Results 71 to 80 of about 1,126 (271)

Radiation‐Resistant Kr‐Selective MOF With Record Kr/Xe Selectivity at Elevated Pressure

Advanced Science, EarlyView.
ABSTRACT The separation of Kr/Xe from spent nuclear fuel off‐gas is critical, yet most current adsorbents exhibit Xe‐Kr co‐adsorption under elevated pressures, posing challenges for industrial pressure swing adsorption processes. Herein, we present and evaluate a metal‐organic framework, CALF‐20M‐w, engineered for molecular sieving separation of Kr/Xe ...
Qihang Tian, Yinhui Li, Qingkuan Meng, Shizhen Liu, Yongzheng Wang, Bin Chen, Heping Ma   +6 more
wiley   +1 more source

Selection and Treatment of Data for Radiocarbon Calibration: An Update to the International Calibration (IntCal) Criteria [PDF]

, 2013
High-quality data from appropriate archives are needed for the continuing improvement of radiocarbon calibration curves. We discuss here the basic assumptions behind 14C dating that necessitate calibration and the relative strengths and weaknesses of ...
Beck, J. Warren,, Grootes, Pieter, Reimer, Ron W.,, Blackwell, Paul G, Richards, David A, Richards, David, Manning, Sturt W., Bronk-Ramsey, Christopher, Hogg, Alan G.,, Hughen, Konrad, Richards, David A.,, Haflidason, Haflidi,, Blackwell, Paul, Scott, E. M., Beck, J Warren, Buck, C.E., Hogg, Alan G, Turney, Chris S.M., Beck, J.W., Bard, Edouard, van der Plicht, Johannes, Bard, E., Heaton, Timothy J., Kromer, Bernd, Hatté, Christine,, Manning, Sturt W.,, Hughen, Konrad A, Turney, Christian S M, Kaiser, K.F., Reimer, Paula J., Richards, David A., Van Der Plicht, J., Southon, John, Blackwell, P.G., Buck, Caitlin E., Plicht, Johannes van der,, Brown, David M., Guilderson, Thomas, P., Bronk Ramsey, C, Hughen, Konrad A., Scott, E Marian, Blackwell, Paul G., Ramsey, Christopher Bronk, Friedrich, Michael,, Blackwell, Paul G.,, Hogg, Alan G., Bayliss, Alex,, Turney, Christian, Reimer, Paula J.,, Brown, David M, Grootes, Pieter M.,, Kaiser, K. Felix, Hogg, A.G., Reimer, Paula; id_orcid, Hughen, Konrad A.,, Edwards, R. Lawrence, Guilderson, Thomas P.,, Reimer, PJ, Turney, C.S.M., Southon, John R.,, Grootes, Pieter M, Manning, Sturt W, Grootes, P.M., Hajdas, Irka,, Kaiser, K. Felix,, Reimer, Ron, Heaton, Timothy J.,, Grootes, Pieter M., Brown, David M.,, Haflidason, Haflidi, Edwards, R. Lawrence,, Southon, J.R., Southon, John R., Guilderson, Thomas P., Bard, Eduoard, Brown, David, Bayliss, A., Edwards, R Lawrence, Hogg, Alan, Heaton, T.J., Edwards, R.L., Southon, John R, Bard, Edouard,, Reimer, Ron W., Turney, Christian S.M.,, Bronk Ramsey, Christopher,, Manning, Sturt, Bayliss, Alex, Guilderson, Thomas, Heaton, Timothy, Reimer, Paula, Buck, Caitlin E.,, Friedrich, M., Hajdas, I., Buck, Caitlin, Reimer, Ron W, Friedrich, Michael, Kromer, Bernd,, Turney, Christian S. M., Guilderson, T.P., Hajdas, Irka, Scott, E. Marian,, Hatté, Christine, Kaiser, K Felix, Manning, S.W., Buck, Caitlin E, Richards, D.A., Scott, Marian E., Beck, J. Warren, Scott, E. Marian, Bronk Ramsey, Christopher, Heaton, Timothy J, Guilderson, Thomas P   +112 more
core   +1 more source

Revisiting Target‐Aware de novo Molecular Generation with TarPass: Between Rational Design and Texas Sharpshooter

Advanced Science, EarlyView.
TarPass provides a rigorous benchmark for target‐aware de novo molecular generation by jointly evaluating protein‐ligand interactions, molecular plausibility, and drug‐likeness on 18 well‐studied targets. Results show that current models often fail to consistently surpass random baseline in target‐specific enrichment, while post hoc multi‐tier virtual ...
Rui Qin, Zijie Chen, Yurong Li, Meijing Fang, Longji Shen, Yilong Su, Odin Zhang, Qinghan Wang, Qun Su, Jike Wang, Tingjun Hou, Yu Kang   +11 more
wiley   +1 more source

