Self‐Complementary Dimers Based on Zwitterionic Halogen Bond Donors
In this study we present the first isolated zwitterionic homodimers based on halogen bonding (XB). After optimization of the structures by changing the Lewis base (LB) and the backbone, their dimerization was observed in gas phase, as well as, in solid state.
Dana Kutzinski +5 more
wiley +1 more source
Production of low sulfur diesel fuel through ultrasonic catalytic oxidative route using novel mixed oxides nanocomposites assisted by solvent extraction. [PDF]
Zahran AI +3 more
europepmc +1 more source
Aminocatalytically generated isobenzofulvenes and 3‐oxidopyridinium betaines act as ambiphilic reaction partners in orbital‐symmetry‐allowed [10+4] cycloadditions or formally symmetry‐forbidden concerted thermal [10+6] cycloadditions. The reaction furnishes three cycloadducts: one [10+4] cycloadduct and two regioisomeric [10+6] cycloadducts.
Jonas Faghtmann +7 more
wiley +1 more source
Interfacial engineering of aluminum powder with a tannic acid/Fe³⁺ complex and fluorosilane for high-performance energetic composites. [PDF]
Liu B +6 more
europepmc +1 more source
Breaking the Mold: Electrophilic Hydrophosphanation Emerges
Electrophilic hydride attack on the olefin, instead of the classical nucleophilic addition by a phosphanido ligand, is unveiled in rhodium‐catalyzed olefin hydrophosphanation. This hydride‐driven pathway operates for both activated and inactivated olefins, with transition states characterized by elongated Rh─H bonds and nascent C─H bond formation ...
Víctor Varela‐Izquierdo +4 more
wiley +1 more source
Smart ROS-regulating biomimetic hydrogel promotes scarless diabetic wound healing via macrophage reprogramming. [PDF]
Du P +8 more
europepmc +1 more source
Reductive conversion of CO2 to formic acid with waste silicon reducing agent catalyzed by in situ generation of active fluoride species from a tertiary amine, protonic acid, and simple inorganic fluoride salt, such as KF and NaF. ABSTRACT The activation and catalytic reduction of carbon dioxide (CO2) using silicon‐based reducing agents is an important ...
S. M. A. Hakim Siddiki +6 more
wiley +1 more source
Application of Amorphous Nanomaterials in Dentistry: A Comprehensive Review. [PDF]
Yin IX +5 more
europepmc +1 more source
Synthesis and Reactivity of 3‐Aminosydnones in Cycloaddition Reactions With Alkynes
The synthesis, functionalization, and reactivity as dipoles of 3‐aminosydnones have been investigated. These neglected compounds undergo smooth cycloaddition reactions with strained alkynes, leading to 1‐aminopyrazoles. ABSTRACT We present in this article the synthesis, functionalization, and properties of 3‐aminosydnones, a forgotten class of ...
Apolline Dominic +7 more
wiley +1 more source
Enhancing hydrogen uptake in TiFe at moderate pressures <i>via</i> rationally designed biomass-derived carbon additives. [PDF]
Kalibek M +9 more
europepmc +1 more source

