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Mechanisms of macromolecular reactions

History and Philosophy of the Life Sciences, 2022
During the past two decades, philosophers of biology have increasingly turned their attention to mechanisms of biological phenomena. Through analyses of mechanistic proposals advanced by biologists, the goal of these philosophers is to understand what a mechanism is and how mechanisms explain.
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Advances and challenges in modeling solvated reaction mechanisms for renewable fuels and chemicals

WIREs Computational Molecular Science, 2020
We provide a critical overview of progress and challenges in computationally modeling multistep reaction mechanisms relevant for catalysis and electrocatalysis.
Yasemin Basdogan   +2 more
semanticscholar   +1 more source

Reaction mechanisms: pericyclic reactions

Annual Reports Section "B" (Organic Chemistry), 2012
AbstractReview: a survey of articles on pericyclic reactions published in 2012; 45 refs.
Edyta M. Greer, Christopher V. Cosgriff
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Ultrafast Reaction Mechanisms in Perovskite Based Photocatalytic C–C Coupling

, 2020
Solar driven carbon–carbon (C–C) bond formation is a new direction in solar energy utilization. Earth abundant nanocrystal based photocatalysts are highly sought after as they can potentially eliminate expensive noble metal catalysts.
Kang Wang   +6 more
semanticscholar   +1 more source

Prenyltransferase: the mechanism of the reaction

Biochemistry, 1976
The enzyme, prenyltransferase, which normally catalyzes the addition of an allylic pyrophosphate to isopentenyl pyrophosphate, has been found to catalyze the hydrolysis of its allylic substrate. The rate of this hydrolysis is markedly stimulated by inorganic pyrophosphate.
C. D. Poulter, Hans C. Rilling
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ChemInform Abstract: Reaction Mechanisms: Polar Reactions

ChemInform, 2012
AbstractReview: 34 refs.
Hon Man Yau, Anna K. Croft
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Inorganic reaction mechanisms

Dalton Transactions, 2020
Sam de Visser, Jonathan Rourke and Kylie Vincent introduce this Dalton Transactions themed collection on inorganic reaction mechanisms.
Sam P. de Visser   +2 more
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Atomically dispersed metal catalysts for the oxygen reduction reaction: synthesis, characterization, reaction mechanisms and electrochemical energy applications

Energy & Environmental Science, 2019
Atomically dispersed metal catalysts for the oxygen reduction reaction, including their synthesis, characterization, reaction mechanisms and electrochemical energy application, are reviewed.
Minmin Liu   +8 more
semanticscholar   +1 more source

Mechanism of the Dihydroorotase Reaction

Biochemistry, 2004
Dihydroorotase (DHO) is a zinc metalloenzyme that functions in the pathway for the biosynthesis of pyrimidine nucleotides by catalyzing the reversible interconversion of carbamoyl aspartate and dihydroorotate. A chemical mechanism was proposed on the basis of an analysis of the effects of pH, metal substitution, solvent isotope effects, mutant proteins,
Tamiko N. Porter   +2 more
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Reaction Mechanisms of Well-Defined Metal-N4 Sites in Electrocatalytic CO2 Reduction.

Angewandte Chemie, 2018
Electrocatalytic CO2 reduction to CO emerges as a potential route of utilizing emitted CO2 . Metal-N-C hybrid structures have shown unique activities, however, the active centers and reaction mechanisms remain unclear because of the ambiguity in true ...
Zheng Zhang   +11 more
semanticscholar   +1 more source

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