Results 141 to 150 of about 16,200 (273)

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich   +9 more
wiley   +1 more source

Investigating Hydrogen Movement and Lithium-Ion Diffusion in Reactive Hydride Composites for Enhanced Hydrogen Storage Performance using QENS and Impedance Spectroscopy

open access: green
Dr Sweta Munshi   +10 more
openalex   +2 more sources

Reversible H<sub>2</sub> storage at moderate temperature by a trilayered lithium borohydride nanocomposite. [PDF]

open access: yesNat Commun
Zhang W   +11 more
europepmc   +1 more source

Unlocking Heterobimetallic Architectures in a Symmetric PNNP Ligand Environment

open access: yesChemistry – A European Journal, EarlyView.
A symmetric PNNP ligand enables the modular assembly of heterobimetallic ZnRu and CoRu complexes from a mononuclear Ru(II) precursor. Ligand deprotonation triggers dearomatization and contraction of the metal–metal distance. Combined DFT and QTAIM analyses reveal metallophilic interaction in CoRu but not in ZnRu, highlighting controllable geometric and
Stanislav Melnikov   +4 more
wiley   +1 more source

Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst

open access: yesChemistry – A European Journal, EarlyView.
While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival   +9 more
wiley   +1 more source

Iridium Complexes of a Triazole‐Derived Pincer Ligand: Synthesis, Reactivity, and Transfer Dehydrogenation Catalysis

open access: yesChemistry – A European Journal, EarlyView.
Ir pincer complexes bearing a triazole architecture in the pincer backbone and O‐ancillary chelating ligands are presented. These were employed in the catalytic transfer dehydrogenation of alkanes as well as of saturated heterocycles. Reactivity of these complexes with silver salts and Lewis acids produced various cationic iridium complexes.
Jesvita Cardozo   +5 more
wiley   +1 more source

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