Tailored D‐π Conjugation Boosts Piezocatalytic CO2 Reduction in a Platinum(II)‐Acetylide Framework
The highly conjugated metalII‐acetylide framework demonstrates efficient ultrasound‐driven conversion of CO2 to CO. The piezoelectric field generated by ultrasound facilitates electron transfer from the tetraphenylene π‐column to the MII‐bis(acetylide) moiety, enabling CO2 activation. Compared to PdII‐ and NiII‐based analogues, the stronger d–π orbital
Mude Zhu +6 more
wiley +1 more source
This study reveals a metabolic signaling axis in the OSCC microenvironment where palmitic acid (PA) drives the activation of CAFs. PA uptake triggers CEBPG‐dependent epigenetic remodeling to upregulate ERN1 and TMBIM6, thereby mitigating ER stress. This adaptive program sustains CAF survival and the pro‐metastatic phenotype, establishing this pathway ...
Yiling Duan +6 more
wiley +1 more source
Concordant ages for the giant Kipushi base metal deposit (DR Congo) from direct Rb–Sr and Re–Os dating of sulfides [PDF]
We report concordant ages of 451.1 ± 6.0 and 450.5 ± 3.4 Ma from direct Rb–Sr and Re–Os isochron dating, respectively, of ore-stage Zn–Cu–Ge sulfides, including sphalerite for the giant carbonate-hosted Kipushi base metal (+Ge) deposit in the ...
Melcher, Frank +2 more
core +1 more source
Causal‐Guided Ultra‐Long‐Term Time Series Forecasting Via Anticipated Covariates
Often treated as unknown, information from the future remains underutilized.We demonstrate that in a coupled dynamical system, providing the future state of the effect enables accurate forecasting of the cause for a long timesteps. A time series forecasting paradigm that introduces anticipated covariates to represent such known future states is ...
Jintong Zhao +4 more
wiley +1 more source
Characterization and migration of atmospheric REE in soils and surface waters [PDF]
Rainwater and snow collected from three different sites in France (Vosges Mountains, French Alps and Strasbourg) show more or less similar shapes of their REE distribution patterns.
Aubert, Dominique +10 more
core +1 more source
Re-Os isotope dating of pyrite from the footwall mineralization zone of the Xinqiao deposit, Tongling, Anhui Province: Geochronological evidence for submarine exhalative sedimentation [PDF]
The Xinqiao deposit is located in the Tongling area, Anhui Province. This deposit is dominantly composed of stratiform sulfide orebodies, which are restricted to the transitional zone from clastic rocks to carbonates at the base of the Late Carboniferous Huanglong Formation.
Guo, WeiMin +4 more
openaire +1 more source
Correcting the apparent priming effect resolves systematic biases in Asian rice fertilizer nitrogen accounting. Net soil retention drops below 7%, while 48% of fertilizer escapes, inflicting US$98.53 billion in annual reactive‐nitrogen damages. High‐resolution mapping uncovers N‐risk archetypes across 42% of the rice area, delivering a spatially ...
Xiuyun Liu +5 more
wiley +1 more source
Human neutrophils exist as two epigenetically imprinted subtypes defined by stable CD177 expression or absence — a ratio that persists across time, circadian rhythms, and inflammation. CD177− neutrophils display a distinct molecular landscape enriched in arginase 1 and lipid metabolism markers, accumulate in head‐and‐neck tumors, and associate with ...
Marcel Jung +39 more
wiley +1 more source
Low to middle Pleistocene paleoclimatic record from the Kraków-Częstochowa Upland (Poland) based on isotopic and calcite fabrics analyses [PDF]
The quality of paleoenvironmental reconstruction based on speleothem records depends on the accuracy of the used proxies and the chronology of the studied record.
Tyc, Andrzej +7 more
core +1 more source
Formation of Gallium Monofluoride in the Coordination Sphere of Nickel
The elusive gas‐phase species gallium monofluoride forms selectively in the coordination sphere of a nickel(II) centre as a product of C(sp3)–F bond activation, with a weakly coordinating anion as the fluorine source. The herein reported gallium monofluoride ligand acts as a very strong σ‐donor ligand at nickel and serves as a fluorine donor towards ...
Johannes Stephan +6 more
wiley +2 more sources

