Results 11 to 20 of about 1,847,287 (303)

Intramolecular Phosphine-Promoted Knoevenagel Based Redox-Reaction

open access: yesMolecules, 2022
A Knoevenagel based redox-reaction promoted by intramolecular phosphine sources is presented for the first time. The influence of different diketones, aldehydes, bases and acids was investigated. The effects of different substituents were evaluated based
Niklas Feuge   +3 more
doaj   +1 more source

Mechanisms in Knockout Reactions [PDF]

open access: yesPhysical Review Letters, 2009
We report on the first detailed study of the mechanisms involved in knockout reactions, via a coincidence measurement of the residue and fast proton in one-proton knockout reactions, using the S800 spectrograph in combination with the HiRA detector array at the NSCL.
R. J. Charity   +24 more
openaire   +7 more sources

AlF–AlF Reaction Dynamics between 200 K and 1000 K: Reaction Mechanisms and Intermediate Complex Characterization

open access: yesMolecules, 2023
AlF is a relevant molecule in astrochemistry as a tracer of F-bearing molecules. Additionally, AlF presents diagonal Franck-Condon factors and can be created very efficiently in the lab, which makes it a prototypical molecular for laser cooling. However,
Weiqi Wang   +2 more
doaj   +1 more source

Calculation of the Tafel slope and reaction order of the oxygen evolution reaction between pH 12 and pH 14 for the adsorbate mechanism

open access: yesElectrochemical Science Advances, 2023
Despite numerous experimental and theoretical studies devoted to the oxygen evolution reaction (OER), the mechanism of the OER on transition metal oxides remains controversial.
Denis Antipin, Marcel Risch
doaj   +1 more source

Mechanisms of metasomatic reactions [PDF]

open access: yesMineralogy and Petrology, 2009
Fluid-aided mass transfer and subsequent mineralre-equilibrationarethetwodefiningfeaturesofmetasomatismand must be present in order for metamorphism to occur.Taking into account geological time scales, the amount offluidrequiredneednotbegreat(considerablylessthan0.01%of the total volume) nor even in continuous flow but the fluidmust be chemically ...
Harlov, D., Marschall, H.
openaire   +5 more sources

How Metal Nuclearity Impacts Electrocatalytic H2 Production in Thiocarbohydrazone-Based Complexes

open access: yesInorganics, 2023
Thiocarbohydrazone-based catalysts feature ligands that are potentially electrochemically active. From the synthesis point of view, these ligands can be easily tailored, opening multiple strategies for optimization, such as using different substituent ...
Michael Papadakis   +9 more
doaj   +1 more source

Reaction mechanism on Ni-C2-NS single-atom catalysis for the efficient CO2 reduction reaction

open access: yesJournal of Experimental Nanoscience, 2021
Ni-based single-atom catalysis (Ni-SAC) has been experimentally reported with superior performance in reducing CO2 to CO. However, due to the ambiguities in its structures, the active sites of Ni-SAC that are responsible for superior performance have not
Qi Yuan   +8 more
doaj   +1 more source

Effect of Equivalence Ratio on Pollutant Formation in CH4O/H2/NH3 Blend Combustion

open access: yesMolecules, 2023
This paper investigates the effect of equivalence ratio on pollutant formation characteristics of CH4O/H2/NH3 ternary fuel combustion and analyzes the pollutant formation mechanisms of CO, CO2, and NOX at the molecular level.
Jingyun Sun   +3 more
doaj   +1 more source

Elimination of chloramphenicol through electro-fenton-like reaction: Reaction mechanism and electron transfer pathway

open access: yesnpj Clean Water, 2023
An electro-Fenton-like reaction process relying on peroxymonosulfate activation can stably degrade chloramphenicol (CAP) within 16 min, where the kinetic rate constant can be as high as 0.089 min−1 and the energy consumption value can be as low as 25.1 ...
Meng Li   +10 more
doaj   +1 more source

Reaction mechanism and detecting properties of a novel molecularly imprinted electrochemical sensor for microcystin based on three-dimensional AuNPs@MWCNTs/GQDs

open access: yesWater Science and Technology, 2023
Microcystins with leucine arginine (MC-LR) is a virulent hepatotoxin, which is commonly present in polluted water with its demethylated derivatives [Dha7] MC-LR.
Rujing Zhao   +6 more
doaj   +1 more source

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