Results 101 to 110 of about 7,648,305 (248)

High‐Pressure Synthesis of Quantum‐Stabilised Manganese Superhydride MnH7

open access: yesAngewandte Chemie, EarlyView.
Superhydrides are a rarity in transition metal hosts. Through high‐pressure, high‐temperature diamond anvil cell studies, the most hydrogen‐rich transition metal hydride, MnH7${\rm MnH}_7$ has been synthesised. Density functional theory calculations demonstrate that zero‐point energy stabilises the crystalline structure that MnH7${\rm MnH}_7$ adopts ...
Mikhail A. Kuzovnikov   +10 more
wiley   +2 more sources

(Table 2) Element concentrations of Re, Os, organic and inorganic C, and isotopic composition of Os and Pb of sediment core SI_1034A

open access: yes, 2006
(Table 2) Element concentrations of Re, Os, organic and inorganic C, and isotopic composition of Os and Pb of sediment core ...
Poirier, André   +1 more
core   +1 more source

Water, Alcohols, Amines, and Amides as Formal Hydrogen‐Atom‐Transfer Reagents Through Activation With Redox‐Active Lewis Acids

open access: yesAngewandte Chemie, EarlyView.
Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley   +1 more source

An Enzymatic Platform for Late‐Stage (Radio)isotope Labelling of Oligonucleotides With Methyltransferases

open access: yesAngewandte Chemie, Volume 138, Issue 39, 21 September 2026.
State‐of‐the‐art synthesis of radiolabelled oligonucleotides involves multi‐step synthesis with high costs, extended timelines and significant radioactive waste generation. Herein, a dual‐methyltransferase platform enables late‐stage, site‐specific labelling, overcoming these limitations through reduced costs, faster turnaround and minimal radioactive ...
Christopher R. B. Swanson   +3 more
wiley   +1 more source

Evolutionary, Functional and Mechanistic Characterisation of Microbial Terpene Synthase‐Like Genes From Springtails

open access: yesAngewandte Chemie International Edition, EarlyView.
A genome analysis revealed the presence of many bacterial‐type terpene synthases in springtails. Four enzymes from Sinella curviseta were functionally characterised, resulting in the isolation of several compounds including sinellene ether, the first diterpene ether identified from a terpene synthase that represents a novel skeleton.
Min Wang   +5 more
wiley   +1 more source

Reassessment of Hydrofluoric Acid Desilicification in the Carius Tube Digestion Technique for Re-Os Isotopic Determination in Geological Samples

open access: yes, 2015
In this study, Re and Os isotopes were systematically determined in six geological reference materials (RMs; covering a wide range of lithologies) using the Carius tube (CT) digestion technique with and without hydrofluoric acid desilicification.
Zhao, Pei-Pei   +19 more
core   +1 more source

Long‐term prognosis is associated with residual disease after neoadjuvant systemic therapy but not with initial nodal status

open access: yesBJS (British Journal of Surgery), EarlyView., 2020
This long‐term follow‐up study determined survival rates in a Swedish national cohort of 417 patients with breast cancer who all had neoadjuvant systemic therapy (NAST). Sentinel lymph node biopsy (SLNB) was performed before NAST in clinically node‐negative and after NAST in clinically node‐positive patients.
L. Zetterlund   +4 more
wiley   +1 more source

Zircon U-Pb, molybdenite Re-Os and muscovite Ar-Ar isotopic dating of the Xitian W-Sn polymetallic deposit, eastern Hunan Province, South China and its geological significance

open access: yes, 2016
The Xitian tungsten-tin (W-Sn) polymetallic deposit, located in eastern Hunan Province, South China, is a recently explored region containing one of the largest W-Sn deposits in the Nanling W-Sn metallogenic province.
Zhou, Yun   +8 more
core   +1 more source

Ni isotopes provide a glimpse of Earth's pre-late-veneer mantle. [PDF]

open access: yesSci Adv, 2023
Xu Y   +9 more
europepmc   +1 more source

European multicentre study on outcome of surgery for sporadic primary hyperparathyroidism

open access: yesBJS (British Journal of Surgery), EarlyView., 2020
Some 5861 patients undergoing first‐time surgery for sporadic primary hyperparathyroidism were registered in the Eurocrine® database between 2015 and 2018. The use of intraoperative parathyroid hormone measurement decreased the risk of conversion and persistent hypercalcaemia.
A. Bergenfelz   +3 more
wiley   +1 more source

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