Results 81 to 90 of about 405 (160)

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Coupling Selective Organic Oxidation With Hydrogen Evolution Over Metal Halide Perovskite Photocatalysts: Halide‐Dependent Design, Mechanisms, and Stability Challenges

open access: yesEcoEnergy, EarlyView.
This Review highlights how metal halide perovskites enable coupled selective organic oxidation and hydrogen evolution under visible light. It summarizes halide‐dependent design principles, surface engineering strategies, reaction mechanisms, and stability challenges, providing guidance for developing efficient and durable photocatalytic systems ...
Jutarat Jitrada   +4 more
wiley   +1 more source

Multidimensional Engineering Enabling Rate‐Matched C−N Coupling for Efficient Organonitrogen Electrosynthesis

open access: yesEcoEnergy, EarlyView.
This review introduces rate matching as a unifying design principle for efficient electrochemical C−N coupling and highlights multidimensional engineering of catalysts, interfaces, and reactors to synchronize the generation of carbon‐ and nitrogen‐containing intermediates, balance their surface coverages, maximize C−N bond formation, and enable ...
Kaixing Cai   +4 more
wiley   +1 more source

Near‐Infrared Light‐Driven Photocatalysis: From Advanced Light‐Harvesting Architectures to Rational Reactor Design

open access: yesEcoEnergy, EarlyView.
This review systematically elucidates the regulatory strategies for NIR light, encompassing macroscopic mechanisms such as band engineering, localized surface plasmon resonance (LSPR), upconversion luminescence, and photosensitizer molecules. Furthermore, it provides an in‐depth discussion on their cutting‐edge applications in energy conversion (e.g ...
Huijuan Wang   +8 more
wiley   +1 more source

Advances in Design Strategy and Mechanism Insights for Alkaline Hydrogen Evolution Reaction: Multilevel Site Engineering and Structure–Activity Relationship

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review is about material design based on engineering multilevel sites from theoretical calculation and synthetic routes to mechanism, structure–activity relationship, challenges and perspectives for boosting hydrogen production in alkaline electrolyte. Electrolytic water splitting is a clean, carbon‐free method for producing green hydrogen and has
Ke Zhang   +9 more
wiley   +1 more source

Origin of Physicochemical and Mechanical Stability of Low‐Temperature Prepared TiO2‐Based Photocatalytic Films: Surface Hydroxyl Density Matching

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Material science advances show how surface chemistry improves low‐temperature prepared TiO2‐SiO2 composite films. Using a colloidal‐based synthesis method instead of a powdered‐based one, researchers exploit hydroxyl groups' interfacial interactions to create nanoscale structures with superior physicochemical and mechanical stability.
Andraž Šuligoj   +7 more
wiley   +1 more source

Navigating the Radical Oxo‐Functionalization of Alkenes Toward Ketones

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Straightforward access to complex ketones in a single synthetic step: This Review surveys the latest advances in three‐component alkene 1,2‐oxo‐functionalizations. The opportunities unlocked by the so‐called single‐electron (1e–) logic, including access to a broad pool of radical precursors and carbonyl oxygen atom sources, are highlighted.
Mattia Lepori   +3 more
wiley   +1 more source

Enhancing g‐C3N4 Photocatalytic Activity: K‐Doping and CuO Heterojunction for Selective CO2 Conversion to CH4

open access: yesElectron, EarlyView.
The CuO/K‐g‐C3N4 heterostructure photocatalyst achieves selective CO2 reduction to CH4 (93.03% selectivity) under visible‐light irradiation. K‐doping enhances crystallinity, whereas CuO forms a p‐n heterojunction to promote charge separation and electron transfer.
Ahmed Ismail   +8 more
wiley   +1 more source

The gut microbiome and drug‐resistant epilepsy: Microbiome–antiseizure medication interactions and implications for pharmacoresistance

open access: yesEpilepsia Open, EarlyView.
Abstract Drug‐resistant epilepsy (DRE) affects approximately one‐third of patients with epilepsy and represents a major unmet clinical need. While traditional hypotheses of pharmacoresistance have focused on alterations in drug targets, efflux transporter overexpression, and intrinsic disease severity, the gut microbiome has recently emerged as a ...
Khaled Zammar   +4 more
wiley   +1 more source

Forage chemical composition drives early metabolic shifts in ponies fed different haylages

open access: yesEquine Veterinary Journal, EarlyView.
Abstract Background Rapid changes between feeds can cause dysbiosis and colic in horses. The metabolic consequences of transitioning between haylages (HY) are currently unknown. Objectives To characterise urinary and faecal metabonomics in ponies transitioned between HY varying in botanical composition and physiological age and to evaluate the speed of
M. J. S. Moore‐Colyer   +2 more
wiley   +1 more source

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