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Mechanisms of macromolecular reactions
History and Philosophy of the Life Sciences, 2022During the past two decades, philosophers of biology have increasingly turned their attention to mechanisms of biological phenomena. Through analyses of mechanistic proposals advanced by biologists, the goal of these philosophers is to understand what a mechanism is and how mechanisms explain.
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Advances and challenges in modeling solvated reaction mechanisms for renewable fuels and chemicals
WIREs Computational Molecular Science, 2020We provide a critical overview of progress and challenges in computationally modeling multistep reaction mechanisms relevant for catalysis and electrocatalysis.
Yasemin Basdogan+2 more
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Reaction mechanisms: pericyclic reactions
Annual Reports Section "B" (Organic Chemistry), 2012AbstractReview: a survey of articles on pericyclic reactions published in 2012; 45 refs.
Edyta M. Greer, Christopher V. Cosgriff
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Ultrafast Reaction Mechanisms in Perovskite Based Photocatalytic C–C Coupling
, 2020Solar driven carbon–carbon (C–C) bond formation is a new direction in solar energy utilization. Earth abundant nanocrystal based photocatalysts are highly sought after as they can potentially eliminate expensive noble metal catalysts.
Kang Wang+6 more
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Prenyltransferase: the mechanism of the reaction
Biochemistry, 1976The enzyme, prenyltransferase, which normally catalyzes the addition of an allylic pyrophosphate to isopentenyl pyrophosphate, has been found to catalyze the hydrolysis of its allylic substrate. The rate of this hydrolysis is markedly stimulated by inorganic pyrophosphate.
C. D. Poulter, Hans C. Rilling
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ChemInform Abstract: Reaction Mechanisms: Polar Reactions
ChemInform, 2012AbstractReview: 34 refs.
Hon Man Yau, Anna K. Croft
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Dalton Transactions, 2020
Sam de Visser, Jonathan Rourke and Kylie Vincent introduce this Dalton Transactions themed collection on inorganic reaction mechanisms.
Sam P. de Visser+2 more
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Sam de Visser, Jonathan Rourke and Kylie Vincent introduce this Dalton Transactions themed collection on inorganic reaction mechanisms.
Sam P. de Visser+2 more
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Energy & Environmental Science, 2019
Atomically dispersed metal catalysts for the oxygen reduction reaction, including their synthesis, characterization, reaction mechanisms and electrochemical energy application, are reviewed.
Minmin Liu+8 more
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Atomically dispersed metal catalysts for the oxygen reduction reaction, including their synthesis, characterization, reaction mechanisms and electrochemical energy application, are reviewed.
Minmin Liu+8 more
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Mechanism of the Dihydroorotase Reaction
Biochemistry, 2004Dihydroorotase (DHO) is a zinc metalloenzyme that functions in the pathway for the biosynthesis of pyrimidine nucleotides by catalyzing the reversible interconversion of carbamoyl aspartate and dihydroorotate. A chemical mechanism was proposed on the basis of an analysis of the effects of pH, metal substitution, solvent isotope effects, mutant proteins,
Tamiko N. Porter+2 more
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Reaction Mechanisms of Well-Defined Metal-N4 Sites in Electrocatalytic CO2 Reduction.
Angewandte Chemie, 2018Electrocatalytic CO2 reduction to CO emerges as a potential route of utilizing emitted CO2 . Metal-N-C hybrid structures have shown unique activities, however, the active centers and reaction mechanisms remain unclear because of the ambiguity in true ...
Zheng Zhang+11 more
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