell for H2O2 production. The presence of a carbonate buffer is essential to achieve a high activity in the anode compartment, while control over mass transport is essential for a ...
Caterina Trotta +7 more
wiley +1 more source
Reply to: Reassessing gas generation from oil thermal cracking associated with the Emeishan Large Igneous Province. [PDF]
Chen C +6 more
europepmc +1 more source
Lithium‐sulfur (Li‐S) batteries contain various NMR‐active nuclear isotopes, including 7Li, 6Li and 33S, which are sensitive to the different chemical reactions that occur during battery cycling. Herein, we use a combination of lithium and sulfur operando NMR spectroscopy to provide new insights at the molecular level, fundamental understanding being ...
Jana B. Fritzke +7 more
wiley +1 more source
Aerobic nitrogen cycle 100 My before permanent atmospheric oxygenation. [PDF]
Uveges BT +4 more
europepmc +1 more source
Chemical Metabolomics: Chemical Biology Tools for Advanced Metabolism Investigations
The human metabolism has been investigated for several millennia. The metabolome is known for a high complexity due to a large number of different metabolites that are present at different concentrations. Metabolomics has been developed as a field to investigate the entire human metabolome and to elucidate disease development mechanisms.
Alejandro Torregrosa‐Chinillach +4 more
wiley +1 more source
Localization of Organelle Proteins Using Data-Independent Acquisition (DIA-LOP). [PDF]
McCaskie K +6 more
europepmc +1 more source
Two‐dimensional (2D) infrared (IR) spectroscopy provides vastly more structural and functional insight into chemical and biological systems than linear IR spectroscopy. Here, we apply 2D‐IR spectroscopy to two controversially discussed states of the [FeFe] hydrogenase active site, revealing the presence of a bridging carbonyl ligand, which is difficult
Cornelius C. M. Bernitzky +7 more
wiley +1 more source