Toward Multi(radio)metalated DNA: Enzymatic Polymerization of Metal‐Chelate‐Modified Deoxyribonucleoside Triphosphates

Angewandte Chemie, EarlyView.
This work presents the first enzymatic polymerization of defined metal‐chelator‐modified nucleotides that leverage polymerase fidelity for uniform (radio)metal loading with successful incorporation of five different metals: Ga, In, Tb, Lu, and Y.
Antonio A. W. L. Wong, François Bénard, David M. Perrin   +2 more
wiley   +2 more sources

Cobalt Single‐Atom Catalysts for Ultrafast Sulfamethoxazole Degradation: Unveiling the Chloride‐Ion‐Enhanced Formation of Co(IV)=O

Advanced Science, EarlyView.
An atomically dispersed Co–N4 single‐atom catalyst rapidly activates peroxymonosulfate to remove the antibiotic sulfamethoxazole from water. Common ions have little impact, but chloride dramatically speeds degradation by promoting a high‐valent Co(IV) = O oxidant via in situ HOCl–catalyst electron transfer.
Anting Ding, Jing Lu, Yafei Fan, Chenyu Zeng, Yuhang Lin, Yufei Shi, Zulin Zhang   +6 more
wiley   +1 more source

CO2‐Induced Reverse Lattice Oxygen Spillover on Pt/CeO2 Enables Sulfur‐Resistant Dry Reforming of Methane

Angewandte Chemie, EarlyView.
A critical step, dry reforming of methane (DRM) converts biogas into useful syngas. Yet trace H2S in biogas rapidly poisons DRM catalysts, limiting practical use. We developed a robust Pt/CeO2 catalyst sustaining DRM activity via CO2‐induced reverse lattice oxygen spillover in H2S‐rich environments.
Jun Liu, Jiang Deng, Jiajia Zheng, Mohsen Beladi Mousavi, Chunning Sun, Jin Li, Xin Chen, Yongjie Shen, Haotian Huang, Ming Xie, Emiliano Cortés, Dengsong Zhang   +11 more
wiley   +2 more sources

Age and Source of the Jinjingzui Skarn-Type Gold Deposit in the Southeastern Hubei Province, China

Applied Sciences
The Jinjingzui gold (Au) deposit is located in the central part of Edong, China. The theoretical gold reserves are large with significant potential for mining and future development.
Yan Li, Chun Cheng, Yuan Yao, Qinghua Yan   +3 more
doaj   +1 more source

Metabolism‐Based Biomarkers for Rapid Phenotypic Antibiotic Susceptibility Testing

Advanced Science, EarlyView.
Metabolic differences emerging after antibiotic exposure provide rapid phenotypic signals of susceptibility and resistance. This review summarizes metabolic biomarkers for rapid phenotypic AST, associated with nutrient uptake, respiratory activity, metabolic reprogramming, and enzymatic function. ABSTRACT The accelerating global crisis of antimicrobial
Sha Yu, Bayinqiaoge, Xi Lu, Xin Wang, Rongfeng Wang, Yi Li, Shi‐Yang Tang, Chengchen Zhang   +7 more
wiley   +1 more source

Bifurcation of *COOH Pathway Determines HCOOH Formation in CO2 Electroreduction on Bismuth

Angewandte Chemie, EarlyView.
Driven by the mechanistic debate of Bi‐catalyzed CO2‐to‐HCOOH conversion, ambiguity remains regarding true reaction pathways. To resolve this, we combined constant‐potential AIMD simulations with spectroscopic evidence to analyze the competitive pathways.
Hyun Dong Jung, Jiawei Deng, Yanbo Hua, Kun Jiang, Seoin Back   +4 more
wiley   +2 more sources

Recent Advances and Challenges in Ammonia‐Hydrogen Energy Conversion

Advanced Science, EarlyView.
This work summarizes the latest progress of various catalytic methods in ammonia‐hydrogen energy conversion. The challenges and outlook of ammonia‐hydrogen energy conversion system are also emphasized. This work expects to build a blueprint of renewable and efficient ammonia‐hydrogen energy conversion systems under mild conditions.
Menghao Lv, Runchao Qin, Jianshuo Chen, Kaiwen Yang, Jianwei Lu, Weiwei Lei, Yifu Yu   +6 more
wiley   +1 more source